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We briefly discuss the history of pumping schemes for the common 22-GHz maser transition in o-H2O, and note that radiative mechanisms have been considered in the past, as well as the better known collisional pumping mechanisms associated with shock waves. Substantial IR irradiation is indeed destructive to inversion at 22-GHz under a wide range of physical conditions. We identify a small number of transitions, including 22 GHz, that can be pumped by both collisional and radiative schemes, and, through radiative transfer modelling over a grid of values in kinetic temperature, number density, and dust temperature, identify loci in density-kinetic temperature space where these schemes lead to strong inversions. The radiative pumping scheme generally operates at higher dust temperature, and lower kinetic temperature, than the collisional scheme. We identify a small network of transitions that form a radiative pumping scheme for the 22-GHz maser, involving radiative transitions of wavelength approximately 6  |$\mu$| m. This network is capable of supplying more than 50 per cent of the 22-GHz inversion under typical radiative pumping conditions, and it is consistent with the need for high dust and low kinetic temperatures determined from the modelling. We identify a probable case of radiative pumping in a massive star-forming region from the observation of a positive correlation between the flux densities of 22-GHz H2O masers and 6.7-GHz methanol masers. We discuss possibilities for finding radiatively pumped H2O maser lines in other source types. [ABSTRACT FROM AUTHOR]

A 3D maser model has been used to perform an inverse problem on the light curves from three high-amplitude maser flares, selected on the basis of contemporaneous infrared observations. Plots derived from the model recover the size of the maser cloud, and two parameters linked to saturation, from three observational properties of the light curve. Recovered sizes are consistent with independent interferometric measurements. Maser objects transition between weak and moderate saturation during a flare. [ABSTRACT FROM AUTHOR]

We simulate maser flares by varying either the pump rate or the background level of radiation in a 3D model of a maser cloud. We investigate the effect of different cloud shapes, saturation levels, and viewpoints. Results are considered for clouds with both uniform and internally variable unsaturated inversion. Pumping and background variations are represented by several different driving functions, some of which are light curves drawn from observations. We summarize the pumping variability results in terms of three observable parameters: the maximum flux density achieved, a variability index, and duty cycle. We demonstrate typical ranges of the flux density that may result from viewing an aspherical object from random viewpoints. The best object for a flare is a prolate cloud, viewed close to its long axis and driven from unsaturated conditions to at least modest saturation. Results for variation of the background level are qualitatively different from the variable pumping results in that they tend to produce short intervals of low flux density under conditions of moderate saturation and sufficient variability to be consistent with strong flaring. Variable background models typically have a significantly higher duty cycle than those with variable pumping. [ABSTRACT FROM AUTHOR]