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Although spectrally selective materials play a key role in existing and emerging solar thermal technologies, temperature‐related degradation currently limits their use to below 700 °C in vacuum and even lower temperatures in air. Here a solar‐transparent refractory aerogel that offers stable performance up to 800 °C in air is demonstrated, which is significantly greater than its silica counterpart. This improved stability is attributed to the formation of a refractory aluminum silicate phase, which is synthesized using a conformal single cycle of atomic layer deposition within the high‐aspect‐ratio pores of silica aerogels. Based on direct heat loss measurements, the transparent refractory aerogel achieves a receiver efficiency of 75% at 100 suns and an absorber temperature of 700 °C, which is a 5% improvement over the state of the art. Transparent refractory aerogels may find widespread applicability in solar thermal technologies by enabling the use of lower‐cost optical focusing systems and eliminating the need for highly evacuated receivers. In particular, a shift to higher operating temperatures while maintaining a high receiver efficiency can enable the use of advanced supercritical CO2 power cycles and ultimately translate to an ≈10% (absolute) improvement in solar‐to‐electrical conversion efficiency relative to existing linear concentrating systems. [ABSTRACT FROM AUTHOR]

Abstract: The development of efficient solar thermal receivers has received significant interest for solar to electrical power conversion and heating applications. Volumetric flow receivers, where the incoming solar radiation is absorbed in the volume of a heat transfer fluid (HTF), promise reduced heat loss at the surface compared to surface absorbers. In order to efficiently store the thermal energy in the volume, nanoparticles can be suspended in the HTF to absorb the incoming radiation. In such systems, compact models are needed to design and optimize the performance. This paper presents an analytical model that investigates the effect of heat loss, particle loading, solar concentration and channel height on receiver efficiency. The analytical model was formulated by modeling the absorption of solar radiation by the suspended nanoparticles as a volumetric heat release inside the flowing HTF. The energy equation was solved with the surface heat losses modeled using a combined radiative and convective heat loss coefficient. The analytical solution provides a convenient tool for predicting the effect of different parameters, in terms of dimensionless numbers (Pe, NuE , , and θamb ), on two-dimensional temperature profiles and system performance. By combining the receiver efficiency with a power generation efficiency, idealized by the Carnot efficiency, an optimum receiver length where the total efficiency is maximized is determined. However, in practice, the maximum efficiency depends on the maximum allowable temperature of the working HTF. As a case study, predictions were made for Therminol® VP-1 with suspended graphite nanoparticles in a 1cm deep channel with a solar concentration of 10. The model predicts an optimum total system efficiency of 0.35 for a dimensionless receiver length of 0.86. Finally, the analytical model was used to estimate the optimum efficiency and the corresponding optimum receiver length for different design configurations with varying NuE and . The results from this paper will help guide experimental design of volumetric flow receivers for solar thermal based power systems. [Copyright &y& Elsevier]

Abstract: Improvements in solar-to-thermal energy conversion will accelerate the development of efficient concentrated solar power systems. Nanofluid volumetric receivers, where nanoparticles in a liquid medium directly absorb solar radiation, promise increased performance over surface receivers by minimizing temperature differences between the absorber and the fluid, which consequently reduces emissive losses. We present a combined modeling and experimental study to optimize the efficiency of liquid-based solar receivers seeded with carbon-coated absorbing nanoparticles. A one-dimensional transient heat transfer model was developed to investigate the effect of solar concentration, nanofluid height, and optical thickness on receiver performance. Simultaneously, we experimentally investigated a cylindrical nanofluid volumetric receiver, and showed good agreement with the model for varying optical thicknesses of the nanofluid. Based on the model, the efficiency of nanofluid volumetric receivers increases with increasing solar concentration and nanofluid height. Receiver-side efficiencies are predicted to exceed 35% when nanofluid volumetric receivers are coupled to a power cycle and optimized with respect to the optical thickness and solar exposure time. This work provides insights as to how nanofluids can be best utilized as volumetric receivers in solar applications, such as receivers with integrated storage for beam-down CSP and future high concentration solar thermal energy conversion systems. [Copyright &y& Elsevier]