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The title compound, [Al(H2O)6][Cr(OH)6Mo6O18]·10H2O, hexaaquaaluminium hexahydroxidooctadecaoxidomolybdochromate(III) decahydrate, crystallizes isotypically with its gallium analogue [Ga(H2O)6][Cr(OH)6Mo6O18].10H2O. In the structure of the title compound, both the [Al(H2O)6]3+ cation and the Anderson-type [Cr(OH)6Mo6O18]3− anion lie on centres of inversion. The anion is composed of seven edge-sharing octahedra, six of which are MoO6 octahedra that are arranged hexagonally around the central Cr(OH)6 octahedron. The anions are linked to each other by O—H...O hydrogen bonds into infinite chains along [100]. These chains are further connected with the [Al(H2O)6]3+ cations through O—H...O hydrogen bonds into sheets parallel to (01overline{1}). O—H...O hydrogen bonds involving all the lattice water molecules finally link the sheets into a three-dimensional network.

In the title coordination polymer, {[Sm2(C4H2O4)3(H2O)6]·6H2O}n, the SmIII ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water molecules. The fumarate ligand lies on an inversion center. Adjacent SmIII ions are bridged by the maleate and fumarate ligands, forming a layer parallel to (011). The layers are further linked by intermolecular O—H...O hydrogen bonds into a three-dimensional supramolecular network.

In the title coordination polymer, [Na2(C4H3N2O2S)Cl(H2O)2]n, the NaI ion lies on a twofold rotation axis and the chloride anion on an inversion center. The NaI ion is six-coordinated by two O atoms from two zwitterionic 2-mercaptopyrimidine-4,6-diolate ligands (mm2 symmetry), two water O atoms (m symmetry) and two Cl atoms in a distorted octahedral geometry. Adjacent NaI ions are bridged by an olate group, a water molecule and a chloride anion into a three-dimensional network. The crystal structure is further stabilized by N—H...Cl, O—H...O and O—H...S hydrogen bonds.

In the title compound, C14H8N4S6, the two five-membered rings lie in the same plane with an r.m.s. deviation of 0.0334 (5) Å. The crystal structure features intermolecular S...N interactions of 3.295 (4) Å.

In the title compound, [Cu(NO3)2(C18H16N2O2)], the CuII ion is six-coordinated in a Jahn–Teller-distorted octahedral environment defined by two O and two N atoms from the ligand and two O atoms from two monodentate nitrate anions.

The title compound, C13H20O3S5, is bisected by a crystallographic twofold rotation axis, which relates the two halves of the molecule to one another: one S, one C and one O atom lie on the axis. The thione S atom lies in the plane of the five-membered rings with an r.m.s. deviation of 0.0042 (5) Å. Parts of the 17-membered macrocycle were refined using a two-part disorder model [occupancies of 0.553 (14) and 0.447 (14)]. There are no noteworthy intermolecular interactions.

In the title compound, C16H16N2O3S6, the two five-membered rings form a dihedral angle of 7.86 (9)°. Weak C—H...N hydrogen bonds link the molecules to form a chain along c; the chains are further connected by weak C—H...O hydrogen bonds to form a three-dimensional supramolecular network.

In the title compound, C18H26O3S8, the two five-membered rings exhibit envelope conformations. The two S atoms in the 17-membered macrocycle deviate from the plane of the fused five-membered ring by 1.429 (3) and −1.434 (3) Å in opposite directions.

The asymmetric unit of the title compound, C19H19NOS6, contains two independent molecules with different conformations of the ethyl groups. The dihedral angles between the pyrrole and benzene rings are 14.19 (14) and 16.29 (17)° in the two molecules. In the absence of short intermolecular contacts, in the crystal, the molecules are packed with their long axes parallel to [10overline{1}].

In the title molecule, C16H22S8O2, two S atoms, two O atoms and ten C atoms form a 14-membered ring with a boat conformation. In the crystal, C—H...O hydrogen bonds link the molecules into dimers which are further connected into a chain along the a axis by C—H...S hydrogen bonds.

In the title molecule, C14H18OS8, one O atom, two S atoms and six C atoms form an 11-membered ring with a chair-like conformation; the planes of the two five-membered rings connected by a carbon–carbon double bond form a dihedral angle of 29.97 (11)°. In the crystal, pairs of weak intermolecular C—H...S hydrogen bonds link two molecules into inversion dimers.

In the title molecule, C11H16O2S5, the two S atoms from the macrocycle are situated on opposite sides of the mean plane of the five-membered ring, deviating from it by 1.288 (3) and 1.728 (3) Å. In the crystal, weak intermolecular C—H...S and C—H...O hydrogen bonds link the molecules into layers parallel to (100). The crystal studied was a racemic twin.

In the title molecule, C9H12S5O, the five-membered ring and attached S atom are essentially coplanar [mean deviation from the mean plane = 0.020 (1) Å]. The two S atoms belonging to the macrocycle deviate from this plane by 1.005 (1) and 1.337 (2) Å. In the crystal, π–π interactions link the molecules into centrosymmetric dimers with a short distance of 3.753 (5) Å between the centroids of the five-membered rings.

In the title molecule, C16H20O5S6, the two five-membered rings form a dihedral angle of 4.7 (3)°. The crystal packing exhibits weak intermolecular C—H...O hydrogen bonds, which link the molecules into chains propagating in [1overline{1}0], and π–π interactions, indicated by the short distances [3.756 (5) Å] between the centroids of five-membered rings from molecules related by translation along the b axis.