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Terrestrial records of the last geomagnetic reversal often have few age constraints. Chronostratigraphy using suborbital-scale paleoceanic events during marine isotope stage 19 may contribute to solving this problem. We applied the method to an 8 m long, high-resolution paleomagnetic record from a loess sequence in China and revealed millennial-to-sub-centennial scale features of the Matuyama–Brunhes (MB) transition. All samples were subjected to progressive thermal demagnetization with 14–15 steps up to 650–680 °C. As a result, 96% of the samples yielded a high-quality remanent magnetization. The MB transition terminated with a 75 cm thick zone with nine polarity flips. The polarity flip zone, dated at about 779–777 ka, began between the warm events "I" and "J" and terminated at the end of the cooling event coincident with the lowest axial-dipole strength interval. Most polarity flips occurred within 70 years. The virtual geomagnetic poles (VGPs) in the upper polarity flip zone clustered in the SW Pacific region, where the MB transitional VGPs from lavas of the Hawaiian and Canary Islands and lacustrine deposits of Java also clustered. These sites were probably dominated by dipolar fields. The absence of transitional fields across polarity flips implies a short time span for averaging fields due to a thin loess-magnetization lock-in zone. The reverse-to-normal polarity reversal dated at about 778 ka in Lingtai occurred at the end of the SW Pacific VGP zone, an important key bed for MB transition stratigraphy. The reversal is a good candidate for the main MB boundary. We found an excursion at about 766 ka spanning about 1 ka. [ABSTRACT FROM AUTHOR]

The Late Paleozoic Ice Age (LPIA) was the longest-lasting icehouse in the Phanerozoic. Previous studies indicated a climate warming interval in the earliest Permian—an apex of the LPIA. To better understand hydroclimatic changes and carbon cycling within this time interval, we conducted a series of high-resolution geochemical and rock magnetic analyses, including magnetic measurements (e.g., magnetic susceptibility, anhysteretic remanent magnetization, hysteresis loops, temperature-dependent susceptibility), ratio of iron to potassium (Fe/K), and carbonate carbon isotope (δ13C carb) from a deep-marine section in South China. Calibrated to the published astronomical time scale, a negative δ13C carb excursion (−1‰) was identified during 298.4–297.9 Ma, and it was time-equivalent with the warming interval, recognized by a decrease in conodont apatite oxygen isotopes in South China, low-latitude sea-level transgression, and high-latitude deglaciation. The negative δ13C carb excursion also coincided with a magmatic pulse of the Skagerrak-Centered Large Igneous Province (LIP), indicating that the perturbation in carbon cycling is likely associated with the release of volcanic CO 2. Furthermore, cyclostratigraphic analysis on multiple paleoclimatic proxies, including ferrimagnetic susceptibility, gamma-ray, and Fe/K, suggested that the negative excursion of δ13C carb also overlapped with the maximum of the eccentricity cycle. It implied that orbital configurations may amplify the feedback of the LIP, causing this short-term warming interval. • High-resolution carbon isotope and magnetic record in the earliest Permian. • Transient climate warming interval is documented in the earliest Permian. • LIP and orbital forcing were critical drivers of the earliest Permian warming. [ABSTRACT FROM AUTHOR]

The anaerobic oxidation of methane, a key geochemical process that is involved in the cycling of sulfate and iron (oxyhydr)oxides in marine sediments, results in the formation of iron sulfides. Although ferrimagnetic iron sulfides have been identified in seepage systems, the link between iron migration and sediment magnetic properties remains poorly understood. Here, we investigate two cores from the Sea of Marmara to evaluate biogeochemical iron cycling and iron sulfide mineralogy in gas hydrate-bearing sediments. Magnetic analyses indicate the presence of greigite and pyrrhotite in a core from a hydrate-rich site with a high hydrocarbon flux, which contrasts with a lack of these minerals in a core characterized by only mild seepage. This is supported by the results of rock magnetic and scanning electron microscope analyses of the sediments. The presence of authigenic greigite is critical for assessing local redox records and together with the occurrence of monoclinic pyrrhotite may suggest specific diagenetic processes in gas hydrate environments. Our analysis demonstrates the usefulness of these ferrimagnetic minerals, with a high saturation isothermal remanent magnetization to magnetic susceptibility ratio (SIRM/χ > 15 kAm−1) and a high index of hysteresis parameters (D JH > 0.2) indicative of magnetic mineralogy changes, for evaluating variability in the intensity of seepage fluxes and for estimating gas hydrate distributions. • Two sediment cores with a similar original terrigenous source have contrasting magnetic properties. • A reducing and strong flux environment caused iron-driven AOM and formation of authigenic magnetic minerals in the sediments. • Greigite and monoclinic pyrrhotite are identified as the major magnetic minerals formed in hydrate-bearing sediments. [ABSTRACT FROM AUTHOR]

A high-precision time framework is critical for improving our understanding of three major events: the Late Ordovician mass extinction, the Hirnantian glaciation, and the Hirnantian isotopic carbon excursion (HICE). In the present study, we conducted detailed cyclostratigraphic analysis of a high-resolution (1–2-cm intervals) anhysteretic remanent magnetization series obtained from the Wanhe section in South China, covering the lower Katian through Hirnantian. Power spectra and derived average spectral misfit results show that the section records the ensemble of Milankovitch cycles with 405-kyr (long-eccentricity), 93–125-kyr (short-eccentricity), 33.8-kyr (main obliquity), and 17–22-kyr (precession) periods. The obliquity period of 33.8 ± 0.46 kyr indicates a precession constant k of 57.19 ± 0.53 arcsec/yr, a length of day of 22.37 ± 0.12 h, and an Earth–Moon distance of 375,330 ± 722 km (vs. 384,000 km today) during the Late Ordovician (445 Ma). The ratios of obliquity band power to total power reveal periodicities of 1.32 Myr for the s 4 – s 3 term and 173.4 kyr for the s 3 – s 6 term. Aided by the highly fluctuating magnetic susceptibility (MS), we recognized a series of 1.32-Myr obliquity-forced glacio-eustatic cycles with three intervals of sea-level rise and climate warming trend characterized by high MS values and two episodes of sea-level fall and climate cooling trend before the Hirnantian. The 405-kyr and subsequent 33.8-kyr calibrations produce an ~7.36-Myr floating astronomical time scale (FATS) for the studied succession, indicating that the estimated durations for the Hirnantian Stage, the worldwide Hirnantian glaciation, and the first and second phases of the Late Ordovician mass extinction were ~1225 kyr, ~830 kyr, ~440 kyr, and ~540 kyr, respectively. This work provides a reliable high-resolution time framework for further investigation of the major geological events occurred in the Late Ordovician, and improves our knowledge of Solar System behaviour and Earth–Moon history during that period. • An ~7.36 Myr ATS was constructed for the early Katian through Hirnantian. • The durations of Hirnantian Stage, glaciation and mass extinction were estimated. • Earth–Moon evolution was constrained for the Late Ordovician. • Obliquity forcing controlled the Late Ordovician glacio-eustasy. [ABSTRACT FROM AUTHOR]