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The study on precipitation isotope variation can potentially improve the understanding of weather processes, regional water cycle and paleoclimate reconstruction in the subtropical monsoon region. Based on the measured stable isotope composition in precipitation (δ18Op) and daily precipitation from January 2010 to December 2021 in Changsha of the subtropical monsoon region of eastern China, the δ18Op variations, amount effect and local meteoric water line (LMWL) were analyzed and compared on daily, monthly and annual time scales, as well as under different precipitation intensities. The results showed that, on the daily time scale, δ18Op was significantly and negatively correlated with precipitation in the study area. Influenced by subcloud evaporation, small precipitation events (≤5 mm/d) could change the rainout level of precipitation isotopes. There were significant differences in the slope and intercept of the LMWL on different time scales, in different seasons and under different precipitation intensities. On the daily and monthly time scales, the slope and intercept of the LMWL in the cold half of the year were significantly smaller and larger than those in the warm half of the year, respectively, and the slope and intercept of the LMWL increased significantly with precipitation intensity, and then remained largely stable. On the annual time scale, the slope and intercept of the LMWL in the cold half of the year were smaller than those in the warm half of the year. The possible reasons for the differences in the LMWL on different time scales are the combined effects of seasonal differences in precipitation intensity and water vapor sources. [ABSTRACT FROM AUTHOR]

The northeastern Tibetan Plateau is located in a climatic junction, which is considered an ideal region to explore the interactions between the summer monsoons and the westerly circulation patterns. However, to date, the needed long-term precipitation-based isotopic dataset is too limited to predict the interactions and patterns. This paper presents an evaluation of hydrometeorological processes and climate dynamics in the northeastern Tibetan Plateau based on a 7-yr precipitation isotope dataset covering the summer monsoon periods from 2012 to 2018. Results illustrated remarkable seasonal isotopic variability, characterized by lower δ18O and δ2H values in June with an average of −10‰ and −66.7‰, respectively. Higher δ18O and δ2H values in July averaged −6.7‰ and −39.5‰, respectively. This clear isotopic variability is largely related to seasonal changes of moisture sources and hydrometeorological processes. These precipitation isotopic values were primarily determined by the amount of precipitation, relative humidity, and convective activity, but showed no correlation with air temperature. Backward trajectory model results showed that Xinjiang, northern China, the Arctic, central Asia, and the South China Sea (SCS) were the primary sources of precipitation for the study site with varying seasonal contributions. The maritime moisture source of the SCS primarily resulted in the lowest precipitation δ18O values during the prevailing summer monsoon, which is mainly as a result of the strong convective activity and rainout processes along the air trajectory. The higher average deuterium excess (d-excess) value of precipitation in September indicated continental sources from central Asia (e.g., 75.4%) as land vapor recycling increases d-excess concentration in the atmosphere. These findings provide further insights into the main factors of precipitation isotopic variability related to atmospheric processes along the trajectory and the relevant factors in the monsoon regions. Significance Statement: Recently, scientists and policy makers have become aware that Tibetan hydroclimate variability provides evidence of changes in regional and global circulation patterns that may result in the intensification of climate-driven extremes. However, these studies largely depend on crucial paleoclimate records of past precipitation isotopes in monsoon regions, which contain great uncertainties because of the complex relationship between climatic variability and precipitation isotopes. This study first presented a 7-yr isotopic dataset to understand the hydrological processes and climate dynamics controlling the isotopic variability in the northeastern Tibetan Plateau. The findings reveal important factors on the isotopic variability associated with atmospheric processes and their key climatic variables, which can enhance our interpretation of the paleoclimate records in monsoon regions. [ABSTRACT FROM AUTHOR]

• The systematic observations benefit the lake water isotopes (δ L) simulations. • This study well simulated the temporal variations of δ L of a small and open lake. • The MBM captured the influences of extreme weather events on the δ L. • The sensitivity test well evaluated the influences of weather seasonality on the δ L. Hydrologic and isotope mass-balance models (MBMs) are useful tools for the simulation and quantitative interpretation of lake water δ18O (δ L). Such studies of small, open lakes are important because δ L may show large responses to weather-driven hydrological variability. A δ L sequence was simulated for three-year and five-day interval data from Taozi Lake, a small, open lake in Changsha, in the East Asian monsoon region of China. The MBMs performed well, with the optimal model explaining 90% of the observed δ L variability. However, it was necessary to parameterize the precipitation input by increasing the lake water depth during heavy precipitation events to capture the observed sharp decreases in δ L. We found that the MBMs using air temperature and the equilibrated atmospheric vapor δ18O (δ A) produced a more negative δ L compared to the model using the surface water temperature and the observed δ A , and that the equilibrated δ A was somewhat arbitrary, which introduced a large error in the model output. A sensitivity test highlighted the importance of the seasonal variability of hydrometeorological and isotopic variables to reproduce the observed δ L variability. Additionally, the simulated average δ L showed a similar pattern of variation to the meteorological variables shifted by different ratios, but for the relative humidity, there was only a narrow window within which a realistic δ L series could be reproduced. Our results show that a realistic MBM can be established based on long-term observations, with implications for studies of hydrologic processes and paleoclimate reconstruction. [ABSTRACT FROM AUTHOR]