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The research was aimed at providing new knowledge in the field of chemical characteristics of solid waste generated in the process of combustion of sewage sludge in fluidized bed furnaces. The research material consisted of disposed fluidized beds (DFB), sewage sludge ash (SSA) and air pollution control residues (APC) from three Polish installations for the thermal treatment of sewage sludge. Natural radionuclides as well as anthropogenic isotope 137 Cs were determined in the tested materials and the migration of a wide spectrum of trace elements to various waste fractions generated in the process of sewage sludge combustion was examined. It was observed that both radioisotopes and most of the trace elements determined accumulate in SSA and DFB, while the APC fraction contains a much smaller amount of them. The exceptions are mercury and selenium, whose volatile compounds migrate to the exhaust gas dedusting system and accumulate in the APC fraction (up to 40 mg/kg and 13 mg/kg, respectively). A potential threat from the 226 Ra isotope in SSA is identified in the context of the management of this waste in the production of building materials because the typical activity of 226 Ra in SSA collected from areas with very low Ra content in natural environment exceeds 1.5-6 times the activity of this isotope in conventional cement mixtures. When managing SSA and DFB, special attention should be paid to the content of metalloids such as As, B and Se, due to the high content of mobile forms of these elements in the mentioned materials., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Anaerobic co-digestion was conducted on the solid residues after three-phase separation of kitchen waste (KWS) and waste-activated sludge (WAS), the synergistic effects and process performance were studied during co-digestion at different ratios of KWS to WAS. KWS and WAS mix ratios of 0:1, 1:4, 1:3, 1:2, 1:1, 2:1, 3:1, 4:1 and 1:0 (based on TS). The results showed that a ratio of KWS to WAS of 1:1 got a very high methane recovery with a methane yield of 310.45 ± 30.05 mL/g VS added . The highest concentration of free ammonia among all reaction systems was only 70.23 ± 5.53 mg/L, which was not enough to produce ammonia inhibition in the anaerobic co-digestion system. However, when the KWS content exceeded 50%, methane inhibition and prolongation of the lag phase were observed due to the accumulation of volatile fatty acids (VFAs), and during the lag phase. Microbial community analysis showed that various bacterial groups involved in acid production and hydrolysis were mainly dominated by phylum Firmicutes , Chloroflexi , Proteobacteria and Bacteroidetes . Hydrogenotrophic methanogen was found to dominate all archaeal communities in the digesters. Co-digestion of KWS with WAS significantly increased the relative abundance of Methanobacterium compared with anaerobic digestion of WAS alone., Competing Interests: The authors declare there is no conflict., (© 2024 The Authors This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY-NC-ND 4.0), which permits copying and redistribution for non-commercial purposes with no derivatives, provided the original work is properly cited (http://creativecommons.org/licenses/by-nc-nd/4.0/).)

Organic fraction of municipal solid waste (OFMSW) and waste activated sludge (WAS) are the most produced organic waste streams in urban centres. Their anaerobic co-digestion (AcoD) allows to generate methane (CH 4 ) and digestate employable as renewable energy source and soil amendment, respectively, fully in accordance with circular bioeconomy principles. However, the widespread adoption of such technology is limited by relatively low CH 4 yields that fail to bridge the gap between benefits and costs. Among strategies to boost AcoD of OFMSW and WAS, use of conductive materials (CMs) to promote interspecies electron transfer has gained increasing attention. This paper presents one of the few experimental attempts of investigating the effects of four different carbon(C)-based CMs (i.e., granular activated carbon - GAC, graphite - GR, graphene oxide - GO, and carbon nanotubes - CNTs) separately added in semi-continuous AcoD of OFMSW and thickened WAS. The presence of C-based CMs has been observed to improve CH 4 yield of the control process. Specifically, after 63 days of operation (concentrations of GAC and GR of 10.0 g/L and of GO and CNTs of 0.2 g/L), 0.186 NL/g VS , 0.191 NL/g VS , 0.203 NL/g VS , and 0.195 NL/g VS of CH 4 were produced in reactors supplemented with GAC, GR, GO, and CNTs, respectively, compared to 0.177 NL/g VS produced in the control process. Likewise, at the end of the test (i.e., after 105 days at concentrations of C-based CMs half of the initial ones), CH 4 yields were 0.193 NL/g VS , 0.201 NL/g VS , 0.211 NL/g VS , and 0.206 NL/g VS in reactors supplemented with GAC, GR, GO, and CNTs, respectively, compared to 0.186 NL/g VS of the control process. Especially with regard to GR, GO, and CNTs, results obtained in the present study represent a significant advance of the knowledge on the effects of such C-based CMs to realistic and scalable AD process conditions respect to previous literature., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Compared to typical anaerobic digestion processes, little is known about both sludge microbial compositions and biogas production models for full-scale dry methane fermentation treating municipal solid waste (MSW). The anaerobic sludge composed of one major hydrogenotrophic methanogen (Methanoculleus) and syntrophic acetate oxidizing bacteria (e.g., Caldicoprobacter), besides enrichment of MSW degraders such as Clostridia. The core population remained phylogenetically unchanged during the fermentation process, regardless of amounts of MSW supplied (∼35 ton/d) or biogas produced (∼12000 Nm 3 /d). Based on the correlations observed between feed amounts of MSW from 6 days in advance to the current day and biogas output (the strongest correlation: r = 0.77), the best multiple linear regression (MLR) model incorporating the temperature factor was developed with a good prediction for validation data (R 2  = 0.975). The proposed simple MLR method with only data on the feedstock amounts will help decision-making processes to prevent low-efficient biogas production., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

To support smart cities in terms of waste management and bioenergy recovery, the co-digestion of sewage sludge (SeS) and food waste (FW) was conducted by the anaerobic membrane bioreactor (AnMBR) under mesophilic and thermophilic conditions in this study. The biogas production rate of the thermophilic AnMBR (ThAnMBR) at the SeS to FW ratio of 0:100, 75:25, 50:50 and 100:0 was 2.84 ± 0.21, 2.51 ± 0.26, 1.54 ± 0.26 and 1.31 ± 0.08 L-biogas/L/d, inconspicuous compared with that of the mesophilic AnMBR (MeAnMBR) at 3.00 ± 0.25, 2.46 ± 0.30, 1.63 ± 0.23 and 1.30 ± 0.17 L-biogas/L/d, respectively. The higher hydrolysis ratio and the poorer rejection efficiencies of the membrane under thermophilic conditions, resulting that the permeate COD, carbohydrate and protein of the ThAnMBR was higher than that of the MeAnMBR. The lost COD that might be converted into biogas was discharged with the permeate in the ThAnMBR, which was partly responsible for the inconspicuous methanogenic performance. Furthermore, the results of energy recovery potential assessment showed that the energy return on investment (EROI) of the MeAnMBR was 4.54, 3.81, 2.69 and 2.22 at the four SeS ratios, which was higher than that of the ThAnMBR at 3.29, 2.97, 2.02 and 1.80, respectively, indicating the advantage of the MeAnMBR over the ThAnMBR in energy recovery potential. The outcomes of this study will help to choose a more favorable temperature to co-digest SeS and FW to support the construction of smart cities., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

The European Central Bank is striving to find environmentally friendly alternative methods of waste disposal. In 2020, it decided to end the disposal of Waste Euro Banknotes (W€B) in landfills and planned to use them for recycling and/or energy recovery. Despite being recognized as an effective tool in a circular economy model, there are no reported studies on the use of W€B as a substrate in anaerobic digestion (AD). Thus, the aim of this research was to assess the viability of W€B to be converted into high-value-added energy products (mainly methane) through AD. W€B (€10 and €20 denominations) provided by the Bank of Spain were used. Biochemical methane potential (BMP) tests of pre-treated (grinded) and untreated W€B were assessed at mesophilic temperature. The ultimate methane yield was considerably higher for pre-treated W€B (334 ± 23 NmL CH 4 g VS -1 added ) than for untreated W€B (297 ± 14 NmL CH 4 g VS -1 added ). The Logistic or Sigmoidal kinetic model adequately fit the experimental data and allowed for obtaining the kinetic parameters of each case studied. In this sense, an increase of 22.4 % in the maximum methane production rate (R max ) was observed for the pre-treated W€B (52.5 ± 0.9 mL CH 4 (g VS·d) -1 compared to the untreated W€B (16.2 ± 1.8 mL CH 4 (g VS·d) -1 ). According to the obtained results, AD may be a good alternative for the energetic valorization and recycling of W€B., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

This research aimed at evaluating optimal conditions to obtain value-added metabolites, such as bio-CH 4 , by co-digesting swine manure and food waste diluted in domestic sewage. The assays were carried out in batches using the statistical methods of Rotational Central Composite Design (RCCD) and Surface Response to evaluate the ranges of food waste (1.30-9.70 gTS.L -1 ), pH (6.16-7.84) and granular Upflow Anaerobic Sludge Blanket sludge as inoculum (2.32-5.68 gTS.L -1 ), besides about 250 mL of swine manure in 500 mL Duran flasks. According to the RCCD matrix, bio-CH 4 yields among 600.6 ± 60.1 and 2790.0 ± 112.0 mL CH 4 gTS.L -1 were observed, besides the maximum CH 4 production rate between 0.4 ± 0.5 and 49.7 ± 2.0 mL CH 4 h -1 and λ between ≤0.0 and 299.3 ± 4.5 h. In the validation assay, the optimal conditions of 9.98 gTS.L -1 of food waste, pH adjusted to 8.0 and 2.20 gTS.L -1 of inoculum were considered, and the bio-CH 4 yield obtained (5640.79 ± 242.98 mL CH 4 gTS.L -1 or also 5201.83 ± 224.07 mL CH 4 gTVS.L -1 ) was 11.3 times higher than in assays before optimization (499.3 ± 16.0 mL CH 4 gTS.L -1 ) with 5 gTS.L -1 of food waste, 3 gTS.L -1 of inoculum and pH 7.0. Besides, the results observed about the energetic balance of the control and validation assays highlight the importance of process optimization, as this condition was the only one with energy supply higher than the energy required for its operation, exceeding max consumption sevenfold. Based on the most dominant microorganisms (Methanosaeta, 31.06%) and the metabolic inference of the validation assay, it could be inferred that the acetoclastic methanogenesis was the predominant pathway to CH 4 production., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Among the waste generated at oil refineries, secondary sludge from biological wastewater treatment processes (activated sludge systems) stands out. This paper aimed to assess the use of anaerobic digestion (AD) to treat sludge by SWOT (Strength, Weakness, Opportunity, and Threat) analysis, ranking the different factors based on sustainability criteria. Additionally, the SWOT factors were matched (TOWS matrix) to help interpret the results. AD was found to be compatible with sustainability. The results demonstrated that the strength of AD (reduced organic load) compensates for its weaknesses (need for operational control and initial implementation costs), thereby avoiding the threat (sludge composition) and making the most of the opportunity (lower disposal cost). AD and co-digestion (added with food waste) used to treat oil refinery sludge showed that around 60% of the factors analyzed were confirmed experimentally. It was concluded that AD should be considered in the sustainable treatment of oil refinery waste activated sludge, especially when mixed with other readily biodegradable wastes.

Anaerobic digestion is a promising method to recover energy from waste, but the slow rate of fermentation hinders its application. Yeast pre-fermentation has been reported to enhance organic matter solubilization and ethanol production to promote syntrophic metabolism and methanogenesis. However, the pre-fermentation with yeast has not been optimized so far. In this study, the lab-scale experiment was conducted to optimize operational conditions, and a pilot-scale study was conducted to evaluate the combined strategy of yeast pre-fermentation and biochar supplementation. Results demonstrated that at a fermentation time of 6 h, temperature of 30 °C, and dry yeast dosage of 2‰, the highest ethanol production was achieved, which accounted for 6.2% of the total COD of pre-fermentation effluent of a mixture of waste-activated sludge and food waste. The methane yield of the pre-fermented waste averaged 161.3 mL/g VS/d, which was 18.7% higher than that of the control group without the yeast inoculation (135.8 mL/g VS/d). With supplementing biochar of 0.5 and 1 g/L, the average methane production was 27.8% and 36.4% higher than the control group, respectively. The volatile solid removal rate was over 10% higher than the control (58.2 ± 3.12%). Consistently, the electrochemical properties of sludge with biochar were significantly improved. A pilot-scale experiment further showed that the methane production with the yeast pre-fermentation and biochar supplementation reached 227 mL/g VS/d, 54.3% higher than that without yeast pre-fermentation and biochar. This study provided a feasible method to combine yeast pre-fermentation and biochar supplementation under optimal conditions, which effectively increased methane production during anaerobic digestion of organic waste., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Inc.)

Anaerobic co-digestion (AcoD) is a vital technology in the decarburization of the economy because of its ability to process organic waste, recover nutrients, and create biogas as a sustainable biofuel all at the same time. This attribute also makes this technology a viable partner in pursuing a circular economic model. However, the poor biogas output of typical substrates like sewage sludge and animal manure and the hefty installation costs limit its viability. This review paper with literature analysis provides a good grasp of the anaerobic co-digesting process with diverse food digestion methods. In this survey, we have analyzed the Anaerobic Digestion of water waste, food waste, and animal manure and the anaerobic co-digestion of animal waste with water waste and food waste with water waste. This analysis demonstrates that anaerobic co-digestion produces more methane biogas than anaerobic digestion. Also, it has been shown that by adjusting the ratio of food and animal waste to water waste, we can produce more methane. In the future, we would like to supplement anaerobic co-digestion by altering the proportion of different wastes that are mixed with water waste in order to increase methane production., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Anaerobic co-digestion (co-AD) of sewage sludge (SS) and food waste (FW) converts municipal organic waste into renewable energy, which plays an important role in achieving carbon emissions reduction. The existing anaerobic digestion (AD) treatment projects often have problems such as low organic conversion and unstable performance. SS and FW were used as raw materials to explore the effects of thermal hydrolysis pretreatment (THP) and mixing ratios on the dewaterability and rheological properties of the digestate. The results showed that co-digestion of FW and SS in a ratio of 1:1 obtained the highest biogas production (255.14 mL/g VS), which was 1.53 times and 14.5 times higher than that of mono-digestion of FW and thermal hydrolysis pretreatment sewage sludge (THSS), respectively. However, the dewaterability of this ratio deteriorated sharply after co-digestion, with a decrease of 54.92%. The groups containing a higher proportion of THSS had improved dewaterability after AD. The apparent viscosity and shear stress were reduced by co-digestion compared with mono-digestion of THSS and FW, indicating a higher flow property of the co-digestion matrix. After the Herschel-Bulkley model fitting, there were linear correlations between rheological indices and soluble chemical oxygen demand (SCOD), and digestate dewaterability.

The impact of food waste (FW) composition on co-fermentation performance was studied to elucidate if adjusting FW composition can be used to drive the fermentation yield and profile, which is relevant for biorefinery applications. First, the impact of individual FW components (i.e., fruit, vegetables, pasta, rice, meat, fish, and cellulose) was assessed. Subsequently, the effect of mixing a protein-rich component and a carbohydrate-rich component was studied (i.e., fish/fruit and fish/cellulose, and meat/rice and meat/vegetable). All experiments were carried out in mesophilic batch assays using waste activated sludge (WAS) as main substrate, the same mixture ratio (70 % WAS +30 % FW on VS basis), and no pH control. Results showed that each FW component had a distinct effect on VFA yield and profile, with protein-rich components reaching the highest VFA yields; 502 and 442 mgCOD/gVS for WAS/Fish and WAS/Meat, respectively. A positive interaction on VFA yield was observed when mixing a protein-rich and a carbohydrate-rich component. This interaction was not proportional to the co-substrates proportion in the mixtures. On the other hand, the VFA profile was clearly driven by the components in the mixture, including both WAS and FW composition. Overall, these results indicate that predicting the VFA yield of WAS/FW co-fermentation is not just related to FW composition, but FW composition could be used to adjust the VFA profile to a certain extent., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 The Authors. Published by Elsevier B.V. All rights reserved.)

Food waste (FW) is a primary constituent of solid waste and its adequate management is a global challenge. Instead of disposal in landfills, integrated treatment of FW with wastewater (WW) can diminish both environmental and economic burdens. Utilizing steady-state modelling and life cycle assessment techniques, this study investigated the prospects of FW integration with biological WW treatment in terms of WW treatment performance, net energy and carbon footprint and economics of the process. The explored scenarios include co-disposal and treatment with WW by using FW disposers and anaerobic co-digestion with sewage sludge in Hong Kong. Compared to the existing WW and FW treatment, the integrated scenarios significantly improved the energy balance (~83-126%), net greenhouse gas emissions (~90%), and economics of operation, with permissible impact on WW treatment performance. Therefore, utilizing the surplus capacity of the existing WW treatment facilities, these integrated scenarios are a promising solution for sustainable development., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

A one-stage anaerobic ammonium oxidation (ANAMMOX) reactor can be quickly started within 40 days by mixing partial nitrifying sludge with ANAMMOX granular sludge with an average temperature of 30 °C. After 70 days of nitrogen load acclimation, Acinetobacter, including Candidatus Kuenenia, became the dominant strain of the system within the reactor, which exhibited high efficiency and a stable nitrogen removal performance. At an influent chemical oxygen demand (COD), NH 4 -N content, total nitrogen (TN) content, hydraulic retention time (HRT), temperature, and reactor dissolved oxygen (DO) content of 100, 60, and 70 mg/L, 6 h, 30 ± 1 °C, and below 0.6 mg/L, respectively, the one-stage ANAMMOX reactor could effectively treat domestic sewage on campus. The removal rates of COD, NH + -N content, total nitrogen (TN) content, hydraulic retention time (HRT), temperature, and reactor dissolved oxygen (DO) content of 100, 60, and 70 mg/L, 6 h, 30 ± 1 °C, and below 0.6 mg/L, respectively, the one-stage ANAMMOX reactor could effectively treat domestic sewage on campus. The removal rates of COD, NH 4 + -N, and TN were approximately 89%, 96.7%, and 70%, respectively.

Semi-aerobic aged refuse biofilters (SAARB) are known to efficiently remove organic matter, nitrogenous substances, and anions from landfill leachate. However, long-term recirculation of mature landfill leachate inevitably leads to accumulation of pollutants and decreases treatment capacity. In this study, the washing action provided by domestic sewage was used to recover and even enhance the treatment performance of SAARBs treating mature landfill leachate. Three SAARB columns were operated for 300 d after which a "Recirculation-Washing-Recirculation" sequence was followed. In the first recirculation period (22 d), removal of chemical oxygen demand (COD) and total nitrogen (TN) decreased from ca. 90% and 60%, respectively, initially to about 75% and less than 20%, respectively. Thereafter, washing (20 d) of the SAARBs was accomplished by applying domestic sewage. In the subsequent second recirculation period (30 d), the SAARBs were operated at the same hydraulic loading as used initially, but achieved high (ca. 90%) COD and relatively high (ca. 59%-76%) TN removal, including degradation of refractory organic matter such as humic- and fulvic-like substances. Overall, the mechanisms of the treatment performance recovery (including organics degradation and nitrification-denitrification) using domestic sewage can be attributed to three main effects: (1) some accumulated pollutants were washed out, thereby leading to recovery of the adsorption ability of aged refuse; (2) the inhibition of bio-refractory organics stress on microbial activities was mitigated by domestic sewage washing; and (3) the wash out of some accumulated salts (e.g., chloride and sulfate ions) probably helped the microbial activity recover., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

This work proposes a new treatment approach involving both food waste disposal and sewerage treatment called MOWFAST i.e. Municipal Organic Waste management by combined Food waste disposal and Sewerage Treatment. MOWFAST involves mixing of food waste directly with raw sewage instead of separate addition to sludge and their combined anaerobic digestion (AD). Compared to conventional sludge digestion, MOWFAST exhibited better digestion capability and allowed a greater degradation of organic material along with higher production of methanogenic-favourable products from the beginning of digestion. This resulted in producing higher specific methane yields (7.86 LCH 4 /kg VS added versus 0.95 LCH 4 /kg VS added ) and 1.4-fold higher cumulative methane yield over sludge AD. Furthermore, compared with conventional food waste-sludge co-digestion, MOWFAST gave higher solubilization of organic material (0.82 g sCOD/g VS added versus 0.23 g sCOD/g VS added ) and specific methane yields (7.86 LCH 4 /kg VS added versus 3.2 LCH 4 /kg VS added ). This proves its feasibility for digestion and methane generation potential., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

This study evaluated the effects of sludge lysate (SL) on the anaerobic bioreduction of Cr(VI) and the role of sludge humic acid (SHA) during this process. The results showed that supplement of SL significantly enhanced the efficiency of Cr(VI) bioreduction by 29.61%, in 12 h compared with that of the control without SL. Moreover, SHA exhibited promoting effects on bioreduction of Cr(VI), and the promotion increased with increasing SHA concentrations from 100 to 300 mg/L. In the presence of 300 mg/L SHA, Cr(VI) (98.21 mg/L) was completely reduced after 24 h with a removal rate increased by 34.3% compared with that of the control without SHA. Further investigation on the bioaugmentation mechanism of SHA by studying the nature of SHA and the reaction mechanism between SHA and Cr(VI) revealed that SHA exhibited a strong adsorption ability, which could adsorb and combine with Cr(VI). The adsorption capacity of Cr(VI) by SHA was calculated as 34.4 mg/g with 0.2 g of SHA and 10 mg/L of Cr(VI). It could also act as redox mediators to accelerate the electron transfer between microorganisms and Cr(VI) to promote reduction of Cr(VI). Furthermore, the effects of SL on the microbial community compositions of the anaerobic Cr(VI) bioreduction system were studied. Brachymonas was the primary bacteria at the genus level. The abundance of electroactive bacteria, such as Acinetobacter, Pseudomonas, and Arcobacter, increased in the SL-amended system. These findings expand the versatility of SL and justify wider use of residual activated sludge, which might contribute to the treatment of heavy metal-contaminated wastewater.

Trace elements (TEs) play an indispensable role in enhancing the stability of anaerobic digestion (AD) of food waste (FW). Significant research on AD of FW with TE supplementation has been conducted with low Fe content inoculum. However, the use of Fe-rich inoculum is inevitable due to chemical phosphorous removal from wastewater in North America. We conducted comprehensive mesophilic batch tests to investigate the effect of TEs (Fe, Ni, Co, Se, and Mo) on FW digestion inoculated with Fe-rich sludge (≥ 1000 mg Fe L -1 ). This paper presents the impact of supplementing various concentrations of TEs on specific methanogenic activity (SMA), maximum specific methane production rate (SMPR max ), and apparent hydrolysis rate constant (K h ). The addition of TEs adversely impacted methanogenic activity by 20 to 58% in the SMA tests. The effects of individual and mixed supplementation of TEs on the SMPR max and K h during FW digestion were negligible; exceptions include Fe, Mo, and Co. Final soluble TE concentrations were 10-29% of the initial soluble TEs. The high Fe concentration in the inoculum reduces the bioavailable fraction of added TEs via coprecipitation. Contrary with many literature reports indicating the need to supplement TE to improve FW digestion efficiency, with Fe-rich sludges, FW digestion does not require TE supplementation.

The codigestion of different wastes is a promising concept to improve methane generation during anaerobic processes. However, the anaerobic codigestion of catering waste leachate with algal biomass and sewage sludge has not been studied to date. The present study investigated methane generation by the anaerobic codigestion of different mixtures of catering waste leachate, microalgal biomass, and sewage sludge. Codigestion of waste mixture containing equal ratios of three substrates had 39.31% higher methane yield than anaerobic digestion of raw sludge. This was possibly because of a proliferation of methanogens during the codigestion period, induced by multiphase digestion of different wastes with different degrees of digestibility. Therefore, codigestion of catering waste leachate, microalgal biomass, and sewage sludge appears to be an efficient technology for energy conversion from waste resources. The scientific application of this codigestion technology with these three substrates may play a role in solving important environmental issues of waste management.

The co-pyrolysis technology was applied to municipal sewage sludge (MSS) and hazelnut shell with alkaline activating agent K 2 CO 3 under N 2 atmosphere. The innovative bio-char produced by co-pyrolysis had significant physical and chemical characteristics. The specific surface area reached 1990.23 m 2 /g, and the iodine absorption number was 1068.22 mg/g after co-pyrolysis at 850 °C. Although hazelnut shell was a kind of solid waste, it also had abundant cellulose resource, which could contribute to porous structure of bio-char during co-pyrolysis with MSS and decrease total heavy metals contents of raw material to increase security of bio-chars. Meanwhile, the residual fractions of heavy metals in bio-char were above 92.95% after co-pyrolysis at 900 °C except Cd to prevent heavy metals digestion, and the bio-char presented significant immobilization behavior from co-pyrolysis technology. Moreover, the yield and the iodine absorption number of bio-chars under different process variables were analyzed, and it was confirmed that appropriate process variables could contribute the yield and the iodine absorption number of bio-char and prevent to etch pore structure excessively to collapse. The changes of surface functional groups and crystallographic structure before and after co-pyrolysis were analyzed by FTIR and XRD, respectively. The hierarchical porous structure of bio-char was presented by SEM and N 2 adsorption-desorption isotherm. The Cu(II) adsorption capacity of the bio-char was 42.28 mg/g after 24 h, and surface functional groups acted as active binding sites for Cu(II) adsorption. Langmuir model and pseudo-second-order model can describe process of Cu(II) adsorption well.

Ever increasing volumes of biosolids (treated sewage sludge) are being produced by municipal wastewater facilities. This is a consequence of the continued expansion of urban areas, which in turn require the commissioning of new treatment plants or upgrades to existing facilities. Biosolids contain nutrients and energy which can be used in agriculture or waste-to-energy processes. Biosolids have been disposed of in landfills, but there is an increasing pressure from regulators to phase out landfilling. This article performs a critical review on options for the management of biosolids with a focus on pyrolysis and the application of the solid fraction of pyrolysis (biochar) into soil.

A greenhouse experiment was performed to investigate the feasibility of sewage sludge modified by coal gasification slag pretreatment and electron beam irradiation in soil application for cultivation of Alhagi sparsifolia Shap . The results showed that modified sewage sludge had an active effect on the growth of Alhagi sparsifolia Shap . The sandy soil and modified sludge at the volume ratio of 2:1 were optimal, and the growth potential of Alhagi sparsifolia Shap . was highest. In the sandy soil, the values of bioconcentration factor of most heavy metals were below 1.0 except for Zn and Cu. The average bioconcentration factor values of heavy metals in Alhagi sparsifolia Shap . decreased in a sequence of Zn>Cu>Ni> Mn>Co>Pb>Cr>Fe>V>Cd>Mo for all treatments. Alhagi sparsifolia Shap . could decrease the eco-toxicity and bioavailability of Ni, Fe, and Mo in all mixed soil, and Alhagi sparsifolia Shap . could reduce the eco-toxicity and bioavailability of all heavy metals discussed in this study (except for Mn) in the mixed soil of SS:MSS = 2:1.

Anaerobic codigestion has been practiced at water resource recovery facilities to increase methane production, but the impact of many variables is still not well understood. In this study, the feasibility of codigesting fats, oils, and grease (FOG), and other high strength wastes (HSWs) with municipal sewage sludge was investigated. Four laboratory-scale digesters were operated at a working volume of 9.75 L, 15 days solids retention time (SRT), and at a temperature of 37 °C. Wastes including whey (cheese), juice, grease trap waste (GTW), and dissolved air flotation waste (DAF), along with municipal sewage sludge, were fed to the digesters in varying amounts. The addition of HSWs led to higher methane production at lower organic loadings. However, at higher organic loadings, the GTW appeared to be toxic to methanogens, leading to a decrease in digester pH and biogas production, and an accumulation of volatile fatty acids within the digester.

The aim of this study was to assess the biogas production generated by the anaerobic co-digestion of two co-substrates-liquid cheese whey (LCW) and beef cattle waste (BCW)-mixed with the organic fraction of municipal solid waste (OFMSW) and inoculated with either granular or suspended sludge. At the end of co-digestion, a high biogas yield was observed for the granular sludge mixture of OFMSW and BCW, which provides support for beef cattle waste as a promising substrate for biogas production. The mixture of OFMSW and LCW resulted in an enhancement of biogas production compared to OFMSW alone; however, the characteristics of LCW led to instability during the process. The key finding was that the type of sludge used influences the biogas production of the mixture. For the two sludges tested, the reactors containing granular sludge produced more biogas than those with suspended sludge. Reactors inoculated with a granular sludge produced 70% more biogas with the mixture of OFMSW and BCW compared to those with the suspended sludge. The OFMSW and LCW mixture with granular sludge produced 16% more biogas than with the suspended sludge.

High solid anaerobic digestion (HSAD) is a rapidly developed anaerobic digestion technique for treating municipal sludge, and has been widely used in Europe and Asia. Recently, the enhanced HSAD process with thermal treatment showed its advantages in both methane production and VS reduction. However, the understanding of the microbial community is still poor. This study investigated microbial communities in a pilot enhanced two-stage HSAD system that degraded waste activated sludge at 9% solid content. The system employed process "thermal pre-treatment (TPT) at 70 °C, thermophilic anaerobic digestion (TAD), and mesophilic anaerobic digestion (MAD)". Hydrogenotrophic methanogens Methanothermobacter spp. dominated the system with relative abundance up to about 100% in both TAD and MAD. Syntrophic acetate oxidation (SAO) bacteria were discovered in TAD, and they converted acetate into H₂ and CO₂ to support hydrogenotrophic methanogenesis. The microbial composition and conversion route of this system are derived from the high solid content and protein content in raw sludge, as well as the operational conditions. This study could facilitate the understanding of the enhanced HSAD process, and is of academic and industrial importance., Competing Interests: The authors declare no conflict of interest.

A Life Cycle Assessment (LCA) was applied to compare different alternatives for sewage sludge treatment: such as land spreading, composting, incineration, landfill and wet oxidation. The LCA system boundaries include mechanical dewatering, the alternative treatment, transport, and final disposal/recovery of residues. Cases of recovered materials produced as outputs from the systems, were resolved by expanding the system boundaries to include avoided primary productions. The impact assessment was calculated using the CML-IA baseline method. Results showed that the incineration of sewage sludge with electricity production and solid residues recovery collects the lowest impact indicator values in the categories human toxicity, fresh water aquatic ecotoxicity, acidification and eutrophication, while it has the highest values for the categories global warming and ozone layer depletion. Land spreading has the lowest values for the categories abiotic depletion, fossil fuel depletion, global warming, ozone layer depletion and photochemical oxidation, while it collects the highest values for terrestrial ecotoxicity and eutrophication. Wet oxidation has just one of the best indicators (terrestrial ecotoxicity) and three of the worst ones (abiotic depletion, human toxicity and fresh water aquatic ecotoxicity). Composting process shows intermediate results. Landfill has the worst performances in global warming, photochemical oxidation and acidification. Results indicate that if the aim is to reduce the effect of the common practice of sludge land spreading on human and ecosystem toxicity, on acidification and on eutrophication, incineration with energy recovery would clearly improve the environmental performance of those indicators, but an increase in resource depletion and global warming is unavoidable. However, these conclusions are strictly linked to the effective recovery of solid residues from incineration, as the results are shown to be very sensitive with respect to this assumption. Similarly, the quality of the wet oxidation process residues plays an important role in defining the impact of this treatment., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

The release rule of phosphorus from sewage sludge during ozonation and removal by the magnesium ammonium phosphate (MAP) method were investigated. The results showed that the concentrations of total phosphorus in aqueous phase (TP (A) ) and orthophosphate (PO 4 3- -P) in ozonized sludge supernatant rose obviously with increasing ozone dose when ozone dose was below 61.2 mg O 3 /gSS then almost kept constant. The TP (A) and PO 4 3- -P contents in the ozonized sludge supernatant were 70.9 and 63.3 mg/L when ozone dose was 61.2 mg O 3 /gSS, respectively. Total phosphorus in the sludge solid (TP (S) ) was mostly distributed in inorganic phosphorus (IP) (more than 81.5% of TP (S) ), and non-apatite inorganic phosphorus (NAIP) was the major component of IP in the sludge (more than 78.7% of IP) during ozonation. The release contribution (RC) of IP to TP (A) accounted for over 73.9%. The optimized conditions for the removal of phosphorus from ozonized sludge supernatant were set at an initial Mg 2+ /PO 4 3- -P molar ratio of 1.8, pH 9.5, and reaction time of 5 min, under which the removal efficiencies of TP (A) and PO 4 3- -P were 43.1 and 52.2%, respectively.

In this study, an integrated two-stage system, including the in-situ catalytic microwave pyrolysis (ICMP) and subsequent catalytic wet oxidation (CWO) processes, was proposed to remove H 2 S released from microwave-induced pyrolysis of sewage sludge. The emission profile and H 2 S removal from the pyrolysis of raw sewage sludge (SS) and sewage sludge spiked with conditioner CaO (SS-CaO) were investigated. The results showed that CaO played a positive role on sulfur fixation during the pyrolysis process. It was found that SS-CaO (10 wt.%) contributed to about 35% of H 2 S removal at the first stage (ICMP process). Additionally, the CWO process was demonstrated to have promising potential for posttreatment of remaining H 2 S gas. At the Fe 3+ concentration of 30 g/L, the maximum H 2 S removal efficiency of 94.8% was obtained for a single Fe 3+ /Cu 2+ solution. Finally, at the pyrolysis temperature of 800 °C, 99.7% of H 2 S was eliminated by the integrated two-stage system meeting the discharge standard of China. Therefore, the integrated two-stage system of ICMP + CWO may provide a promising strategy to remove H 2 S dramatically for the biomass pyrolysis industry.

It is well recognized that management of wastewater and sludge is a critical environmental issue in many countries. Wastewater treatment and sludge production take place under different technical, economic, and social contexts, thus requiring different approaches and involving different solutions. In most cases, a regular and environmentally safe wastewater treatment and associated sludge management requires the development of realistic and enforceable regulations, as well as treatment systems appropriate to local circumstances. The main objective of this paper is to provide useful information about the current wastewater and sludge treatment, management, regulations, and research in Oman. Based on the review and discussion, the wastewater treatment and sludge management in Oman has been evolving over the years. Further, the land application of sewage sludge should encourage revision of existing standards, regulations, and policies for the management and beneficial use of sewage sludge in Oman., Implications: Wastewater treatment and sludge management in Oman have been evolving over the years. Sludge utilization has been a challenge due to its association with human waste. Therefore, composting of sewage sludge is the best option in agriculture activities. Sludge and wastewater utilization can add up positively in the economic aspects of the country in terms of creating jobs and improving annual income rate. The number of research projects done on wastewater reuse and other ongoing ones related to the land application of sewage sludge should encourage revision of existing standards, regulations, and policies for the management and beneficial use of sewage sludge in Oman.

Sewage sludge derived biochar (SSDB) was used as a supplementary material for municipal sewage sludge (SS) and wood chips mixtures (WC) treated by combined composting and vermicomposting. SSDB added to the mixture before composting resulted in significantly higher reproduction rate: on week 4 the number of cocoons increased by 213% when compared to the mixture with no biochar. On week 6 the average number of juveniles increased 11-fold in the mixture with biochar added before composting and 5-fold in the mixtures with biochar added after composting when compared to the mixture with no biochar. Biochar added before composting reduced bioavailability of Cd and Zn to E. fetida. The biochar-added vermicomposts showed good fertilizing properties except for elevated concentrations of Cr. The pH of all vermicomposts was in the range of 5.27-5.61. The obtained vermicomposts can be used as a growing medium for horticultural purposes or as an amendment in calcareous soils., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Sludge is an important source of greenhouse gas (GHG) emissions, both in the form of direct process emissions and as a result of indirect carbon-derived energy consumption during processing. In this study, the carbon budgets of two sludge disposal processes at two well-known sludge disposal sites in China (for biodrying and heat-drying pretreatments, both followed by mono-incineration) were quantified and compared. Total GHG emissions from heat drying combined with mono-incineration was 0.1731 tCO 2 e t -1 , while 0.0882 tCO 2 e t -1 was emitted from biodrying combined with mono-incineration. Based on these findings, a significant reduction (approximately 50%) in total GHG emissions was obtained by biodrying instead of heat drying prior to sludge incineration., Implications: Sludge treatment results in direct and indirect greenhouse gas (GHG) emissions. Moisture reduction followed by incineration is commonly used to dispose of sludge in China; however, few studies have compared the effects of different drying pretreatment options on GHG emissions during such processes. Therefore, in this study, the carbon budgets of sludge incineration were analyzed and compared following different pretreatment drying technologies (biodrying and heat drying). The results indicate that biodrying combined with incineration generated approximately half of the GHG emissions compared to heat drying followed by incineration. Accordingly, biodrying may represent a more environment-friendly sludge pretreatment prior to incineration.

The development of anaerobic digestion involves both co-digestion of solid wastes and optimization of the feeding recipe. Within this context, substrate characterisation is an essential issue. Although it is widely used, the biochemical methane potential is not sufficient to optimize the operation of anaerobic digestion plants. Indeed the biochemical composition in carbohydrates, lipids, proteins and the chemical oxygen demand of the inputs are key parameters for the optimisation of process performances. Here we used near infrared spectroscopy as a robust and less-time consuming tool to predict the solid waste content in carbohydrates, lipids and nitrogen, and the chemical oxygen demand. We built a Partial Least Square regression model with 295 samples and validated it with an independent set of 46 samples across a wide range of solid wastes found in anaerobic digestion units. The standard errors of cross-validation were 90mgO 2 ⋅gTS -1 carbohydrates, 2.5∗10 -2 g⋅gTS -1 lipids, 7.2∗10 -3 g⋅gTS -1 nitrogen and 99mgO 2 ⋅gTS -1 chemical oxygen demand. The standard errors of prediction were 53mgO 2 ⋅gTS -1 carbohydrates, 3.2∗10 -2 g⋅gTS -1 lipids, 8.6∗10 -3 g⋅gTS -1 nitrogen and 83mgO 2 ⋅gTS -1 chemical oxygen demand. These results show that near infrared spectroscopy is a new fast and cost-efficient way to characterize solid wastes content and improve their anaerobic digestion monitoring., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Alternative fertilizer resources have drawn attention in recent times in order to cope up with ever increasing demand for fertilizer. By-products of bioenergy system are considered favourable as organic fertilizer due to their ability to recycle plant nutrients. Present study evaluates fertilizer suitability of by-products of two bioenergy systems viz. 3 types of anaerobic digestion by-products (digestate) from local surplus biomass such as cowdung, Ipomoea carnea:cowdung (60:40) and ricestraw:green gram stover:cowdung (30:30:40) and one gasification by-product (biochar) from rice husk. Digestates were assessed considering 4 different application options of each viz. whole, solid, liquid and ash from solid digestates. Digestate characteristics (organic matter, macronutrients, micronutrients and heavy metal content) were found to be a function of feedstock and processing (solid liquid separation and ashing). Ipomoea carnea based digestates in all application options showed comparatively higher N, P, K, NH 4 + -N, Ca, Mg, S and micro nutrient content than other digestates. Separation concentrated plant nutrients and organic matter in solid digestates, making these suitable both as organic amendments and fertilizer. Separated liquid digestate shared larger fraction of ammonium nitrogen (61-91% of total content), indicating their suitability as readily available N source. However, fertilizer application of liquid digestate may not match crop requirements due to lower total nutrient concentration. Higher electrical conductivity of the liquid digestates (3.4-9.3mScm -1 ) than solid digestates (1.5-2mScm -1 ) may impart phyto-toxic effect upon fertilization due to salinity. In case of by-products with unstable organic fraction i.e. whole and solid digestates of rice straw:green gram stover:cowdung digestates (Humification index 0.7), further processing (stabilization, composting) may be required to maximize their fertilizer benefit. Heavy metal contents of the by-products were found to be within the permitted range specified for organic fertilizer (vermicompost) in India. However, higher Al content of the digestates in whole, solid and ash phase (0.06-16.97gkg -1 fresh matter) can be a concern in acid soil which may cause Al toxicity. Understanding on agrochemical characteristics of bioenergy by-products with varying feedstock and application option is expected to promote their valorization opportunities considering user specific requirements. In the context of agriculturally dominant but energy deficient rural Indian scenario, integrated production of bioenergy and by-product based fertilizer could be very significant to meet the critical additional requirement of both energy and fertilizer., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Solar dried sewage sludge (SS) conversion by pyrolysis and gasification processes has been performed, separately, using two laboratory-scale reactors, a fixed-bed pyrolyzer and a downdraft gasifier, to produce mainly hydrogen-rich syngas. Prior to SS conversion, solar drying has been conducted in order to reduce moisture content (up to 10%). SS characterization reveals that these biosolids could be appropriate materials for gaseous products production. The released gases from SS pyrolysis and gasification present relatively high heating values (up to 9.96 MJ/kg for pyrolysis and 8.02  9.96 MJ/kg for gasification) due to their high contents of H 2 (up to 11 and 7 wt%, resp.) and CH 4 (up to 17 and 5 wt%, resp.). The yields of combustible gases (H 2 and CH 4 ) show further increase with pyrolysis. Stoichiometric models of both pyrolysis and gasification reactions were determined based on the global biomass formula, C α H β O γ N δ S ε , in order to assist in the products yields optimization.

Aerobic pre-treatment was applied prior to two-stage anaerobic digestion process. Three different food wastes samples, namely carbohydrate rich, protein rich and lipid rich, were prepared as substrates. Effect of aerobic pre-treatment on hydrogen and methane production was studied. Pre-aeration of substrates showed no positive impact on hydrogen production in the first stage. All three categories of pre-aerated food wastes produced less hydrogen compared to samples without pre-aeration. In the second stage, methane production increased for aerated protein rich and carbohydrate rich samples. In addition, the lag phase for carbohydrate rich substrate was shorter for aerated samples. Aerated protein rich substrate yielded the best results among substrates for methane production, with a cumulative production of approximately 351ml/gVS. With regard to non-aerated substrates, lipid rich was the best substrate for CH 4 production (263ml/gVS). Pre-aerated P substrate was the best in terms of total energy generation which amounted to 9.64kJ/gVS. This study revealed aerobic pre-treatment to be a promising option for use in achieving enhanced substrate conversion efficiencies and CH 4 production in a two-stage AD process, particularly when the substrate contains high amounts of proteins., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

A two-phase digestion system for treating agricultural waste is beneficial for methane production. This study explored the effect of solid content, temperature, and mixing mode on the process of hydrolysis and acidification using rice straw and cow dung launched in non-airtight acidogenic system. The results showed that the substrate could be hydrolyzed efficiently in the initial stage, the hydrolysis coefficient (k) of maximum cellulose and hemicellulose can be increased by 217.9% and 290.5%, respectively, compared with those of middle and last stages. High solid content played a leading role in promoting hydrolysis, resulted in hydrolysate content (sCOD) that was significantly higher than in treatments with low solid content (P<0.01), and led to organic acids accumulation up to 5.8 and 6.7g/L at mesophilic and thermophilic temperatures. Thermophilic temperature stimulated the hydrolysis and acidification of low solid content (P<0.05), and improved organic acid accumulation of high solid content only during the middle stage (P<0.01). Mixing mode was not a major factor, but increasing the mixing time was necessary for organic acid accumulation during the last stage (P<0.05). In addition, the study comprehensively analyzed a series of corresponding relationships among each operating parameter during the whole treatment process using canonical correspondence analysis., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Abundant organic compounds in textile dyeing sludge (TDS) provide possibility for its anaerobic digestion (AD) treatment. However, preliminary test showed little biogas generation in direct AD of the TDS during 20days. In order to improve the AD availability of TDS, alkaline, acid, thermal and thermal alkaline pretreatments were performed. Color and aromatic amines were specifically measured as extra characteristics for the AD of TDS. The rate-limiting steps of AD of TDS were slow hydrolysis rate and inhibited acidogenesis, which were somewhat overcome by pretreatments. Thermal alkaline pretreated TDS performed best enhancement on solubilisation. The biochemical methane potential tests revealed that thermal pretreated TDS showed highest total methane production of 55.9mL/gVS fed compared to the control with little methane generation. However, thermal alkaline pretreated TDS did not perform well in BMP test as expected. Moreover, the hydrophilicity of reactive dyes in TDS could seriously affect dewaterability of TDS., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Anaerobic co-digestion of food waste with primary sewage sludge is beneficial for urban centers, while the optimized conditions reported in the literature are not locally suitable for Hong Kong. Therefore, the present study was aimed to develop an optimized mixing ratio of food waste to chemically enhanced primary-treated sewer sludge (CEPT) for co-digestion using batch tests under mesophilic (37°C) and thermophilic (55°C) conditions. The mixing ratios of 1:1, 1:2, 1:3, 2:1 and 3:1 (v v(-1)) of food waste to CEPT sludge was tested under the following conditions: temperature - 35°C and 55°C; pH - not regulated; agitation - 150 rpm and time - 20 days. The thermophilic incubations led a good hydrolysis rate and 2-12-fold higher enzyme activities than in mesophilic incubations for different mixing ratios. While the acidogenesis were found retarded that leading to 'sour and stuck' digestion for all mixing ratio of food waste to CEPT sludge from thermophilic incubations. The measured zeta potential was most favourable (-5 to -16.8 mV) for methane production under thermophilic incubations; however the CH4 recovery was less than that in mesophilic incubations. The results suggested that the quick hydrolysis and subsequent acid accumulation under thermophilic incubation lead to inhibited methanogenesis at the early stage than in mesophilic systems. It is concluded that buffer addition is therefore required for any mixing ratio of food waste to CEPT sludge for improved CH4 recovery for both mesophilic and thermophilic operations.

The objectives of the study were to compare the effects of the composting and the vermicomposting processes on the distribution of particles into three size fractions, and to assess the agrochemical properties of the size fractions of the composts and the vermicomposts. Three different mixtures of biowaste were subjected to two thermophilic pre-composting, and then the mixtures were subsequently subjected to 5months composting and vermicomposting under laboratory conditions. Vermicomposting was able to achieve the finer and more homogeneous final product compared to composting. For compost, the highest portion of the finest fraction was achieved from products which originated from kitchen waste containing used paper, followed by digestate with straw, and finally sewage sludge with garden biowaste. In most cases, compost particles which were less than 5mm exhibited the better agricultural potential than coarser compost. However, agrochemical properties of the finest vermicompost exceeded classical compost., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Combustion and pyrolysis processes were assessed and compared for two types of lignocellulosic biowastes: agricultural (Eucalyptus bark, grape seeds, peach stones, walnut shells, olive waste and peanut shells) and industrial (primary and biological paper mill sludge) biowastes. They were characterized by elemental, proximate and thermal analyses; the pyrolysis behaviour was studied by thermogravimetric analysis and the gases produced were identified using mass spectrometry. Agricultural biowastes showed the highest calorific values, close to the fossil fuel values (20-30MJkg(-1)) and, in general, emission of gases containing the carbon element (CH4, C2H2, CO and CO2) was higher than that of the tested industrial biowastes, making the agricultural biowastes highly competitive for combustion applications such as gas fuel. Further, the solid product which resulted from the pyrolysis of industrial biowastes is a material with large specific surface area, which is a good characteristic for possible applications as adsorbent in water remediation., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Electrocoagulation has recently attracted attention as a potential technique for treating toxic effluents due to its versatility and environmental compatibility, generating a residue chemically suitable to be used as a soil additive. In the present study, landfill leachate sludge hazardous effects were investigated prior and after electrocoagulation process using in vitro assays with the mammalian cells CHO-k1. An integrated strategy for risk assessment was used to correctly estimate the possible adverse landfill leachate sludge effects on human health and ecosystem. Electrocoagulation process proved to be an effective treatment due to possibility to improve effluent adverse characteristics and produce sludge with potential to be used as soil additive. Despite low cytoxicity, the residue presented genotoxic and mutagenic effects, indicating a capacity to induce genetic damages, probably due to induction of polyploidization process in cells. The observed effects demand an improvement of waste management methods for reduce negative risks of landfill leachate sludge application., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Permanently increasing in the amount of sludge resulted in the serious environment burden. This work reports a novel carbothermal process for converting the Fe-rich waste sludge into cleaner nano-flake Fenton-like catalyst to relieve the crisis. The transformation of Fe species at different carbothermal temperature was evaluated by XRD analysis. SEM and XPS analyses were involved to characterize the morphology and chemical bonds of the catalysts. Results shown that the resulted catalyst carbonized at 800 °C (Fe-SC-800) was composed of Fe(0) and Fe3O4, performing nano-flake-like structure. The Fe-SC-800 has the highest catalytic activity in degradation of AOII in C0 = 200 mg/L. The efficiency achieves at 98% within 30 min at neutral pH, which is ascribed to the hydroxyl radical oxidation. Moreover, no iron is leached and the Fe-SC-800 could be recycled for three times at least. Thus, the Fe rich sludge could be reutilized as a valuable source for eco-friendly catalyst production, constituting an ecological way to manage these sludge wastes and eliminate the sludge and organic pollution to environment., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Gum arabic is multifunctional and used in food products, pharmaceutical, confectionery, cosmetic, printing and textile industry. Gum arabic has an excellent market and its production is being increased to meet the market demand. In the process, huge quantity of solid waste is generated during its refining process. An attempt has been made to vermicompost this organic waste using Eudrilus eugeniae. This research work is first of its kind. Literature on this substrate has not been reported anywhere else for vermicomposting. Results were excellent with volatile solid reduction of 51.34 %; C/N ratio reduced to 16.31 % indicating efficient loss of carbon as carbon dioxide during vermicomposting period. Manurial value, i.e. nitrogen, phosphorus and potassium content in the range, required for the plants also increased. Porosity of 67.74 % and water holding capacity of 65.75 % were observed. The maturity of the vermicompost was evaluated through scanning electron microscopy wherein the complete conversion of large raw material particles into finer particles forming a uniform matrix with more surface area was observed indicating its efficient conversion. Microbial quality of vermicompost was also studied. The final vermicompost is free of fungal cells and pathogenic bacteria.

High-solids anaerobic digestion (HSAD), a promising method with smaller reactor and less heating energy consumption, showed relatively lower digestion efficiency sometimes and higher tolerance to some inhibitors. To investigate the phenomena, the archaeal and bacterial communities in four anaerobic digesters treating sewage sludge with total solids (TS) of 10-19% were investigated. Although acetoclastic methanogenesis conducted mainly by genus Methanosarcina was still the main pathway producing methane, the total ratio of acetoclastic methanogens decreased along with the increased TS. In contrary, the relative abundance of hydrogenotrophic methanogens increased from 6.8% at TS 10% to 22.3% at TS 19%, and methylotrophic methanogens from 10.4% to 20.9%. The bacterial community was dominated by five phyla. Acidogenic and acetogenic bacteria affiliated to Firmicutes decreased following the increase of TS; while the proteolysis phylum Bacteroidetes increased, with a tolerant family ST-12K33 notably existing in the digesters at TS 17% and 19%., (Copyright © 2016 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

By using thermogravimetric analysis (TGA), the effects of different additives (MgO, Al2O3 and ZnO) on the pyrolysis characteristics and activation energy of municipal solid waste (MSW), paper sludge (PS) and their blends in N2 atmosphere had been investigated in this study. The experiments resulted that these additives were effective in reducing the initial temperature and activation energy. However, not all the additives were beneficial to reduce the residue mass and enhance the index D. For the different ratios of MSW and PS, the same additive even had the different influences. The catalytic effects of additives were not obvious and the pyrolysis became difficult with the increase of the proportion of PS. Based on all the contrast of the pyrolysis characteristics, MgO was the best additive and 70M30P was the best ratio, respectively., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Mixed fermentative/hydrolytic bacteria were enriched on lignocellulose substrates in minimal medium under semi-anaerobic mesophilic conditions in the presence or absence of natural zeolite as growth supporter to ultimately bioaugment non-adapted sludge and thereby enhance the overall anaerobic digestion (AD) of recalcitrant plant material. Desired enzyme activities, i.e. xylanases and cellulase were monitored during subsequent cultivation cycles. Furthermore, enriched microbial communities were characterized by 16S rRNA-based 454-Pyrosequencing, revealing Firmicutes, Bacteriodetes, Proteobacteria and Spirochaetes to be the predominant bacterial groups in cultures derived from anaerobic sludge and raw crop material, i.e. maple green cut and wheat straw as well. Enriched populations relevant for biopolymer hydrolysis were then compared in biological methane potential tests to demonstrate positive effects on the biogasification of renewable plant substrate material. A significant impact on methane productivity was observed with adapted mixed cultures when used in combination with clinoptilolite to augment and supplement non-adapted bioreactor sludge., (Copyright © 2016. Published by Elsevier Ltd.)

Fat waste discarded from butcheries was used as a cosubstrate in the anaerobic codigestion of sewage sludge (SS). The process was evaluated under mesophilic and thermophilic conditions. The codigestion was successfully attained despite some inhibitory stages initially present that had their origin in the accumulation of volatile fatty acids (VFA) and adsorption of long-chain fatty acids (LCFA). The addition of a fat waste improved digestion stability and increased biogas yields thanks to the higher organic loading rate (OLR) applied to the reactors. However, thermophilic digestion was characterized by an effluent of poor quality and high VFA content. Results from spectroscopic analysis suggested the adsorption of lipid components onto the anaerobic biomass, thus disturbing the complete degradation of substrate during the treatment. The formation of fatty aggregates in the thermophilic reactor prevented process failure by avoiding the exposure of biomass to the toxic effect of high LCFA concentrations.

A leachbed is a relatively simple anaerobic digester suitable for high-solids residues and on-farm applications. However, performance characteristics and optimal configuration of leachbeds are not well-understood. In this study, two 200 L pilot-scale leachbeds fed with spent straw bedding from pigs/swine (methane potential, B0 = 195-218 L CH4 kg(-1) VS fed) were used to assess the effects of leachate recirculation mode (trickling vs. flood-and-drain) on the digestion performance. Results showed comparable substrate solubilisation extents (30-45% of total chemical oxygen demand fed) and methane conversion (50% of the B0) for the trickling and flood-and-drain modes, indicating that digestion performance was insensitive to the mode of leachate flow. However, the flood-and-drain leachbed mobilised more particulates into the leachate than the trickling leachbed, an undesirable outcome, because these particulates were mostly non-biodegradable. Inoculation with solid residues from a previous leachbed (inoculum-to-substrate ratio of 0.22 on a VS basis) hastened the leachbed start-up, but methane recovery remained at 50% of the B0 regardless of the leachate recirculation mode. Post-digestion testing indicated that the leachbeds may have been limited by microbial activity/inhibition. The high residual methane potential of leachate from the trickling (residual Bo = 732 ± 7 L CH4 kg(-1) VS fed) and flood-and-drain leachbeds (582 ± 8 L CH4 kg(-1) VS fed) indicated an opportunity for further processing of leachate via a separate methanogenic step. Overall, a trickling leachbed appeared to be more favourable than the flood-and-drain leachbed for treating spent bedding at farm-scale due to easier operation., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Unlabelled: The main objectives of this study were to investigate the compostability of wastewater treatment sludge (WTS) containing different bulking agents (BAs) and to determine the most efficient BA. Four different compost trials consisting of mixtures of wheat straw (WS), plane leaf (PL), corncob (CC) and sunflower stalk (SS) with WTS were performed in laboratory reactors. In all experiments, a mixture of 60% WTS and 40% BA (wet basis) was used. The temperature, dry matter (DM), organic matter (OM), pH, electrical conductivity (EC) and C/N ratio were monitored during the composting process. Evaluation of the operational parameters showed that the highest organic matter degradation (i.e. 37.6%), loss of dry matter (i.e. 29.6%) and temperature (i.e. 64 °C) were achieved for the WTS-CC mixtures. Results also showed that the WTS-SS mixture was also successful in terms of these operational parameters. Use of bulking agents for the treatment of wastewater treatment sludge in composting process is an important issue with regards to process efficiency, economy and disposal of agricultural waste. Corncob and sunflower stalk that were previously not used for the composting of WTS from food industry were shown to be highly successful BA materials in this study., Implications: The compostability of wastewater treatment sludge from the food industry with different bulking agents was studied. Wheat straw, plane leaf, corncob, and sunflower stalk were used as bulking agents. The required microbial stabilization and degree of mineralization were achieved with corncobs and sunflower stalks.

Anaerobic codigestion of source selected organic fraction of municipal solid waste (SS-OFMSW) and sewage sludge may be one of the most viable solutions to optimize oversized digesters efficiency in wastewater treatment plants. Based on results of BMP tests obtained for sewage sludge and SS-OFMSW, pilot plant tests were carried out by 3.4 m(3) CSTR reactor at mesophilic temperature. A mix of fruit and vegetable waste from wholesale market and canteen waste was used as SS-OFMSW substrate. Tests were conducted applying an OLR (organic loading rate) ramp with 6 different phases until a value of 3.2 kgVS/m(3) d. Feedstock and digestate characteristics, efficiency and process parameters were monitored. The anaerobic codigestion development was stable in each phase: early indicators like VFA (volatile fatty acids) and FOS/TAC ratio were always below instability threshold values. The maximum OLR tested determined a GPR (gas production rate) of 0.95 N m(3)/m(3) d and SGP (specific gas production) of 0.49 N m(3)/kgVS with a VS abatement of 67.3%., (Copyright © 2015 Elsevier Ltd. All rights reserved.)