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Much denser YBa2Cu3O7 (YBCO) superconducting films at least 1 μm thick with smooth surfaces have been obtained after introducing (Y/Nd)BCO multilayered structures. A significant enhancement of current carrying abilities has been achieved in these pulsed laser deposited films. The critical current density (Jc) has been increased by a factor of up to three in the entire field range. The imitation of the (Y/Nd)BCO multilayered structure by using YBCO ‘interlayers’ has also exhibited a considerable improvement in the current carrying ability. Similarities and differences between these two ‘multilayering’ approaches, leading to the observed effects, are discussed. The presence of interfaces even without element variation is likely to be the key to the improvements observed. In order to further promote Jc enhancement, small ‘multilayered’ additions of silver (Ag) to the films and multilayers provide various results: (i) rather strong enhancement for rather thin films and low addition levels, (ii) considerable degradation for large addition levels, and (iii) much less pronounced effect for thicker films. The enhancement of Jc is observed in zero and low magnetic fields, but has almost no effect at higher fields. All these experimental observations are discussed in terms of pinning, transparency and structural modifications introduced during the deposition of the film structures. [ABSTRACT FROM AUTHOR]

We have investigated the nature of the residual damage in diamond crystals following the ion implantation/graphitization 'lift-off' process, using near-edge x-ray absorption fine structure spectroscopy and transmission electron microscopy. A defective but crystalline interface is found, which displays dense pre-edge unoccupied states and an almost complete loss of the core-level C 1s exciton signature. This residual crystalline damage is resistant to standard chemical etching, however a hydrogen plasma treatment is found to completely recover a pristine diamond surface. Analysis and removal of residual ion-induced damage is considered crucial to the performance of many diamond device architectures. [ABSTRACT FROM AUTHOR]

High temperature superconducting tapes based on cuprate compounds are nowadays available on long lengths by several companies. Because high superconducting properties are strongly influenced by the crystallographic orientation of the superconducting film, and because the appropriate crystallographic orientation is obtained through epitaxial film growth, the development of an oriented template is of crucial technological importance. In the rolling assisted biaxially textured substrate (RABiTS) technique, a strong cube texture is obtained by cold rolling fcc metal tape and high temperature annealing, followed by the deposition of one or more buffer layer by either physical vapor deposition (PVD) or chemical solution deposition (CSD). Using the latter approach, it has been recently shown that it is possible to combine substrate recrystallization and buffer layer growth in a single step if the onset of recrystallization occurs at a temperature lower than buffer layer nucleation. In the present contribution, a detailed investigation of biaxially-oriented La 2 Zr 2 O 7 (LZO) buffer layer grown on cold-rolled Ni-W substrate by combined EBSD, AFM and TEM analyses is reported. It is shown that it is possible to obtain highly {001}〈110〉-textured LZO film directly on cold-rolled Ni-W substrate. Although some small polycrystalline regions appear, this approach leads to a strong suppression of grain boundary grooving typically occurring in RABiT-type substrates. Further, it is shown that, notwithstanding the microstructure of the metal substrate continues to evolve during the conversion heat treatment, the obtained LZO film is well adherent, without cracks or delamination. [ABSTRACT FROM AUTHOR]