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The development of high‐performance X‐ray detectors requires scintillators with fast decay time, high light yield, stability, and X‐ray absorption capacity, which are difficult to achieve in a single material. Here, we present the first example of a lanthanide chalcogenide of LaCsSiS4 : 1 % Ce3+ that simultaneously integrates multiple desirable properties for an ideal scintillator. LaCsSiS4 : 1 % Ce3+ demonstrates a remarkably low detection limit of 43.13 nGyair s−1 and a high photoluminescence quantum yield of 98.24 %, resulting in a high light yield of 50480±1441 photons/MeV. Notably, LaCsSiS4 : 1 % Ce3+ exhibits a fast decay time of only 29.35±0.16 ns, making it one of the fastest scintillators among all lanthanide‐based inorganic scintillators. Furthermore, this material shows robust radiation and moisture resistance, endowing it with suitability for chemical processing under solution conditions. To demonstrate the X‐ray imaging capacity of LaCsSiS4 : 1 % Ce3+, we fabricated a flexible X‐ray detector that achieved a high spatial resolution of 8.2 lp mm−1. This work highlights the potential of lanthanide chalcogenide as a promising candidate for high‐performance scintillators. [ABSTRACT FROM AUTHOR]

Scintillators are a unique class of luminescent materials with specific applications towards radiation detection. The emitters within state‐of‐the‐art scintillators are mostly limited to bismuth, cerium, europium, thallium, lead, tungsten, etc. A shared feature of these elements is the relatively high atomic number, which is responsible for high radiation stopping power and radiation‐induced luminescence. Searching for new scintillating materials is an essential target aiming at specific applications. In this Concept article, we will discuss our recent works on the topic of "uranyl‐bearing scintillators". As a virgin territory in this field, uranyl‐bearing scintillators show intrinsic merits for designing new materials with X‐ray detection capability, that is, the large photoelectric cross‐section, high X‐ray attenuation efficiency, and high crystal density. In addition, we also present challenges in the further development of the uranyl‐bearing scintillators. [ABSTRACT FROM AUTHOR]

For the first time, we report intense X-ray scintillation enabled by a series of isotypic lanthanide (Eu and Tb) based metal–organic frameworks, initially showing a very efficient X-ray to visible light luminescence conversion. By systematic adjusting of the molar ratio of Eu3+ and Tb3+ in the same MOF structure as a traditional strategy for color-tuning in lanthanide-based photoluminescent materials, linear multicolor visualization of X-ray radiation from red to green can be facilely achieved, providing a new class of scintillating materials with continuous color tunability that can be customized for desired purposes. Moreover, these lanthanide–organic framework based scintillators exhibit excellent radiation resistance and humidity stability, in comparison with the state of the art and commercially-available X-ray scintillator, CsI:Tl. [ABSTRACT FROM AUTHOR]

Flexible X-Ray Detector, Lanthanide Chalcogenide Scintillator, Luminescence, X-Ray Imaging Keywords: Flexible X-Ray Detector; Lanthanide Chalcogenide Scintillator; Luminescence; X-Ray Imaging EN Flexible X-Ray Detector Lanthanide Chalcogenide Scintillator Luminescence X-Ray Imaging 1 1 1 08/10/23 20230814 NES 230814 B Scintillators b . Frontispiece: Emergence of a Lanthanide Chalcogenide as an Ideal Scintillator for a Flexible X-ray Detector. [Extracted from the article]

Keywords: luminescence; radiation detection; scintillators; uranium As a new area in this field, uranyl-bearing scintillators show intrinsic merits for designing new materials with X-ray detection capability, that is, a large photoelectric cross-section, high X-ray attenuation efficiency, and high crystal density. Luminescence, radiation detection, scintillators, uranium. [Extracted from the article]