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1 figure.-- Talk delivered at the SmallChem 2021 International online conference (17th-18th february 2021)., Amino-terminated oligoglycines non-covalently self-assemble, through cooperative hydrogen bonding formation, into biocompatible rigid 2D nanostructures called tectomers, either in solution or in surfacepromoted processes. Tectomers effectively coat carboxylated multi-walled carbon nanotubes (MWCNT-COOH) and strongly interact with graphene oxide (GO). Electrostatic interactions and hydrogen bonding formation accounts for the strong interfacial interaction of tectomers with MWCNTCOOH and GO, respectively. The resulting composites were characterized by electron- and atomic force microscopies, UV-vis and X-ray photoelectron (XPS) spectroscopies and contact angle measurements. Because of this high affinity of tectomers to GO, tectomers efficiently coat wet-spun GO fibers (Fig. 1). We also show that, due to their versatile surface chemistry, tectomers act as supramolecular peptidic adhesives for the immobilization of a variety of carbon nanomaterials, nanoparticles, molecules and drugs on the GO fiber surface therefore allowing GO fiber functionalization. The resulting ultrathin coatings exhibit remarkable water-resistant properties. This tectomer-based “double-sided sticky tape” fiber functionalization strategy can be extended to other fibers, fabrics and substrates, making it very attractive for technological and smart textile applications

Work presented at the nano Portugal 2020 Online Conference (nanoPT2020), Nanoscience and Nanotechnology International Conference, 23th - 24th september 2020., Amino-terminated oligoglycines non-covalently self-assemble, through cooperative hydrogen bonding formation, into biocompatible rigid 2D nanostructures called tectomers. Tectomers effectively coat carboxylated multi-walled carbon nanotubes (MWCNT-COOH) and strongly interact with graphene oxide (GO). Electrostatic interactions and hydrogen bonding formation accounts for the strong interfacial interaction of tectomers with MWCNT-COOH and GO, respectively. Because of the high affinity of tectomers to GO, tectomers have been used to coat wet-spun GO fibers. We here show that, due to their versatile surface chemistry, tectomers act as supramolecular adhesives for nanomaterial and molecule immobilization on the GO fiber surface. Tectomer-coated GO fibers can then be subsequently decorated with a variety of carbon nanomaterials (carbon nanotubes, carbon nanohorns, carbon nanocones, and highly fluorescent nanodiamonds), metal (gold, platinum, iron) nanoparticles, acrylate-based polymer nanoparticles, fluorophores and drugs. The resulting ultrathin coatings exhibit remarkable water resistant properties. We show that this tectomer-based “double-sided sticky tape” fiber functionalization strategy can be extended to other fibers and fabrics, such as polyurethane/PEDOT:PSS, poly(methyl methacrylate) and polyester, making it very attractive for a variety of technological and smart textile applications.

16 Figuras.-- Información suplementaria disponible en línea en la página web del editor.-- © 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/, Amino-terminated oligoglycine two-dimensional (2D) peptide self-assemblies (known as tectomers) have a versatile surface chemistry that allows them to interact with a variety of nanomaterials and to actas supramolecular adhesives for surface functionalization. Here, we have exploited the strong hydrogen-bond based interaction between tectomers and graphene oxide (GO) to functionalize GO fiber surfaces with different carbon nanomaterials (carbon nanotubes, carbon nanohorns, carbon nanocones, and highly fluorescent nanodiamonds), metal (gold, platinum, iron) nanoparticles, acrylate-based polymernanoparticles, fluorophores and drugs. The resulting ultrathin coatings exhibit remarkable water resis-tant properties. This tectomer-mediated fiber decoration strategy allows coating functionalities to be tailored by choosing the appropriate nanomaterials or other molecules. We show that this strategy can be extended to other fibers and fabrics, such as polyurethane/PEDOT:PSS, poly(methyl methacrylate) and polyester, making it very attractive for a variety of technological and smart textile applications., Authors thank the Fundación Domingo Martínez (Ayudas a la Investigación 2013) and Diputación General de Aragón (Grupo de Nanosensores y Sistemas Bioanalíticos (N&SB), ref. E25_17R) for research funding. MT would like to acknowledge University of Sussex strategic development fund. JMR acknowledges funding from the Australian Research Council (DP170102859).