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1. Iron hydrogenase active site mimic holding a proton and a hydride.

2. High turnover photocatalytic hydrogen formation with an Fe(III) N-heterocyclic carbene photosensitiser.

3. Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)–polypyridyl-catalyzed reduction of water.

4. Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenasesElectronic supplementary information (ESI) available: Synthesis, crystal data of 5, electrochemistry data and details of overpotential calculation. CCDC 811891. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1cc14449aThis article is part of the ChemComm‘Artificial photosynthesis’ web themed issue

5. Model of the Iron Hydrogenase Active Site Covalently Linked to a Ruthenium Photosensitizer: Synthesis and Photophysical Properties.

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