Yang, Linlin, Li, Lingfei, Liu, Renyong, Xie, Chenggen, Zhao, Jun, Chang, Wengui, Chen, Lijuan, Yan, Yehan, Zhang, Ningning, Zhang, Wei, Liu, Bianhua, and Yang, Liang
Carbon dots (CDs) as a remarkable fluorescent nanomaterial have the advantages of easy preparation, good photostability and high sensitivity. However, the poor aqueous solution stability of carbon dots largely limited their practical application due to the characteristic of easily forming precipitation for long time storage. Here, a kind of cationic fluorescent carbon dots CDs-P(Ph) 3 was designed by introducing a cationic compound, (4-carboxybutyl) triphenyl phosphonium bromide, to construct an electrostatic shell outside the dots. Such electrostatic shell could highly improve carbon dots stability in an aqueous solution to make CDs-P(Ph) 3 stable for long-term storage with negligible aggregation. Meanwhile, the sensitivity of CDs-P(Ph) 3 for hypochlorous acid (HClO) was also enhanced on the basis of the electron-withdrawing effect of cationic substituents on the surface of carbon dots. The limit of detection of CDs-P(Ph) 3 for HClO was as low as ∼0.32 μM. Additionally, the fluorescence of CDs-P(Ph) 3 could be rapid quenched by HClO with a quenching efficiency of more than 80% within 30 s. The excellent stability of CDs-P(Ph) 3 in an aqueous solution made it suitable for on-site detecting HClO in real samples, such as tap, well and lake water. Such designed fluorescent nanomaterial would provide a practical application pathway for optical sensing detection in environmental samples. [Display omitted] • The cationic fluorescence carbon dots were easily obtained by one-step synthesis. • Utilize the electrostatic repulsion of cation groups modified on surface of CDs to highly enhance its stability in aqueous. • The strong electron-withdrawing inductive effect of cation groups made CDs having higher sensitivity for HClO. • Real-time assessment and in-situ inspections of drinking water safety in the field. [ABSTRACT FROM AUTHOR]