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Within this work, we report the results of nuclear inelastic scattering experiments of the low-spin phase of the iron(II) mononuclear SCO complex Fe[HBpz3]2 and density functional theory based calculations performed on a model molecule of the complex. We show that the calculated partial density of vibrational states based on the structure of a single iron(II) center which is linked by three pyrazole rings to borat is in good accordance with the experimentally obtained 57Fe-pDOS and assign the molecular vibrations to the prominent optical phonons. [ABSTRACT FROM AUTHOR]

We report the results of optical pump-nuclear resonance probe experiments on the SCO complex [FeII(L-PtII(t-but-tpy))2](BF4)2 with L being 2,6-di(pyrazol-1-yl)-4-(trimethylsilylethynyl)pyridine) and t-but-tpy being 4,4′,4″-Tri-tert-Butyl-2,2′:6′,2″-terpyridine using a novel experimental set-up at the beamline P01, Petra III, DESY Hamburg. We investigate the changes in the spin state of the complex when it is excited by laser pulses of 766 nm wavelength and pulse width < 100 ps. Our simulations of the nuclear forward scattering data indicate a dominant low spin state along with some high spin fraction in the absence of laser pulses. We observe clear changes in the time-spectrum following the instant at which the laser pulse hits the sample. Furthermore, these alterations are recorded as the relative timing of the laser pulses with respect to the synchrotron pulses is varied. [ABSTRACT FROM AUTHOR]