Search

Taking the Lower Permian Fengcheng Formation shale in Mahu Sag of Junggar Basin, NW China, as an example, core observation, test analysis, geological analysis and numerical simulation were applied to identify the shale oil micro-migration phenomenon. The hydrocarbon micro-migration in shale oil was quantitatively evaluated and verified by a self-created hydrocarbon expulsion potential method, and the petroleum geological significance of shale oil micro-migration evaluation was determined. Results show that significant micro-migration can be recognized between the organic-rich lamina and organic-poor lamina. The organic-rich lamina has strong hydrocarbon generation ability. The heavy components of hydrocarbon preferentially retained by kerogen swelling or adsorption, while the light components of hydrocarbon were migrated and accumulated to the interbedded felsic or carbonate organic-poor laminae as free oil. About 69% of the Fengcheng Formation shale samples in Well MY1 exhibit hydrocarbon charging phenomenon, while 31% of those exhibit hydrocarbon expulsion phenomenon. The reliability of the micro-migration evaluation results was verified by combining the group components based on the geochromatography effect, two-dimension nuclear magnetic resonance analysis, and the geochemical behavior of inorganic manganese elements in the process of hydrocarbon migration. Micro-migration is a bridge connecting the hydrocarbon accumulation elements in shale formations, which reflects the whole process of shale oil generation, expulsion and accumulation, and controls the content and composition of shale oil. The identification and evaluation of shale oil micro-migration will provide new perspectives for dynamically differential enrichment mechanism of shale oil and establishing a "multi-peak model in oil generation" of shale. [ABSTRACT FROM AUTHOR]

Shale oil and gas are currently the major fields of unconventional hydrocarbon exploration and development. The Fengcheng Formation (FF) shale in the Mahu Sag of the Junggar Basin is an alkaline lacustrine organic-rich shale with an extremely prospective shale oil potential. However, its strong heterogeneity and complex pore structure greatly influence the development of shale oil. It is significant to investigate the pore and geochemical characteristics of shale reservoirs for shale oil extraction. In this study, the pore structure and geochemical characteristics of FF have been investigated using core analysis, Rock-Eval pyrolysis, X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), mercury injection capillary pressure (MICP), low-temperature gas adsorption (LTGA), and X-ray computed tomography (X-ray CT). The results show that the shale of FF has moderate organic matter abundance, and the kerogen is mainly of Type II, which is now at the peak of oil generation. Shale minerals are mainly composed of carbonate (dolomite and calcite) and siliceous (quartz and feldspar) minerals, with extremely low clay mineral content. The pore types are mainly intergranular pores (inter-P), intragranular pores (intra-P), and microfractures associated with mineral particles. The pore space is contributed predominantly by micropores of 0.5–1.2 nm and mesopores of 10–50 nm, whereas macropores are underdeveloped. The pores are mostly ink bottle- and slit-shaped, and the pore connectivity is relatively poor. The pore development of shale in the FF is influenced by organic matter abundance, thermal maturity, mineral composition, etc. Organic matter content (TOC), thermal maturity (Ro), and carbonate minerals have a positive effect on pore development, and the pore volume (PV) increases with TOC, Ro, and carbonate minerals. While clay minerals show a negative effect, the PV decreases with clay minerals. Additionally, the influence of the clay mineral content on the pore morphology of shale should not be ignored. This study investigates the pore structure and geochemical characteristics of the alkaline lacustrine shale of FF in Mahu Sag, which is significant to deepen the understanding of alkaline lacustrine shale and to improve the production of shale oil. [ABSTRACT FROM AUTHOR]

The pore structure of a carbonate reservoir determines the fluidity and storage characteristics of hydrocarbon, and it is vital for reservoir evaluation and oil and gas production. The Visean and Serpukhovian carbonate reservoirs in the Marsel exploration area of the Chu-Sarysu Basin possess a complex lithology and pore structure, which significantly affect production efficiency. The pore structure of the reservoirs was investigated in this study via X-ray diffraction, conventional petrophysical measurements, cast thin section analysis, scanning electron microscopy (SEM), imaging logging, and high-pressure mercury injection (HPMI). The findings show that the lithology in this area mainly comprises fine-grained limestone, bioclastic limestone, and silty limestone; moreover, the mineral assemblage in this region is markedly different. The types of carbonate reservoir pore spaces are complex and diverse. Primary pores are mainly biological cavity pores with small pore size, mostly isolated individuals, poor connectivity, and weak percolation capacity. Secondary dissolution pores, which are dominated by intergranular dissolution pores, intragranular dissolution pores, and microfractures, are the dominant storage spaces in the Carboniferous carbonate reservoirs. Through an innovative approach of combining imaging logging and cast thin section analysis, it was concluded that mainly three types of fractures exist, namely conductivity fractures, fissures, and resistive fractures. Moreover, structural fractures in this area are relatively developed, which substantially increases the percolation capacity of the reservoirs and it is conducive to oil and gas flow. However, some structural fractures are filled with calcite, destroying the effectiveness of the fractures and reducing the percolation capacity. Based on capillary pressure curves, the samples were divided into three types, of which the physical properties decrease in the order of type I > type III > type II. The fractal dimensions obtained from HPMI and SEM data characterize the complexity of the reservoir microstructure in the study area. The formation of high-porosity and high-permeability zones was caused by quasi-syngenetic dolomitization and syngenetic–quasi-syngenetic dissolution. In this study, the pore structure of carbonate reservoirs in the area was evaluated quantitatively, which is highly significant to improving oil and gas recovery. [ABSTRACT FROM AUTHOR]

Hydrocarbon potential evaluation is a high priority in oil/gas exploration which is significantly influenced by evaluation methods and subjective cognition. With the aim of quantitatively establishing a hydrocarbon generation and expulsion (HGE) model of source rocks, a data-driven approach is proposed based on abundant and readily available Rock-Eval/total organic carbon content (TOC)/vitrinite reflectance (VRo) datasets. This approach takes into account the original hydrocarbon generation potential (GPIo) and the loss of TOC. Hydrocarbon generation simulation was also adopted in this study. This data-driven method was applied to the Lower Paleogene Shahejie Formation (Es4), which has three sets of superior source rocks (average thickness > 250 m, TOC > 3%). The GPIo of the Es4 low-maturity source rock was 600 mg HC/g TOC. The initial maturity values of hydrocarbon generation and expulsion were 0.36% and 0.46%, respectively. The Gaosheng sub-member of the Es4 source rock had the largest amount of hydrocarbon generation but a limited amount of hydrocarbon expulsion, implying a favorable exploration of shale oil resources. By contrast, the values of the conventional, unconventional tight, and shale oil resource potentials of the Niuxintuo sub-member were 3.20 × 107, 7.70 × 107, and 5.93 × 108 t, respectively, indicating good prospects for tight oil and shale oil exploration. A comparison between the previous method and the data-driven method showed considerable differences in the restoration of GPIo and TOC, and both had their own limitations. This data-driven approach provides a quick and valid source rock evaluation method and can greatly enhance the accuracy of resource assessment. [ABSTRACT FROM AUTHOR]

Abundant shale oil resources were recently found in the organic‐rich Permian Lucaogou (P2l) Formation shale, Jimusar Sag, Junggar Basin. Although some scholars have conducted some researches on the basic geochemical characteristics of the Lucaogou Formation shale, it is not enough to effectively guide the shale oil exploration in the area. This is because during the exploration process of shale oil, besides the basic geochemical characteristics of shale, its mineral composition, physical properties, and oil‐bearing characteristics are all very important evaluation parameters. To systematically evaluate the favourable shale oil exploration sections in the Lucaogou Formation, 265 pieces of shale cores were sampled from well Ji174 in this study. Besides the basic geochemical characteristics of the 265 pieces of cores, the mineralogical, petrophysical, and oil‐bearing characteristics were also analysed. Results show that the shale has abundant organic matter (average total organic carbon 3.51%, average petroleum generation potential 15.67 mg/g), dominated by Type II1 and Type II2 kerogen, and has entered the early‐mature to mature stage. The Upper Member of the Lucaogou Formation has relatively higher organic matter and organic matter type is relatively more oil prone compared to the Lower Member; however, organic matter thermal maturity is lower. The P2l Formation shale is characterized by high carbonate minerals and low clay minerals, and when considering mineralogical brittleness, both the Upper and Lower members are ideally fracturable in shale oil development. The P2l Formation shale has a wide porosity range (1.1–13.9%), and the Lower Member's porosity is slightly greater. The inversion of shale porosity in the P2l Formation is controlled by the differentiated mineral composition. The oil saturation index values of the Lower Member shale are significantly greater than the Upper Member shale. From the above, the Lower Member of the P2l Formation shale is ideally suited and has greater shale oil potential in the Jimusar Sag, Junggar Basin, especially in the depth intervals of 3,255–3,272, 3,282–3,298, and 3,317–3,334 m in the well Ji174. [ABSTRACT FROM AUTHOR]

Despite the enormous potential of continental shale oil resources, only recoverable shale oil is economically valuable. Shale oil development decisions can greatly benefit from an accurate assessment of recoverable shale oil resources. Three crucial factors for evaluating shale oil recoverable resources are shale oil content, movable oil ratio, and recovery factor. However, because of the significant variety of continental shale, it is challenging to define the aforementioned characteristics. The methodologies and technology for determining the shale oil recoverable resource evaluation parameters, particularly the shale oil content, movable oil ratio, and recovery factor, are thoroughly discussed in this paper. Taking the Tertiary Sha-3 continental shale in Dongpu and Nanpu sags in Bohai Bay Basin, eastern China as an example, the shale oil content was obtained by the pyrolysis method with light and heavy hydrocarbon calibration comprehensively considered, and the main controlling factors of shale oil content were explored. Four geological parameters, including the sedimentary facies, pore structure, surrounding rock quality, and burial depth, primarily regulate the variation features of continental shale oil. The formation mechanism and primary governing variables of movable oil were then revealed using a physical simulation experiment. As porosity and permeability rise, clay mineral content falls, oil viscosity falls, and kerogen concentration rises, the movable oil ratio rises as well. Through stepwise linear regression, a quantitative estimation model for movable oil ratio was developed. After that, a literature search was used to determine the average recovery factor for continental shale oil. Finally, using the volume method model and the Monte Carlo methodology, the recoverable shale oil resources in the Gaoliu area of Nanpu Sag were assessed. The retention, movability, and resource potential of continental shale oil are better understood as a result of this study. [ABSTRACT FROM AUTHOR]

Hydrocarbon evaporative loss evaluation is important for shale oil resource assessment. We propose a mass balance model to evaluate the hydrocarbon evaporative loss (S 1-loss ) in this study. The proposed method is applied to a large Rock-Eval pyrolysis dataset on source rock samples from the Lucaogou Formation in the Jimusaer Depression of the Junggar Basin, NW China, as a case study to evaluate the S 1-loss . The results indicate that the S 1-loss can range from 0.12 to 7.25 mg/g Rock, corresponding to 11%–89% loss of the generated hydrocarbons (S 1-loss /(S 1 +S 1-loss )) due to evaporation before lab analysis. It appears that when Ro ≤ 1.3%, S 1-loss and S 1-loss /TOC decreases gradually with increasing Ro, likely corresponding to increasing oil density as results of heterogeneous source rock compositions and increased accommodation space via the creation of organic pores of large specific surface for heavy and large hydrocarbon molecules in oil window. When Ro > 1.3%, S 1-loss /TOC begins to increase with increasing Ro as more oil crack to gaseous and light hydrocarbons that are more susceptible to evaporative loss. In the case of similar Ro, the relative S 1-loss /TOC varies little among the samples but the absolute S 1-loss amount increases with increasing TOC. Restricted by regional geological conditions in this study, we focused on the S 1-loss for lacustrine type I kerogen only, and quantification of evaporative loss for other kerogen types remains a subject for further study. [ABSTRACT FROM AUTHOR]

Shale oil exploration of the Permian Lucaogou Formation (P2l) has greatly advanced in the Jimusar Sag in the Junggar Basin. However, despite the strong exploration prospects of shale oil resources, the potential of shale oil resources in the Junggar Basin has been insufficiently assessed. This study performs systematical evaluation of P2l source rocks in the Jimusar Sag and proposes an improved hydrocarbon generation potential method to assess the hydrocarbon generation and expulsion characteristics and evaluates the shale oil resource potential of the P2l source rocks in the Jimusar Sag. The results show that the P2l source rocks are thick (up to 200 m) and are distributed over a wide area (up to 1200 km2) in the study region. It contains high TOC (2%-5%), characterized by dominantly type I and type II kerogen. The source rocks are in the low mature-mature stage, and possess good conditions for generation of hydrocarbons. The P2l source rocks reached the hydrocarbon expulsion threshold at a thermal maturity of 0.8% vitrinite reflectance. The efficiency of hydrocarbon expulsion of the source rock is 34%. The amounts of hydrocarbons generated and expelled were 65 × 108 t. Based on the above information, the shale oil resources potential is calculated to be 43 × 108 t, indicating very good shale oil resource prospect in the P2l source rocks of the Jimusar Sag. Copyright © 2017 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

The decline of proven conventional petroleum resources in the shallow portions of the Nanpu sag has shifted attention to the exploration of deep unconventional oil and gas resources there, especially the shale oil resources in the middle Eocene shales of the Shahejie Formation (MES shales). In this study, to assess the oil potential of the MES shales, we carried out a systematical geochemical and basin modeling characterization. The results show that the MES shales have low maturity and are at the early stage of hydrocarbon generation, with a mean vitrinite reflectance of 0.64% and low ratio of C 27 18α(H)-22, 29, 30-trisnorneohopane to C 27 17α(H)-22, 29, 30-trisnorhopane (0.44–1.18). The MES shales contain abundant organic matter (OM), with an average total organic carbon content of 2.21 wt %. Biomarker analyses show that the OM in the MES shales derived mainly from floating macrophyte and aquatic algae, microalgae and bacteria. The sapropelinite group in the MES shales is predominant in the organic macerals, and the kerogen is sapropelic and dominated by types I and II 1. Biomarker analyses also reveal that the MES shales were deposited in the stratified water column as suggested by the presence of gammacerane, under relatively warm and wet climatic conditions. The anoxic conditions built up in the water column facilitated the OM preservation, although slight microbial degradation resulted in relatively high carbon preference index values. Modeling results based on geochemical data and basin analyses show that considerable quantities of hydrocarbons remain in the low-maturity MES shales. The preliminary estimate of the quantity of shale oil resources in the Gaoliu area of Nanpu sag is approximately 1.78 × 108 t. Nanpu sag have good shale oil potential, and shale oil exploration may be more feasible for MES shales, especially in the context of in-situ heating technology. • Middle Eocene Shale in Nanpu Sag of the Bohai Bay Basin are typical early mature. • MES shale deposited under a warm and wet climate with slight microbial degradation. • Middle Eocene lacustrine shale in Nanpu Sag contains good shale oil potential. [ABSTRACT FROM AUTHOR]

Lacustrine shale oil resources are abundant and play important roles in maintaining a sustainable economy. The uncertainty in the movable oil content of organic-rich shales with strong heterogeneity is the greatest risk in their exploration. Various methods exist for movable oil content evaluation, but they present many challenges, especially insufficient accuracy, complicated test procedures, high costs, and limited application. In this study, an extensive review of the theories, techniques, and methods of movable oil content evaluation and their merits and demerits for lacustrine shales were conducted. Then, taking the lacustrine shale of the Paleogene Shahejie Formation (50.5–33 Ma) of the Dongpu Depression, Bohai Bay Basin, as an example, the multi-step Rock-Eval pyrolysis method combined with light hydrocarbon calibration was utilized to evaluate the movable oil content Subsequently, key factors controlling movable oil content were investigated, including organic matter richness, type, and thermal maturity, quartz content, clay mineral content, pore volume, and specific surface area. Both the systematic cluster analysis results and regression standardization coefficients indicate that the total organic carbon content, pore volume, and specific surface area are the main controls on movable oil content. Finally, a quantitative estimation model for movable oil content was established and validated using a statistical product and service solutions modeling. This study improves the understanding of shale oil enrichment laws and provides a novel and practical quantitative model for movable oil content estimation in lacustrine organic-rich shales across the world. [ABSTRACT FROM AUTHOR]

Reconstructing the hydrocarbon generation and expulsion history of source rocks is an essential part of evaluating the hydrocarbon resource potential by genetic method. The hydrocarbon generation potential method is an efficient tool for quantifying the hydrocarbon generation and expulsion characteristics of source rock and evaluating the hydrocarbon resource potential based on Rock-Eval data. Although various revised versions of the method are publicly available, the following problems remain to be resolved: (a) the method is subjective; (b) implicit limitations are observed; and (c) rock mass loss is not considered, which may result in unacceptable errors. In this study, we propose a revised hydrocarbon generation potential method. Expressions for calculating the original rock mass (G o), original total organic carbon (TOC o), transformation ratio (T R), hydrocarbon expulsion ratio (E R) and hydrocarbon expulsion efficiency (f) were developed and incorporated into the hydrocarbon generation and expulsion history reconstruction and hydrocarbon resource potential evaluation, and these expressions combined conventional and unconventional resource evaluations systematically with objective and accurate results. The first member of the Qingshankou Formation (K 2 qn 1) in the Northern Songliao Basin, Northeast China, was used as an example to demonstrate the application of the proposed method. The results have been compared with the unrevised method using the same Rock-Eval data sets and verified with previous reports to demonstrate its reliability. The results also indicate that the hydrocarbon generation threshold (HGT) and hydrocarbon expulsion threshold (HET) of K 2 qn 1 are Ro = 0.4% and Ro = 0.6%, respectively. Three hydrocarbon generation and expulsion peak stages were identified: K 2 n (81–74 Ma), K 2 m (74–66 Ma), and N 2 t (66–0 Ma). The hydrocarbon generation and expulsion centers of K 2 qn 1 are mainly the Qijia-Gulong Sag and Sanzhao Sag. The resource potentials of conventional oil, unconventional tight oil, and shale oil associated with K 2 qn 1 source rocks in the Northern Songliao Basin are 8.15 × 108 t, 22.97 × 108 t, and 62.1 × 108 t, respectively. [ABSTRACT FROM AUTHOR]

Saline lacustrine shales are widely developed in the Es3 strata of the Dongpu Depression. Recently, a high-yield oil flow from the upper sub-member of Es3 (Es3U) of the PS18-1 well first confirmed the presence of shale reservoirs. However, the detailed difference of geochemistry, hydrocarbon generation potential, and reservoir quality between the upper (Es3U), middle (Es3M), and lower (Es3L) sub-members of Es3 saline shales remained unclarified. Both geochemical and petrophysical analyses were performed to answer above questions in this study. The results indicate that compared with Es3U and Es3M shales, Es3L shale has a higher TOC content (mean 1.94%). Oil-prone type I-II kerogen is the main kerogen type of Es3U and Es3L shales, while Es3M shale is dominated by type II-III kerogen. Es3L shale shows a relatively higher original hydrocarbon generation potential (mean 10.26 mg HC/g Rock) with an average original total organic carbon (TOC o) value of 1.62%, and a higher generated hydrocarbon (Q HC) than other two sets of shales. Compared with the dual organic matter source of marine and terrestrial organisms of Es3M shales, the main organic matter of Es3U and Es3L shales derived from aquatic organisms, and developed in saline water and brackish–saline water, respectively, with strong reducing environment. Organic-matter pores are undeveloped in Es3 shales, whereas interparticle and intraparticle pores are easily to be found. Higher brittle minerals are found in Es3U and Es3L shales, which are beneficial to form fracturing fractures during the development process, and widely developed bedding plane fractures can provide good conditions for hydrocarbon migration. Based on discussion, Es3L shales with present-day TOC over 1.5%, higher brittle minerals and gypsum salt around can be considered to be the most promising area for further shale oil exploration in the northern Dongpu Depression. • Difference of saline shale geochemical and petrophysical characteristics was compared. • Es3 shales deposited in a strong reducing to reducing environment. • TOC r of 0.4% and 1.5% are threshold of effective and high-quality source rocks, respectively. • Es3L shale with higher S 2o , producible oil content, brittle minerals and gypsum-salt surrounding is favorable for exploration. [ABSTRACT FROM AUTHOR]

This study analyzes the bulk and molecular geochemical data of 56 core samples of the Eocene Qianjiang Formation, a confined source rock unit embedded with salt intervals formed in a hypersaline lacustrine setting in central China. These source rocks within a single evaporative cycle collected from a recent shale oil exploration well are highly laminated, consisting of both intra- and inter-salt shales. Both organic pores and matrix pores serve as storage for hydrocarbon generated from kerogen within the source rock. Because the contrast in density between kerogen and oil, conversion of kerogen to oil inevitably leads to the increase in pore pressure and oil expulsion from kerogen within the same source rock unit. Impregnation of source rocks by expelled oils from nearby mature source rocks or from the organic-rich laminae within the same source rock units leads to anomalous Rock-Eval pyrolysis data, characterized by an abnormally high S1 peak, a high Production Index (PI), a suppressed Tmax and other anomalies. It is contradictory that both Rock-Eval pyrolysis data and sterane isomerization ratios of the studied inter-salt shale samples indicate strong impact of allochthonous hydrocarbons in the source rocks, whereas most aliphatic biomarker parameters obtained from the solvent extracts of these shales still provide useful information on the vertical variation in organic source input and depositional environment of the host rocks. This study provides insights into the bulk and molecular geochemical data interpretation, particularly in the inter-salt shale oil system evaluation in inferring the prevailing directions and pathways of diagenetic fluid movement and hydrocarbon migration. • Impregnation of source rocks by expelled oils leads to anomalous Rock-Eval pyrolysis data • Evaporative edimentary records are biased, where the inter-salt sediments recorded mainly the salinity reducation process • Contradictory geochemical parameters in laminated inter-salt shales provide insight into the prevailing fluid directions and pathways [ABSTRACT FROM AUTHOR]

Almost 70 years after shale oil was first studied, "self-souring" was widely regarded as an essential feature of shale oil. Recently, micromigration, which is a bridge connecting hydrocarbon generation, expulsion and enrichment in shale, has been discovered and confirmed as shale oil exploration deepens. However, due to strong heterogeneity, quantitative evaluation of hydrocarbon micromigration in shale remains unclear, making scientific understanding of shale oil enrichment mechanisms highly challenging. Based on the mass balance principle, we provide a quick and novel method to quantify hydrocarbon micromigration with the most commonly available geochemical data from Rock-Eval/total organic carbon (TOC) analysis by subtracting the real hydrocarbon generation potential (HGP R) from the original hydrocarbon generation potential (HGP O). The HGP R is calculated from pyrolysis parameters after light hydrocarbon calibration. Based on a kerogen kinetic theory, the HGP O is restored by utilizing a data-driven model with IBM-SPSS statistics. The results show that the Fengcheng Formation (P 1 f) shale features medium TOC contents, mixed kerogen types, mature to overmature levels, and high oil contents. Sixty-five percent of the P 1 f shale samples exhibit hydrocarbon intramicromigration, while the rest exhibit hydrocarbon extramicromigration. Shale oil contents and composition are closely related to hydrocarbon micromigration. The greater the hydrocarbon intramicromigration is, the higher the shale oil content. Micromigration occurs due to differences in hydrocarbon expulsion, pore space, and capillary pressure among shales. This method has a worldwide application for shale oil evaluation, and the findings will help to uncover shale oil differential enrichment mechanisms. • A quick and novel method is developed to quantify hydrocarbon micromigration in shale. • Micromigration is induced by differences in hydrocarbon expulsion, pore space, and capillary pressure. • The novel method provides a new perspective with which to investigate shale oil enrichment mechanisms. [ABSTRACT FROM AUTHOR]