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This paper reports the results of radioactivity concentrations and heavy metal content in soil samples collected from non-agricultural areas in the municipality and vicinity of North Kosovska Mitrovica, formerly the most important mining area in Europe. The estimated average activity concentrations of (226)Ra, (232)Th, (40)K and (137)Cs are 40.6 ± 19, 48 ± 25.4, 743.2 ± 200.5 and 81 ± 119 Bq kg(-1), respectively. The estimated average absorbed dose rate in the air and the annual effective dose are 78.7 nGy h(-1) and 96.6 μSv, respectively. The radium equivalent activity and external hazard index were also calculated. High contents of Pb, Zn, Cu, Cd, As and Ni were found in the analyzed soil samples, thus indicating pollution of the environment. Most metals have a wide range of values spanning 2 to 3 orders of magnitude, which is particularly evident for Pb and Zn. Correlations between the activity concentrations of the radionuclides, the heavy metal content in soil and the basic soil properties were determined by means of the Pearson linear coefficient. Strong positive correlations between the naturally occurring radionuclides, and also among Pb, Zn, Cu and Cd were found.

In urban areas, forest patches and parks are usually the places where people spend most of their time outdoors. Because of poor environmental protection policy and insufficient investment in industry and energy, Serbia is often ranked among the European countries with the greatest environmental pollution. In recent years, ecological protests have been organized throughout the country with the aim of raising ecological awareness and resolving environmental issues. The topic has become particularly popular since the plans for opening new mining areas in western Serbia came to the fore. This study was conducted with the aim to investigate radioactivity levels and metals content in soil and foliage of the most popular parks in Belgrade, the capital and largest city of Serbia. Based on a GIS (geographic information system) approach, the spatial distribution maps of radionuclides (226Ra, 232Th, 40K, 7Be, and 137Cs) and metals (As, Cd, Cr, Co, Cu, Na, Ni, Pb, Zn, K, Ca, Mg, and Mn) were made. Ambient dose-equivalent rate in air was also measured. The annual effective doses and excess lifetime cancer risk from radionuclides were calculated. Health effects of exposure to heavy metals in soil were estimated by noncarcinogenic and carcinogenic risk assessment. [ABSTRACT FROM AUTHOR]

After NATO bombing of Serbia in 1999, UNEP has identified Kragujevac as one of the four heavily polluted environmental "hot spots". Damaging of industrial and military targets caused the release of substantial amounts of hazardous chemical substances into the environment. This study was conducted in order to access the exposure of residents of Kragujevac city to persistent soil pollutants, twenty years after NATO air campaign. The paper reports the results of measuring radionuclides, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and heavy metals (As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn, and Hg) in soil samples collected from two depths (0–15 cm and 15–30 cm) at 30 locations along the riverbank of the Lepenica River. The average specific activities of 226Ra, 232Th, 40K and 137Cs were comparable to average worldwide values; excess lifetime cancer risk (ELCR) from natural radionuclides ranged from 1.1·10−4 to 3.3·10−4. The measured concentrations of As, Co, Cr, Cu, and Ni exceeded the limit values in most of the samples. Non-carcinogenic risk (hazard quotient and hazard index) and carcinogenic risk from heavy metals were assessed. Total hazard index was 0.257 and 2.16 for adults and children, respectively. Sum of measured PAHs ranged from 110 to 1026 μg kg−1. Sum of PCBs exceeded the limit value of 20 μg kg−1 in all samples (it ranged from 48.8 to 196.8 μg kg−1), but it was still below the remediation level. The differences between two layers with respect to all measured variables were not statistically significant. Image 1 • Soil in a "hot spot" area was investigated twenty years after NATO bombing. • Significant contamination by PCBs was observed. • As, Co, Cr, Cu, and Ni exceed the limit values. • PAHs follow anthropogenic pattern and have pyrogenic origin. • Activities of 226Ra, 232Th, 4 K and 137Cs are comparable to worldwide averages. [ABSTRACT FROM AUTHOR]

Transfer factors of natural radionuclides and 137 Cs from soil to plants used in traditional medicine were determined. The transfer factors (TF) were calculated as Bq kg −1 of dry plant per Bq kg −1 of dry soil. Mass activity concentrations of 226 Ra, 232 Th, 40 K and 137 Cs in soil and plant samples were measured with high purity germanium detector (HPGe). The concentrations of As, Co, Cr, Cu, Mn, Ni, Pb and Zn were determined, as well as the cation exchange capacity (CEC) and the content of exchangeable cations (Ca, Mg, K, Na). Wide ranges of values were obtained for all the metals, especially for Cr and Ni. The Absalom model was used for determination of the amount of 137 Cs transferred from soil to plant based on soil characteristics such as pH, exchangeable potassium, humus and clay contents. The estimated transfer factors were in the range from 0.011 to 0.307 with an arithmetic mean of 0.071, median of 0.050, geometric mean of 0.053 and geometric standard deviation (GSD) of 2.08. This value agreed well with that calculated from the measurements of 0.069, geometric mean 0.040 and GSD 3.19. Correlations between radionuclides, metals, physicochemical properties and transfer factors were determined by Spearman correlation coefficient. There was a strong positive correlation between 137 Cs transfer factor and the ratio of transfer factor for K and 137 Cs. Principal Component Analysis (PCA) was performed in order to identify some pattern of data. [ABSTRACT FROM AUTHOR]