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Based on daily meteorological records for 651 sites across China during the period 1960–2018, we estimated the changes in isotopic variations in raindrops as they descend from cloud base to ground over past decades, and tested the sensitivity of isotopic variations to climate parameters like air temperature and relative humidity. Air temperature correlates positively and relative humidity correlates negatively with below‐cloud isotopic variation. Generally, the below‐cloud evaporation effect on precipitation isotopes in the arid and semi‐arid regions of China is much greater than that in the humid and semi‐humid regions, although the impact might be reduced under cold‐arid or hot‐humid conditions. With aridity increasing with distance from the coast, the continental effect of precipitation isotopes is modified due to the below‐cloud evaporation. The seasonal pattern of the measured isotopic composition in precipitation near the ground and estimated at cloud base, is still similar in most regions, although the seasonal range is higher at the ground. During the last five decades, the below‐cloud evaporation effect has enhanced for the cold and arid regions of China especially across Qinghai‐Tibet Plateau and Inner Mongolia, due to combined effects of increasing air temperature and decreasing relative humidity. Although the below‐cloud evaporation effect is not always the dominant factor influencing the variability of stable isotopes, it needs to be considered as one of the contributing factors. This enhanced effect may impact the interpretation of past climate based on stable water isotopes, particularly in paleoclimate studies using speleothems and tree rings. Key Points: Below‐cloud evaporation effect on precipitation isotopes is assessed nationwideThe variability of below‐cloud evaporation effect is controlled by the warming climateEnhanced below‐cloud evaporation may affect interpretation of long‐term isotope records [ABSTRACT FROM AUTHOR]

Different water sources exploited for public use have different exposure to risks associated with climatic and environmental change. Isotope ratios of tap water have previously been studied as a potential tool to link public supply waters with water source characteristics at local to continental scales, providing information on the footprint of and potential risks associated with the water sources used. Work that combines intensive spatial and temporal sampling with independent water management data has been limited, however. In this study, an extensive observation network was established during 2014–2016 to provide monthly tap water sampling across China. We show that the spatial distribution of annual mean tap water isotope ratios is generally consistent with that of local precipitation across China. We identify seasonal correlation between tap water and precipitation isotope ratios in south China, where use of surface water is prevalent. In contrast, relatively invariant tap water isotope ratios elsewhere in China, which are not correlated with seasonal variation of precipitation isotope ratios, can be attributed to use of groundwater or water from river basins with longer storage times. The tap water isotope signatures identified here could be widely applied to characterize water supplies and associated sustainability challenges in different regions worldwide. Key Points: A new nationwide network of tap water isotope data across China was establishedConnection between monthly stable isotopes in tap water and precipitation is identifiedDiagnostic patterns of tap water isotopes are associated with water resource use [ABSTRACT FROM AUTHOR]

Terrestrial moisture contributed by surface evaporation and transpiration, also known as recycled moisture, plays an important role in hydrological processes especially across arid central Asia. The stable hydrogen and oxygen isotopes can be used for water budget analysis to calculate the contribution of recycled moisture to precipitation between two locations along the moisture flow. Based on a three-component isotopic mixing model, the moisture recycling in oasis stations of arid central Asia during summer months is assessed. At large oases of Urumqi, the proportional contribution of recycled moisture to local precipitation is approximately 16.2%, and the mean proportions of surface evaporation and transpiration are 5.9% ± 1.5% and 10.3% ± 2.2%, respectively. At small oases like Shihezi and Caijiahu the contribution of recycled moisture is less than 5%, and the proportion of surface evaporation is much less than that of transpiration. The vegetative cover in arid central Asia is generally sparse, but the evapotranspiration contribution to precipitation cannot be ignored at the widely distributed oases. The oasis effect shows great variability depending on locations and water availability for evapotranspiration. [ABSTRACT FROM AUTHOR]

Approximately one-third of the Earth's arid areas are distributed across central Asia. The stable isotope composition of precipitation in this region is affected by its aridity, therefore subject to high evaporation and low precipitation amount. To investigate the factors controlling stable water isotopes in precipitation in arid central Asia, an observation network was established around the Tianshan Mountains in 2012. Based on the 1052 eventbased precipitation samples collected at 23 stations during 2012-2013, the spatial distribution and seasonal variation of δD and δ18O in precipitation were investigated. The values of δD and δ18O are relatively more enriched in the rainfall dominant summer months (from April to October) and depleted in the drier winter months (from November to March) with low D-excess due to subcloud evaporation observed at many of the driest low elevation stations. The local meteoric water line (LMWL) was calculated to be δD=7.36δ18O+0.50 (r²=0.97, p<0.01) based on the event-based samples, and δD=7.60δ18O+2.66 (r²=0.98, p<0.01) based on the monthly precipitation-weighted values. In winter, the data indicate an isotopic rain shadow effect whereby rainout leads to depletion of precipitation in the most arid region to the south of the Tianshan Mountains. The values of d18Osignificantly correlate with air temperature for each station, and the best-fit equation is established as δ18O=0.78T - 16.01 (r²=0.73, p<0.01). Using daily air temperature and precipitation derived from a 0.5° (latitude)?0.5° (longitude) gridded data set, an isoscape of δ18Oin precipitation was produced based on this observed temperature effect. [ABSTRACT FROM AUTHOR]

Based on the 420 samples of precipitation and related meteorological parameters obtained from the four sampling sites (Yongdeng, Gaolan, Lanzhou and Yuzhong) in Northwest China from April 2011 to February 2013, the influence of sub-cloud secondary evaporation effect on stable isotopes in precipitation was analyzed. Four main factors affecting the secondary evaporation were precipitation, air temperature, water vapor pressure, and relative humidity. The results showed that sub-cloud secondary evaporation had a significant effect on isotopes when the rainfall amount was small, but the correlation was not significant for snowfall or heavy rainfall. As the temperature increased, the secondary evaporation was enhanced. Water vapor pressure greatly impacted the sub-cloud secondary evaporation of the rain, but had less influence on the snow events. Relative humidity showed an influence on d-excess value, as well as the slope and intercept of the δD-δ 18 O correlation equation of light rainfall, but had a small impact when snow occurred. The estimated secondary evaporation rate was generally lower in winter and higher in summer, and spatially varied depending on locations. During the summer monsoon period (June to September), the secondary evaporation rate was estimated to be between 5.90% and 10.50% for each station with the mean value of 8.30%, and during the winter monsoon period (October to May), the rate was between 3.20% and 5.62%, with the average value of 4.54%. [ABSTRACT FROM AUTHOR]

Based on the precipitation samples obtained at Lanzhou City (36°06′N, 103°44′E, 1,548 m a.s.l.) in western China and its surrounding counties (Yongdeng, Gaolan, and Yuzhong) from April 2011 to February 2013, the characteristics of stable isotopes in precipitation and the correlations between δO and meteorological factors were analyzed. The LMWL (local meteoric water line) of Lanzhou City and its surrounding areas was calculated, and the order of LMWL slopes in the four stations is Yuzhong (7.70) > Lanzhou (7.57) > Yongdeng (7.24) > Gaolan (6.80). Both the slope and intercept of the LMWLs for each station are less than those of the global meteoric water line. There is a weakly positive correlation between δO and air temperature, and the correlation between δO and precipitation amount is weakly negative. Evidenced from the slope and intercept of LMWL and the relationship between δO and relative humidity, there is secondary evaporation when the precipitation falls from clouds to the ground. [ABSTRACT FROM AUTHOR]

The deuterium excess in precipitation is an effective indicator to assess the existence of sub-cloud evaporation of raindrops. Based on the synchronous measurements of stable isotopes of hydrogen and oxygen (δ2H and δ18O) in precipitation for several sites in Lanzhou, western China, spanning for approximately four years, the variations of deuterium excess between the ground and the cloud base are evaluated by using a one-box Stewart model. The deuterium excess difference below the cloud base during summer (−17.82‰ in Anning, −11.76‰ in Yuzhong, −21.18‰ in Gaolan and −12.41‰ in Yongdeng) is greater than that in other seasons, and difference in winter is weak due to the low temperature. The variations of deuterium excess in precipitation due to below-cloud evaporation are examined for each sampling site and year. The results are useful to understand the modification of raindrop isotope composition below the cloud base at a city scale, and the quantitative methods provide a case study for a semi-arid region at the monsoon margin. [ABSTRACT FROM AUTHOR]

The deuterium excess (d) in precipitation, determined by the stable hydrogen and oxygen isotopes (δ2H and δ18O), is a widely applied parameter in tracing the water vapor source. Based on the multiple-year observations of stable water isotopes in precipitation at four stations in the Lanzhou city, Northwest China, we analyzed the variations in deuterium excess in precipitation at the Asian monsoon margin region. The mean value of deuterium excess at the study region is 11.0‰ in the dry season and 8.0‰ in the wet season. The d value in precipitation negatively correlates with air temperature and vapor pressure. The low d value during the wet season reflects the monsoon moisture transported from long distances. During the dry season, the continental air masses correspond to the higher d value in precipitation. The moisture regimes based on reanalysis data are generally consistent with the findings using a stable isotopic approach, and the monsoon moisture is highlighted in summer precipitation at these monsoon margin sites. [ABSTRACT FROM AUTHOR]

The stable isotopes in precipitation provide a new understanding for the mechanism study of water cycles in the Loess Plateau. However, there has never been an introduction for the Tianshui area, which is transitioning from semi-humid to semi-arid. We analyzed the time series changes of stable isotopes in precipitation at seven sampling points during pre-monsoon, monsoon and post-monsoon periods (April to October) in the Tianshui area. The results show that the temperature effect not only shows spatial differences but also seasonal changes and a weak precipitation effect is only found during the monsoon period. At the same time, the variation characteristics of precipitation isotopes before and after the monsoon clearly record the advancing and retreating time of the monsoon. We captured this important time node around 7 May and 21 September. Due to the influence of the regional microclimate formed by different natural conditions, the kinetic fractionation effect of isotopes in precipitation cause obvious differences in the slope and intercept of the meteoric water line in different natural regions, which shows that the stable isotopes in precipitation with high-resolution changes in a short period of time are of great significance to deeply explore the hydrological process of regional microclimates. [ABSTRACT FROM AUTHOR]

Stable isotopes (e.g., δ2H and δ18O) in tap water are important tools to understand the local climate or environment background, water sources and the state of regional water supply. Based on 242 tap water samples, 35 precipitation samples and 24 surface water samples gathered in the urban area of Lanzhou, the basic spatiotemporal characteristics of isotopes in tap water, their connection with isotopes in other water bodies and change during the process from raw water to tap water are discussed in detail, combining the information of local tap water supply and water source. It can provide reliable help for understanding the isotope characteristics of local tap water, regional water supply management and determination of tap water source of in a small area. Except for the establishment of a new data set of isotopes in tap water with complete time series and uniform spatial distribution of sampling sites, other results show that: (1) The Local Tap Water Line (LTWL) of Lanzhou is δ2H = (6.03 ± 0.57) δ18O + (−8.63 ± 5.44) (r2 = 0.41, p < 0.01). (2) For seasonal variations, δ2H and δ18O in tap water both are higher in autumn and lower in spring. The diurnal and daily variations of isotopes in tap water are not large. As for spatial variations, the monthly mean values of δ2H and δ18O in tap water at each sampling site show little difference. The isotopes in tap water collected from one single sampling site can be considered as a representative for isotopes in tap water in the area with a single tap water source. (3) Isotopes in tap water show weak connection with precipitation isotopes, but exhibit good connection (consistent seasonal variation, similar numerical range, small numerical difference and high correlation) with isotopes in surface water, which is the direct water source. Isotopes in water change little from raw water to tap water. Isotopic composition of tap water in Lanzhou can be used as a representative of isotopes in surface water. [ABSTRACT FROM AUTHOR]