1. The transformation of In2S3 film from flower-like to net-like structure by tunable microwave reaction for buffer layer in CuInS2/TiO2 solar cells.
- Author
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Peng, Fenglan, Zheng, Chaofan, Li, Haixin, Tao, Yuyue, Guo, Hengbo, Lu, Xiaoyi, and Yue, Wenjin
- Subjects
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SOLAR cells , *PHOTOELECTRICITY , *BUFFER layers , *PHOTOVOLTAIC power systems , *OPEN-circuit voltage , *MICROWAVES , *SURFACE defects - Abstract
Two morphologies of In 2 S 3 film were synthesized directly on FTO surface with microwave-assistant solution method. With reaction time/temperature/microwave power increasing, In 2 S 3 film assembled by hierarchical flower-like structure (In 2 S 3 flower) transformed into In 2 S 3 film assembled by net-like structure (In 2 S 3 net) with increased size and crystallinity. Compared to In 2 S 3 flower, In 2 S 3 net displayed stronger light-harvesting ability with higher charge separation, contributing to stronger photocurrent and lower charge transfer resistance. Based on the excellent photoelectrical properties, TiO 2 /In 2 S 3 /CuInS 2 /spiro-oMeTAD solar cells were fabricated with two In 2 S 3 films as the buffer layers as compared to the device without In 2 S 3 , which displayed obviously higher photovoltaic parameters due to the decreased surface defects on TiO 2 and the increased complementary absorption from In 2 S 3. Furthermore, the device with In 2 S 3 net presented higher short current density (J sc) than that with In 2 S 3 flower because the thicker In 2 S 3 layer strengthened the contribution of complementary light-harvesting. However, it displayed lower open circuit voltage (V oc), which was attributed to the presence of defects on the surface of overgrown In 2 S 3 for increased interfacial recombination. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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