Search

Food waste (FW) is one of the major biomasses produced in large quantities in urban areas, which contributes to more than one-third of global greenhouse gas emissions. FW must be properly managed to minimize its environmental consequences. Hydrothermal carbonization (HTC) of FW is a promising technology compared to conventional methods. The objective of the present study is to maximize the mass yield (M Y ), higher heating value (HHV) and energy yield (E Y ) of FW by optimizing the operational variables of HTC process. Additionally, process water generated during HTC of FW under optimal conditions was evaluated for methane yield using anaerobic digestion. To optimize the HTC process, three operational variables, including solid-to-liquid (S/L) ratio, temperature, and reaction time, were manipulated using response surface methodology (RSM). According to RSM studies, the optimum operating conditions are 198.5 °C for 150 min with a 0.2 S/L ratio, resulting in M Y , HHV and E Y as 62.5%, 21.24 MJ/kg and 81.71%, respectively. Proximate and elemental analysis for the hydrochars synthesized at various operating conditions reveals that the temperature and reaction time have a significant impact on fixed carbon and carbon percentage. The anaerobic digestion results showed that the combination of process water and hydrochar, yielded a maximum cumulative methane production of 298.5 ± 16.34 mL/g COD. To mimic methane production, the modified Gompertz model was utilized. Thus, this finding contributes towards the commercialization of the HTC process to produce solid fuel (hydrochar) and provides a way to find an alternative energy source that enhances the HTC process and tackles the problem of process water disposal., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The effect of leachate (L) as a reaction medium in hydrothermal carbonization (HTC) of food waste (FW) on the thermal behaviour of the resulting hydrochar (H) was investigated. The physicochemical and structural characterization of FW hydrochar produced using leachate (FWH-L) at different process temperatures (180/210/240 °C) confirmed the improved properties over raw FW. Kinetic analysis using Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS) and Friedman methods revealed that FWH-L have a lower activation energy (E a ) than raw FW. The average E a values for raw FW by FWO, KAS and Friedman methods were 196.18, 196.85, 206.34 kJ/mol, respectively, while for FWH-L they were 127.89, 124.22 and 134.5 kJ/mol, respectively. The computed thermodynamic parameters showed that FWH-L has improved combustion behaviour. The results of FWH-L are well comparable to FW hydrochar produced using distilled water (FWH-DW). These findings demonstrated that residual ions in leachate would act as a catalyst, benefiting the HTC degradation reaction path., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)