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Your search keyword '"Bao, Hong-Fei"' showing total 1 results
Start Over Author "Bao, Hong-Fei" Topic rotaxanes
1 results on '"Bao, Hong-Fei"'

1. Guest exchange in a porous cucurbit[6]uril-based metal-organic rotaxane framework probed by NMR and X-ray crystallography.

Author

Wu XS, Wang XL, Zhu FL, Bao HF, Qin C, and Su ZM

Subjects
Crystallography, X-Ray, Magnetic Resonance Spectroscopy, Models, Molecular, Molecular Structure, Particle Size, Porosity, Surface Properties, Bridged-Ring Compounds chemistry, Imidazoles chemistry, Metal-Organic Frameworks chemistry, Rotaxanes chemistry
Abstract

The first CB[6]-based 3D porous metal-organic rotaxane framework is constructed by the reaction of CuCl2, terephthalic (H2BDC) and CB[6]-based [2]pseudorotaxanes ([PR44]2+·2[PF6]-) under solvothermal conditions. The structure of MORF-1 is a pillared-layer structure with 5-connected sqp topology, in which the effective free volume is 45.4% of the crystal volume. The guest molecules exchange in a single-crystal-to-single-crystal fashion, which was investigated using NMR spectroscopy and X-ray crystallography.

Published
2018
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