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Transparent insulation structures play a pivotal role in harnessing solar energy efficiently, akin to the greenhouse effect in the atmosphere. This study undertakes a systematic evaluation of a novel sorbitol- or bio-based polycarbonate (bio-PC) for thermal insulation (TI) structures and hot water collector systems. Employing optical and mechanical methods, the bio-PC was comprehensively characterized on the polymer film level. Subsequently, the technical and ecological performance of these structures in various hot water collectors and systems was rigorously modelled and simulated. Results indicated that the novel bio-PC exhibited superior properties compared to conventional materials like cellulose acetate or fossil-based PC, showcasing promising prospects for widespread adoption. Drawing parallels to the greenhouse effect of CO2, the functional principle of transparent insulation structures is rooted in high solar transmittance and infrared absorbance, primarily governed by carbon-oxygen bonds. While fossil-fuel based transparent insulation materials have been prevalent, they suffer from drawbacks such as average infrared absorbance and susceptibility to yellowing. In contrast, the newly introduced bottom-up biopolymer bio-PC, derived from sorbitol derivatives, offers a compelling alternative. The study sheds light on the potentials and limitations of bio-PC for transparent insulation structures in integrated storage or flat plate collectors, aiming to mitigate environmental impacts associated with traditional materials. Future research directions emphasize refining modelling tools and addressing input data deficiencies, particularly for life cycle analysis. Concurrently, efforts are directed towards enhancing simulation accuracy and reliability through concurrent measurements of collector systems equipped with bio-PC-based transparent insulation. This research underscores the critical role of innovative materials in advancing sustainable energy solutions, with bio-PC emerging as a promising candidate in the realm of transparent insulation technology. [ABSTRACT FROM AUTHOR]