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Biodiesel can be produced both in homogeneous and heterogeneous ways. Heterogeneous synthesis allows to easily separate catalyst from esters. In this work, eggshells as a heterogeneous catalyst were used for triglyceride transesterification with 1-butanol. Response surface methodology was used for process optimization. It was obtained that eggshells are a suitable catalyst for transesterification processes. A longer process duration and higher catalyst amount have a high influence on ester yield. However, the amount of 1-butanol should not be maximized. Optimum transesterification reaction conditions were obtained when the process temperature was 110 °C, 1-butanol-to-oil molar ratio 11.3:1, eggshells amount 7.41 wt%, and process duration 11.81 h. Under these conditions, 98.78 wt% of ester yield was obtained. [ABSTRACT FROM AUTHOR]

The aim of studies was to investigate the process of enzymatic interesterification of rapeseed oil with methyl formate and to determine the influence of three independent variables on the product yield. After evaluating the effectiveness of three enzymatic preparations, the industrial preparation Lipozyme TL IM was selected for the research. Using the surface response methodology, a model describing the dependence of the yield of rapeseed methyl esters on the molar ratio of methyl formate to oil, the amount of catalyst and the duration of the process was created. The following conditions were determined in which the highest yield of rapeseed oil methyl esters was obtained: molar ratio of methyl formate to oil 40:1, process duration 60 h and 14.57% of catalyst Lipozyme TL IM from the amount of oil. Under these conditions, an 81.79% yield of rapeseed oil methyl esters was obtained. Comparative studies of the physical and chemical properties of the product obtained during the interesterification process were performed and their compliance with the requirements of conventional biodiesel standard EN 14214 was evaluated. [ABSTRACT FROM AUTHOR]

Chemical and physical properties (density, kinematic viscosity, flash point, copper strip corrosion, calorific value) of multicomponent biofuel blends, containing rapeseed oil butyl or methyl esters, biobutanol and fossil diesel fuel are discussed in this paper. Ester, water and partial glycerides contents were determinated in multicomponent biofuel blends. These properties were compared with the same properties of pure biodiesel (rapeseed oil butyl and methyl esters) and pure diesel fuel. As there are no standards for blends fuel, containing more than 7  of biocomponents, that is why, density and viscosity were evaluated according standards EN 14214 and EN 590. It is determined that the addition of butanol and rapeseed oil butyl esters should improve the cold flow properties, such as cloud point and cold filter plugging point. As rapeseed oil butyl esters were produced from high acidity rapeseed oil (4%), much attention was deviated for oxidation stability and acidity of pure rapeseed oil butylesters and it blends with butanol and diesel fuel. [ABSTRACT FROM AUTHOR]

Abstract: Environmentally friendly lubricants are desirable in many applications in which water or soil pollution is expected. The use of natural additives can enhance the renewability of environmentally friendly lubricants and makes them more attractive for users. The main purpose of this study was to investigate sage and thyme extracts as natural antioxidants in rapeseed oil. Their efficiency was investigated under accelerated oxidation and storage conditions and was estimated according to induction period, peroxide and acid number variation, kinematic viscosity and viscosity index changes, and tribological and corrosion properties. The observed results show that sage and thyme extracts have good oxidation stabilisation properties; therefore, the modification of rapeseed oil with these extracts can improve the oxidation stability of rapeseed oil both in storage and in use. [Copyright &y& Elsevier]

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A novel method of interesterification of rapeseed oil utilising methyl fomate and an enzymatic catalyst to produce biodiesel without the need for glycerol separation was researched. Using the enzyme preparation Lipozyme TL IM as a catalyst, the simultaneous processes of oil extraction from rapeseed and interesterification in-situ were investigated. Three independent variables were assessed for their interaction and impact on the yield of rapeseed methyl esters: the mass ratio of methyl formate to rapeseed, the time, and the amount of catalyst. Utilising surface response methodology, process optimisation was performed, and a model explaining the impact of independent variables on the yield of rapeseed methyl esters was developed. Lab testing has verified that the optimal process parameters have been identified, resulting in a 94.24 % rapeseed methyl ester yield. Using a 48:1 mass ratio of methyl formate to rapeseed and 23.33 % of the enzymatic catalyst in 64.5 h produced the highest yield. The reaction product contained conventional biodiesel (rapeseed methyl esters) along with mono-, di-, and triformyl glycerides. The interesterification product's physical and chemical characteristics were identified, and the resulting quality indicators were compared with the specifications of standards for biodiesel and mineral diesel fuel. [ABSTRACT FROM AUTHOR]