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The current issue of global warming and the role of the ocean in global exchange of CO2 increases the interest in solid budgets of marine carbonate production and dissolution. The present study utilizes grain-size composition of pelagic sediments in order to trace spatial and temporal variability of carbonate sedimentation in the South Atlantic for the Holocene and Last Glacial Maximum (LGM, 19–23 cal kyr BP). A decrease in grain size (e.g. sand content, mean grain size of coarse carbonate silt) indicates increased carbonate dissolution as a result of increased fragmentation of calcareous microfossils. The spatial grain-size pattern suggests a threshold water depth below which a gradual grain-size decrease becomes increasingly rapid. This water depth is considered as the sedimentary lysocline. For the Holocene time slice, a constant, gradual decrease of foraminifer carbonate of about 5–10% per 1000 m water depth above the lysocline gives evidence for supra-lysoclinal dissolution. The water depth of the lysocline for the Holocene is tied to the interface of North Atlantic Deep Water and Antarctic Bottom Water (AABW) ( ca 4100 m). Submarine ridges which restrict intrusion of AABW into the Angola Basin cause an asymmetry in carbonate preservation across the Mid-Atlantic Ridge. The lysocline was reconstructed at ca 3100 m for the LGM. These data suggest that the ca 1000 m rise of the lysocline eradicated the Holocene east–west asymmetry. [ABSTRACT FROM AUTHOR]

The Atlantic is regarded as a huge carbonate depocenter due to an on average deep calcite lysocline. However, calculations and models that attribute the calcite lysocline to the critical undersaturation depth (hydrographic or chemical lysocline) and not to the depth at which significant calcium carbonate dissolution is observed (sedimentary calcite lysocline) strongly overestimate the preservation potential of calcareous deep-sea sediments. Significant calcium carbonate dissolution is expected to begin firstly below 5000 m in the deep Guinea and Angola Basin and below 4400 m in the Cape Basin. Our study that is based on different calcium carbonate dissolution stages of the planktic foraminifera Globigerina bulloides clearly shows that it starts between 400 and 1600 m shallower depending on the different hydrographic settings of the South Atlantic Ocean. In particular, coastal areas are severely affected by increased supply of organic matter and the resultant production of metabolic CO2 which seems to create microenvironments favorable for dissolution of calcite well above the hydrographic lysocline. [Copyright &y& Elsevier]

In this study, we test various parameters in deep-sea sediments (bulk sediment parameters and changes in microfossil abundances and preservation character) which are generally accepted as indicators of calcium carbonate dissolution. We investigate sediment material from station GeoB 1710-3 in the northern Cape Basin (eastern South Atlantic), 280 km away from the Namibian coast, well outside today’s coastal upwelling. As northern Benguela upwelling cells were displaced westward and periodically preceded the core location during the past 245 kyr (Volbers et al., submitted), GeoB 1710-3 sediments reflect these changes in upwelling productivity. Results of the most commonly used calcium carbonate dissolution proxies do not only monitor dissolution within these calcareous sediments but also reflect changes in upwelling intensity. Accordingly, these conventional proxy parameters misrepresent, to some extent, the extent of calcium carbonate dissolution. These results were verified by an independent dissolution proxy, the Globigerina bulloides dissolution index (BDX′) (Volbers and Henrich, submitted). The BDX′ is based on scanning electronic microscope ultrastructural investigation of planktonic foraminiferal tests and indicates persistent good carbonate preservation throughout the past 245 kyr, with the exception of one pronounced dissolution event at early oxygen isotopic stage (OIS) 6.The early OIS 6 is characterized by calcium carbonate contents, sand contents, and planktonic foraminiferal concentrations all at their lowest levels for the last 245 kyr. At the same time, the ratio of radiolarian to planktonic foraminiferal abundances and the ratio of benthic to planktonic foraminiferal tests are strongly increased, as are the rain ratio, the fragmentation index, and the BDX′. The sedimentary calcite lysocline rose above the core position and GeoB 1710-3 sediments were heavily altered, as attested to by the unusual accumulation of pellets, aggregates, sponge spicules, radiolaria, benthic foraminifera, and planktonic foraminiferal assemblages.Solely the early OIS 6 dissolution event altered the coarse fraction intensely, and is therefore reflected by all conventional calcium carbonate preservation proxies and the BDX′. We attribute the more than 1000 m rise of the sedimentary calcite lysocline to the combination of two processes: (a) a prominent change in the deep-water mass distribution within the South Atlantic and (b) intense degradation of organic material within the sediment (preserved as maximum total organic carbon content) creating microenvironments favorable for calcium carbonate dissolution. [Copyright &y& Elsevier]

Abstract: In this study, the coccolith compositions of 213 surface sediment samples from the South Atlantic and Southern Ocean were analysed with respect to the environmental parameters of the overlying surface waters. From this data set, the abundance patterns of the main species and their ecological affinities were ascertained. In general, Emiliania huxleyi is the most abundant species of the recent coccolith assemblages in the study region. However, the lower photic zone taxa, composed of Florisphaera profunda and Gladiolithus flabellatus often dominate the assemblages between 20°N and 30°S. If E. huxleyi is excluded, Calcidiscus leptoporus and F. profunda become the most abundant species, each dominating discrete oceanographic regimes. While F. profunda is very abundant in the sediments underneath warmer, stratified surface waters with a deep nutricline, Calcidiscus leptoporus is encountered in high-productivity environments. Furthermore, the results of a canonical correspondence analysis reveal affinities of Gephyrocapsa spp., Helicosphaera spp. and Coccolithus pelagicus for intermediate to higher nutrient conditions in a well-mixed upper water column. In contrast, Gladiolithus flabellatus seems to be associated with high temperatures and salinities under low-nutrient conditions. Based on the relative abundances of Calcidiscus leptoporus, F. profunda, Gladiolithus flabellatus, Helicosphaera spp., Umbilicosphaera foliosa, Umbilicosphaera sibogae and a group of subordinate subtropical species, six surface sediment assemblages have been identified, which reflect the distribution and characteristics of the overlying surface waters. Their distribution appears to be mainly a function of the relative position of the nutricline and thermocline in the overlying photic zone. [Copyright &y& Elsevier]

Abstract: Middle to late Miocene calcareous nannofossil data of ODP Site 1085 from the eastern South Atlantic off Namibia were analysed to document spatial and temporal changes in surface-ocean circulation, upwelling initiation, and associated productivity. Our data show that calcareous nannofossils constitute a significant part of the carbonate fraction throughout the investigated interval from 12.5 to 7.7 million years (Ma). Highest numbers of calcareous nannofossils (up to 38,000×106 nannofossils g−1 sediment) were observed during the intervals 9.9 to 9.7 and 8.7 to 8.0 Ma. These elevated numbers of calcareous nannofossils may generally be linked to the initiation of upwelling at about 10 Ma in the studied region. In contrast, diminished numbers of calcareous nannoplankton, as in the interval 9.6 to 9.0 Ma, probably characterise time intervals of weaker productivity resulting in a decrease of nannofossil carbonate contents in the sediments of Site 1085. This decrease in nannofossil production could be one possible explanation for the major CaCO3 depression in between 9.6 and 9.0 Ma. Coccoliths of the genus Reticulofenestra are the most abundant taxa. Their occurrences are characterised by changes in the investigated time interval. In addition, Coccolithus pelagicus, Calcidiscus leptoporus and Umbilicosphaera spp. contribute a common part of the assemblage. Calcareous nannofossils account for more than half of the carbonate, with peak contribution up to 80% at 8.8 Ma. [Copyright &y& Elsevier]

The Mar del Plata (MdP) Canyon at the Argentine continental margin is incorporated into a major contourite depositional system, built by the incursion of southern-sourced water masses affecting the seafloor at different waters depths. The new sedimentological, morphological and hydro acoustic data provide novel insights into contour and turbidity current interactions in mid-slope (blind) canyons, which do not have a connection to the shelf or an onshore river system. Such canyons are capable to record climate-related ocean stratification changes, current variability, and slope stability. Three sediment cores were obtained along the MdP Canyon thalweg covering the last 20,000 years and compiled with two cores from the adjacent Ewing Terrace. Turbidity-current activity within the MdP Canyon was limited to the time interval from Last Glacial Maximum (LGM) to the late deglacial. During the LGM and early deglacial, turbidites reached both the proximal sector and the distal northern flank of the canyon. During the late deglacial only the proximal sector was characterized by turbidite deposition. Similarities in mineralogy and grain-size data indicate that the material transported by the turbidity currents originated from the mid-slope Ewing Terrace. Glacial turbidity-current activity was most probably favored by increased sediment supply along the Ewing Terrace from a shallowed and/or enhanced glacial Antarctic Intermediate Water (AAIW) nepheloid layer. These sediments were trapped by the MdP Canyon, in particular at the head area. During the late deglacial, a displacement or limited AAIW nepheloid layer resulted in less sediment transfer along the Ewing Terrace and immediate accumulation in the MdP Canyon head restricting turbidite deposition to the proximal sector of the canyon. In general, contourite-turbidite interactions provide valuable information on variations in thermohaline circulation such as AAIW distribution and current strength. • Thermohaline circulation induced turbidity-current activity. • Contour and turbidity current interaction restricted to late last glacial period. • Intermediate nepheloid layer sediment supply induces sediment instabilities. • Transformation of sediment flows into low-density turbidity currents. [ABSTRACT FROM AUTHOR]