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Stable hydrogen and oxygen isotopes are widely used as tracers in studying hydrologic processes. Surface water is an important component of the water cycle, and it is an effective vehicle for analyzing regional moisture sources and modern hydrologic processes. We collected surface water samples from August 2018 to August 2023 on the northern slope of the Kunlun Mountains during the Third Xinjiang Scientific Expedition and measured the stable hydrogen and oxygen isotope values. Additionally, we compiled the previous surface water isotope data in the region. We analyzed the spatial distribution characteristics of the stable hydrogen and oxygen isotopes of surface water on the northern slope of the Kunlun Mountains. The results showed that: (1) The surface water isotope values on the northern slope of the Kunlun Mountains showed spatial variations characterized by low values in the west and high values in the east. The local surface water line is δ² H=5.98xδ18 O-6.86 (R²=0.65, n=141). (2) A comparison of the stable isotope values of surface water and precipitation on the northern slope of the Kunlun Mountains reveals that the regional surface water isotope value averages are generally lower than the weighted precipitation isotope values. (3) The spatial distribution of surface water isotopes on the northern slope of the Kunlun Mountains is influenced by the interplay of two key factors: the water vapor advection by westerly winds and the local recycled moisture; additionally, evaporation also changed the regional surface water isotope values. [ABSTRACT FROM AUTHOR]

The widely-distributed altitude effect of stable isotopes in meteoric water, i.e., the negative correlation between stable hydrogen (or oxygen) isotope compositions and altitude, is the theoretical basis of isotope paleoaltimetry in climate proxies. However, as many recent local observations have indicated, the inverse altitude effect (IAE) in meteoric water does exist, and the regime controlling IAE is still unclear on a global scale. Based on a remote sensing product of the Infrared Atmospheric Sounding Interferometer (IASI), we examined the global frequency of IAE in water vapor isotopes, and the possible influences on isotopes in precipitation and climate proxies. According to the satellite-based δD values in water vapor at 2950 m and 4220 m above sea level, frequent IAEs are observed on a daily scale in North Africa, West and Central Asia, and North America, and IAEs are more likely to occur during the daytime than during the nighttime. We also converted water vapor δD to precipitation δD via equilibrium fractionation and then analyzed the potential presence of IAE in precipitation, which is more associated with climate proxies, and found that the spatial and temporal patterns of water vapor can be transferred to the precipitation. In addition, different thresholds of δD difference were also tested to understand the impact of random errors. The potential uncertainty of the changing isotope and altitude gradient should be considered in paleo-altitude reconstructions. [ABSTRACT FROM AUTHOR]

Quantitatively assessing the evaporation‐caused stable water isotope fractionation in precipitation below the cloud base is of great significance to understand the modern hydrological circulation especially in a plateau climate. Based on the hourly meteorological data at eight meteorological stations of the Gannan Plateau at the eastern margin of Qinghai‐Tibet Plateau in 2020, we examined the spatial and temporal variations of below‐cloud evaporation effect on precipitation isotopes, and then discussed the factors influencing the below‐cloud evaporation across the Gannan Plateau. The contemporary observation of precipitation isotopes at one site in the Gannan Plateau is also applied to understand the local meteoric water line associated with the below‐cloud evaporation. From 9:00 to 21:00 Beijing Time, the impact of below‐cloud evaporation is greater than that during the rest periods. Within the study region, the below‐cloud evaporation in the central area is usually stronger than that of the surrounding area. The diurnal and monthly variability of relative humidity is highly consistent with that of the remaining raindrop mass fraction after evaporation as well as the isotope variation in raindrop below the cloud base. When the relative humidity is greater than 95%, there is a linear relationship between the remaining raindrop mass fraction and the below‐cloud deuterium‐excess variation of approximate 1.1‰/%. Global warming will increase the below‐cloud evaporation effect across the Gannan Plateau. The findings are useful to understand the below‐cloud evaporation and isotope fractionation under a plateau climate. [ABSTRACT FROM AUTHOR]

Precipitation is an important natural resource relating to regional sustainability in arid central Asia, and the stable oxygen and hydrogen isotopes provide useful tracers to understand precipitation processes. In this study, we collected the hourly meteorological data at several stations on the southern slope of the Altai Mountains in arid central Asia, from March 2017 to June 2022, and examined the diurnal impact of below-cloud evaporation on stable isotope compositions of precipitation. During nighttime, the changes in isotope compositions below cloud base are generally weak. The enhanced impact of below-cloud evaporation can be found after around 15:00, and the impact is relatively strong in the afternoon, especially from 18:00 to 22:00. Summer and spring usually have a larger impact of below-cloud evaporation than autumn, and the winter precipitation is generally not influenced by below-cloud evaporation. On an annual basis, the differences in evaporation-led isotope changes between daytime and nighttime are 1.1‰ for stable oxygen isotope compositions, 4.0‰ for stable hydrogen isotope compositions and 4.7‰ for deuterium excess. The period from 2:00 to 10:00 shows relatively low sensitivity to relative humidity, and from 14:00 to 22:00 the impacts are sensitive. Considering the fluctuations of precipitation isotope compositions, the impact of below-cloud evaporation does not greatly modify the seasonal environmental signals. [ABSTRACT FROM AUTHOR]

The isotope-enabled general circulation models (GCM) have been widely applied to simulate the variability of stable isotopes in meteoric water at various time scales. The in-situ observations of water vapour isotopes are an important basis for assessing the performance of isotope-enabled GCMs, although they are still limited. Here we compiled the observations of near-surface water vapour isotopes on a daily scale at 17 stations in East Asia, and assessed the skill and the association between isotope error and meteorological errors on a daily scale. Generally, the spatial pattern and seasonal variability can be well simulated in the isotope-enabled GCMs. The models show better skill for warm and humid backgrounds, which also corresponds to the monsoonal regions with lower latitudes in East Asia. As spatial resolution is finer, the skill of models is better, which can be seen from the two GCMs. According to the correlation coefficient, the improvement of resolution is more obvious in summer than in winter, especially for IsoGSM. In addition, the correlation coefficient in winter is usually larger than that in summer. The daily modelling has good potential to investigate the daily or synoptic climate information in water isotopes. The findings are useful for understanding the applicability of isotope-enabled models in East Asia and the climate factors influencing the skill of isotope-enabled models on a daily basis. • This is the first systemic assessment of daily water vapour isotopes in East Asia using in-situ observations. • The models show better performances in monsoonal regions with warm and humid backgrounds, than cold and dry conditions. • The assessments provide the basis to interpret the skill of models in East Asia, and how it relates to climate conditions. [ABSTRACT FROM AUTHOR]

• Compared to the microphysical model, the isotope inversion model usually underestimates the evaporation in arid regions. • The microphysical model is more sensitive to errors in temperature and relative humidity than the isotope inversion model. • The range of raindrop remaining fraction in the isotope inversion model was determined for different isotopic inputs. In global hydrological circulation, evaporation widely occurs from the land, the oceans, and other water surfaces. Compared to the evaporation from open water, the below-cloud evaporation of falling raindrops is more difficult to quantify. As an alternative to the traditional microphysical model, the difference in stable water isotopes between water vapour and precipitation provides a new perspective to estimate the raindrop mass loss. According to the recent observations of stable isotopes in near-surface water vapour and precipitation in five sampling stations from humid to arid climates in East Asia, we quantified the below-cloud evaporation of raindrops using both a microphysical model and an isotope inversion model. The results indicate that the isotope inversion model, relative to the microphysical model, usually underestimates the impact of below-cloud evaporation on precipitation, especially in arid inland. The sensitivity test of the two models to errors in climatic factors shows that the microphysical model was more sensitive to errors in temperature and relative humidity than the isotope inversion model. We also plot the ranges that the isotope inversion model has solutions under various meteorological and isotope inputs. The findings are useful for understanding the atmospheric processes below the cloud base and the comparability of different methods in quantifying below-cloud evaporation. [ABSTRACT FROM AUTHOR]

• The new observation and modelling provide a basis to understand the altitude effect in central Asian precipitation isotopes. • Below-cloud evaporation enhances the altitude effect for most areas in the arid mountain-basin system. • The periods with a larger gradient of altitude effect usually have higher temperature and more precipitation. The stable water isotopes of precipitation provide important information about the hydrological circulation. In the arid mountain-basin system in central Asia, the altitude effect of precipitation isotopes has been a controversial topic in recent years, but the sample availability in extreme environments constrains the accurate understanding of the relationship between altitude and stable isotopes in precipitation. Based on the observation of precipitation isotopes around the Tarim Basin covered by the world's second-largest shifting desert, we examined the relationship between altitude and isotope composition. There is an altitude effect of precipitation isotopes between the basin and the surrounding mountains, with the modelled gradient for annual mean δ 18O being approximately 1.96 ‰ per 1000 m, which is weaker than the observed gradient focusing on the oases (2.75 ‰ per 1000 m). The largest modelled difference in δ 18O between 1000–2000 m and 2000–3000 m above sea level occurs in August and September. The periods with a larger gradient of altitude effect usually have higher temperature and more precipitation. Across the westerlies-dominated central Asia, the below-cloud evaporation enhances the altitude gradient of precipitation isotopes for most areas. The findings are useful to understand the local and remote drivers of precipitation isotopes and the paleoaltimetry of stable isotopes in climate proxies. [ABSTRACT FROM AUTHOR]

Based on daily meteorological records for 651 sites across China during the period 1960–2018, we estimated the changes in isotopic variations in raindrops as they descend from cloud base to ground over past decades, and tested the sensitivity of isotopic variations to climate parameters like air temperature and relative humidity. Air temperature correlates positively and relative humidity correlates negatively with below‐cloud isotopic variation. Generally, the below‐cloud evaporation effect on precipitation isotopes in the arid and semi‐arid regions of China is much greater than that in the humid and semi‐humid regions, although the impact might be reduced under cold‐arid or hot‐humid conditions. With aridity increasing with distance from the coast, the continental effect of precipitation isotopes is modified due to the below‐cloud evaporation. The seasonal pattern of the measured isotopic composition in precipitation near the ground and estimated at cloud base, is still similar in most regions, although the seasonal range is higher at the ground. During the last five decades, the below‐cloud evaporation effect has enhanced for the cold and arid regions of China especially across Qinghai‐Tibet Plateau and Inner Mongolia, due to combined effects of increasing air temperature and decreasing relative humidity. Although the below‐cloud evaporation effect is not always the dominant factor influencing the variability of stable isotopes, it needs to be considered as one of the contributing factors. This enhanced effect may impact the interpretation of past climate based on stable water isotopes, particularly in paleoclimate studies using speleothems and tree rings. Key Points: Below‐cloud evaporation effect on precipitation isotopes is assessed nationwideThe variability of below‐cloud evaporation effect is controlled by the warming climateEnhanced below‐cloud evaporation may affect interpretation of long‐term isotope records [ABSTRACT FROM AUTHOR]

The oxygen isotope compositions in atmospheric water including water vapor and precipitation have been widely used to trace moisture sources and to reconstruct past climates. However, the environmental controls of stable isotopes in atmospheric water depend on the time scales. Because of limited observations in arid Central Asia, factors controlling interannual variations in atmospheric water isotopes are still not clear. Using an isotope-enabled general climate model, we do not find at the annual scale the significant relationship between temperature and δ 18O values during 1979–2020 that is usually observed at the monthly scale. Under a warming background, there is no significant enriching trend in water isotopes. We found a strong positive correlation between westerly (and southerly) water vapor flux and δ 18O values on an interannual scale for the area between 35°N–50°N and 50°E–80°E in the upstream direction. High and low δ 18O years are characterized by different atmospheric circulations of mid-latitude Westerlies, and do not always correspond to the warm and cold years respectively. When the prevailing Westerlies are enhanced, the Westerlies circulation may carry more water vapor from the lower latitudes, leading to higher δ 18O values in Central Asia. The changes in Westerlies circulation are supported by the clustered backward trajectories during enriched and depleted years. The limited precipitation isotope observations also show similar findings as the simulations on an interannual scale. The interannual variations of stable isotopes in atmospheric water in arid Central Asia reflect the changes in the mid-latitude Westerlies circulation. This should be taken into account when interpreting oxygen isotope proxies of paleoclimate records. • Temperature effect of water isotopes exists on a seasonal scale, but is weakened on an annual scale in Central Asia. • On an annual scale, there are positive correlations between westerly (and southerly) water vapor flux and isotope value. • The critical area controlling interannual variability of water isotopes in the Tianshan Mountains is identified. [ABSTRACT FROM AUTHOR]

Stable oxygen isotopes in precipitation contain meaningful environmental information on a synoptic scale and can be applied to diagnose hydrometeorological processes. A series of rainstorms occurred at the southern Tianshan Mountains during the period from May to June 2013, and the event-based precipitation was sampled along the mountain range from west to east. Based on δ18O values in precipitation samples as well as the corresponding meteorological parameters, the moisture transport paths during the sampling period were identified. In late-May (stage 1), isotopes in precipitation collected generally showed a depleting trend. In mid-June (stage 2), there was no coherent trend of isotopes in precipitation for these stations, and only isotope values in Aksu showed a continually depleting trend. Checking other meteorological proxies during the sampling period, the event-based precipitation isotopes sensitively reflected the moisture process. In central Asia, both the westerly and monsoon moisture can be delivered to cause extreme precipitation events, and the isotopic information provides an alternative tool to investigate the atmospheric processes. [ABSTRACT FROM AUTHOR]

In arid northwest China where the precipitation intensity is relatively low, the stable hydrogen and oxygen isotopes (δ 2H and δ 18O) in precipitation are usually impacted by the sub-cloud evaporation. To understand the sub-cloud evaporation effect under an arid climate, we used the hourly meteorological data at 14 stations in the Kaxgar-Yarkant River Oasis, a rainshadow oasis of northwest China, and estimated the monthly and hourly isotopic change in falling drops from the cloud base to the ground. The results showed that the hourly meteorological observations are an effective way to assess the spatiotemporal pattern of sub-cloud evaporation effect. Across the 14 stations, the annual mean changes in deuterium excess below cloud base ranged from −19.1‰ to −6.8‰. The impacts of sub-cloud evaporation during spring and autumn are larger than those during winter and weaker than those during summer. The exponential regression (R 2 = 0.96), instead of linear regression (R 2 = 0.85), is better at describing the relationship between the raindrop remaining fraction and the isotopic changes from the cloud base to the ground. The sensitivity analysis of isotopic changes to different relative humidity scenarios shows that the drying scenario may lead to slightly larger sensitivity than the wetting scenario. The impact of sub-cloud evaporation on stable isotope compositions in precipitation may be underestimated when low precipitation events (especially less than 1 mm/h) are not sampled. • Hourly meteorological records are effective to assess sub-cloud evaporation effect on precipitation isotopes. • Arid mountains show a strong sub-cloud evaporation effect like nearby low-lying plains. • The impact of sub-cloud evaporation may be underestimated when low precipitation events are not sampled. [ABSTRACT FROM AUTHOR]

The seasonal and inter-annual variations of stable isotopes in alpine precipitation in arid Central Asia is of great help to understand the modern hydrological processes and climate proxy in the westerly-dominant region. In this study, we measured the 3-year precipitation isotope values at a site located on the southern Tianshan Mountains in Central Asia. The δ 18O values of precipitation show a statistically significant relationship with air temperature (R 2 = 0.58). The trajectory diagnostics indicate the strong influence of westerly moisture, although the local trajectories do exist. According to the 3-year isotope records in the sampling site, the δ 18O values of precipitation correlated with the meridional circulation index, while the correlation with the zonal circulation index is generally weak. An isotope-enabled GCM is used to analyze the correlation between the δ 18O values in summer precipitation and the meridional and zonal wind speeds on a longer time scale; there is a strong correlation between the δ 18O values and the meridional wind speed for the upwind direction. The findings indicate the meridional movement of mid-latitude westerly can be sensitively recorded in the modern precipitation in arid Central Asia, and the inter-annual variability of precipitation isotopes in Central Asia can not only be attributed to temperature effect. • A multiple year measurement of precipitation isotope in a mountainous site of arid Central Asia is presented. • The δ 18O value of precipitation is significantly correlated with the meridional wind in the upwind direction. • The inter-annual isotopic variation of precipitation are attributed to the moisture path, instead of only temperature effect. [ABSTRACT FROM AUTHOR]

The local meteoric water lines (LMWLs) reflect water sources and the degree of sub-cloud evaporation at a specific location. Lanzhou is a semi-arid city located at the margin of the Asian monsoon, and the isotope composition in precipitation around this region has aroused attention in hydrological and paleoclimate studies. Based on an observation network of stable isotopes in precipitation in Lanzhou, LMWLs at four stations (Anning, Yuzhong, Gaolan and Yongdeng) are calculated using the event-based/monthly data and six regression methods (i.e., ordinary least squares, reduced major axis, major axis regressions, and their counterparts weighted using precipitation amount). Compared with the global meteoric water line, the slope and intercept of LMWL in Lanzhou are smaller. The slopes and intercepts calculated using different methods are slightly different. Among these methods, precipitation-weighted least squares regression (PWLSR) usually had the minimum average value of root mean sum of squared error (rmSSEav), indicating that the result of the precipitation weighted method is relatively stable. Higher precipitation amount and lower air temperature result in larger slopes and intercepts on an annual scale, which is out of accordance with the summertime. [ABSTRACT FROM AUTHOR]

Deuterium excess and stable oxygen isotopes in precipitation have been widely applied to trace the source of water vapor. In this study, hydrogen and oxygen isotope analyses of samples were collected on seven sampling stations in Dingxi area from April 2019 to April 2020. The seasonal variation of hydrogen and oxygen stable isotopes as well as the d-excess indicate that the source of water vapor in Dingxi area is mostly from a single source. However, there are different sources of water vapor in the summer. Meanwhile, water vapor sources were analyzed using the Lagrange algorithm, indicating two different principal water vapor sources for precipitation in the area: some locally recycled water vapor in summer and autumn, and most water vapor from the westerly belt. Further studies using the PSCF and CWT analysis methods show that the locally recycled water vapor contributes more to its precipitation in the northwest of Dingxi area. [ABSTRACT FROM AUTHOR]

The stable isotopes (δD and δ18O) in soil water allow tracing of the flow and transportation of water in the soil. However, there are few studies on the use of soil water stable isotopes to explore the soil water in the floodplain, especially in determining the soil water source and infiltration mechanism. The Bayesian mixing model (MixSIAR) was integrated with the line conditioned excess (lc-excess) of stable isotopes (δD and δ18O) in precipitation, soil water (0–150 cm), river water, and groundwater to determinate the source and recharge mechanisms of two different soil profile types in the floodplain of the upper Yellow River in Lanzhou, China. The results showed that soil water below 80 cm was affected by river water recharge, affecting soil water content and stable isotopic composition at S1 sampling points (profile parallel to river water); this effect was not observed at S2 (profile is higher than the river water) sampling points. The isotopic compositions of the soil water sources at the two sampling points (S1: δD = −77.41‰, δ18O = −11.01‰; S2: δD = −74.02‰, δ18O = −10.56‰) were depleted more than those in the long-term amount-weighted precipitation isotopes (δD = −56.30‰, δ18O = −8.17‰). The isotope signatures of soil water sources are similar to the isotope characteristics of some high-intensity precipitation events (≥30 mm/day), indicating that soil water originates from a fraction of the total precipitation. The piston flow (60%) and the preferential flow (40%) coexist, but soil moisture and rainfall intensity will affect the sequence of the two infiltration methods. This study provides insights for understanding the hydrological process of the upper Yellow River and evaluating groundwater quality and protecting the floodplain environment. [ABSTRACT FROM AUTHOR]

The proportional contribution of recycled moisture to local precipitation is a geographically dependent parameter that cannot be ignored in water budgets. Stable hydrogen and oxygen isotopes are sensitive to environmental changes and can be applied to investigate the modern water cycle. In this study, a three-component mixing model is used to calculate the contribution of different water vapors (advection, evaporation and transpiration) to summer precipitation in Lanzhou city, Northwest China. The results show that for all sampling sites in Lanzhou, the contribution of advection vapor to precipitation is the largest, followed by the plant transpiration vapor, and the contribution of surface evaporation water vapor is usually the least, with the average values of 87.96%, 9.1% and 2.9%, respectively. The spatial differences of plant transpiration vapor are generally larger than those of advection vapor and surface evaporation vapor, and the high values appear in Yongdeng, Daheng and Gaolan. [ABSTRACT FROM AUTHOR]

The deuterium excess in precipitation is an effective indicator to assess the existence of sub-cloud evaporation of raindrops. Based on the synchronous measurements of stable isotopes of hydrogen and oxygen (δ2H and δ18O) in precipitation for several sites in Lanzhou, western China, spanning for approximately four years, the variations of deuterium excess between the ground and the cloud base are evaluated by using a one-box Stewart model. The deuterium excess difference below the cloud base during summer (−17.82‰ in Anning, −11.76‰ in Yuzhong, −21.18‰ in Gaolan and −12.41‰ in Yongdeng) is greater than that in other seasons, and difference in winter is weak due to the low temperature. The variations of deuterium excess in precipitation due to below-cloud evaporation are examined for each sampling site and year. The results are useful to understand the modification of raindrop isotope composition below the cloud base at a city scale, and the quantitative methods provide a case study for a semi-arid region at the monsoon margin. [ABSTRACT FROM AUTHOR]

The spatial distribution of stable water isotopes (also known as an isoscape) in precipitation has drawn increasing attention during the recent years. In this study, based on the observations at 32 stations, we assessed two widely applied global isoscape products (Regionalized Cluster-based Water Isotope Prediction (RCWIP) and Online Isotopes in Precipitation Calculator (OIPC)) at the Qinghai-Tibet Plateau (QTP) and then established an improved isoscape of oxygen isotopes in precipitation on a monthly basis using a regionalized fuzzy cluster method. Two fuzzy clusters can be determined, which is consistent using three meteorological data. The monthly isoscapes show the seasonal movement of high and low isotopic value regions across the QTP and reveal the influences of monsoon and westerly moisture. According to the cross validation, the δ18O in precipitation in the new monthly isoscapes for the QTP we propose performs better compared to the existing global products. To create a regional isoscape in many other regions, the regionalized fuzzy cluster method can be considered especially for regions with complex controlling regimes of precipitation isotopes. [ABSTRACT FROM AUTHOR]

Isotope data at mid-latitude locations are commonly available on annual, monthly, and daily timescales; however, they are rarely available for the variations occurring on the sub-hourly scale within individual precipitation events. To fill this gap, sub-hourly (every 10 min) sequential samples were collected for nine precipitation events, and the δ18O values of the individual events were analyzed from June to October 2019 in Lanzhou, Northwest China. The Sequential Meteoric Water Line (SMWL) correlation between δ2H and δ18O is δ2H = 7.33 δ18O + 9.78 (R2 = 0.97, N = 170). All events had a similar decreasing variability pattern in the initial period (before the vertical gray dotted line), while during the later period (after the vertical gray dotted line), negative δ18O values dominated, exhibiting a different pattern. Variations in the δ18O values were about 1–5‰ during most intra-events. We found that δ18O values mainly exhibit three patterns in the intra-event, namely a "V"-shaped pattern, an "L"-shaped pattern, and a decreasing pattern. Positive δ18O values are controlled by re-evaporation in the beginning period. Relative humidity has no effect on the δ18O values of precipitation events, mainly because dry and warm conditions are conducive to the evaporation of rainwater in the study region. The changes in the isotopic characteristics of precipitation are closely linked to the regional climate. The continuous analysis of precipitation samples revealed that the rapid change of δ18O values is related to different moisture sources and transport paths. A new air mass with enriched heavy isotope intrusion can change the isotopic composition in the intra-event. [ABSTRACT FROM AUTHOR]

Based on 1260 tap water samples gathered monthly and 136 surface water samples collected seasonally in the eastern margin of the Qinghai–Tibet Plateau, the local tap water line, the basic spatiotemporal characteristics of tap water isotopes, and their indication for water source under different water supply modes were discussed, linking the local tap water supply and water source information. A new tap water isotopes data set based on dense sampling sites was established, which was reliable for the analysis of tap water isotope features, tap water supply management, and tap water sources. The main conclusions are: (1) The local tap water lines in Gannan and Longnan are δ2H = (7.06 ± 0.17) δ18O + (3.24 ± 1.75) (r2 = 0.81, p < 0.01) and δ2H = (5.66 ± 0.09) δ18O + (−8.12 ± 0.82) (r2 = 0.82, p < 0.01), respectively. (2) The annual mean δ2H and δ18O in tap water show an increasing trend from southwest to northeast. The seasonal differences of δ2H and δ18O in tap water in Gannan and Longnan are small. (3) The correlation of tap water isotopes with those in main source water is high, while that of isotopes in tap water with those in non-water source is low. Under the central water supply mode by local tap water company, tap water isotopes in Gannan where groundwater is the direct water source show weak connection with those in surface water and precipitation, and those in tap water in Longnan with surface water as main source water reveal good connection with isotopes in surface water. Under mixed water supply modes, tap water isotopes indicate that surface water is the main tap water source in Gannan and Longnan with multiple water sources. [ABSTRACT FROM AUTHOR]

A Lagrangian diagnostic adjusted using specific humidity, with 6 h intervals along the trajectory and with lifting condensation level as cloud base height, was employed to identify the moisture source regions around the Tianshan Mountains, northwest China. Then, the relationship between precipitation stable isotopes and diagnosed duration–distance of moisture trajectory was analyzed. In this region, the median value of transport duration from moisture source to precipitation sampling site is approximately 3 days, and most moisture sources are closer than 1000 km. According to the Lagrangian diagnosed moisture sources, the higher precipitation summer months usually have rapid air mass movement, and remotely sourced moisture can be delivered to arid central Asia; in the dryer winter months, the moisture loading is weak, and longer transport duration and shorter source distances are observed. As trajectory duration increases, δ18O in sampled precipitation shows a positive trend, especially on the northern slope, and the short-duration events are usually significantly impacted by local recycled moisture with depleted isotopic signatures. The northern slope usually shows relatively shorter duration and longer distance, and more distant sources have more enriched isotopic values. [ABSTRACT FROM AUTHOR]

Stable isotopes (e.g., δ2H and δ18O) in tap water are important tools to understand the local climate or environment background, water sources and the state of regional water supply. Based on 242 tap water samples, 35 precipitation samples and 24 surface water samples gathered in the urban area of Lanzhou, the basic spatiotemporal characteristics of isotopes in tap water, their connection with isotopes in other water bodies and change during the process from raw water to tap water are discussed in detail, combining the information of local tap water supply and water source. It can provide reliable help for understanding the isotope characteristics of local tap water, regional water supply management and determination of tap water source of in a small area. Except for the establishment of a new data set of isotopes in tap water with complete time series and uniform spatial distribution of sampling sites, other results show that: (1) The Local Tap Water Line (LTWL) of Lanzhou is δ2H = (6.03 ± 0.57) δ18O + (−8.63 ± 5.44) (r2 = 0.41, p < 0.01). (2) For seasonal variations, δ2H and δ18O in tap water both are higher in autumn and lower in spring. The diurnal and daily variations of isotopes in tap water are not large. As for spatial variations, the monthly mean values of δ2H and δ18O in tap water at each sampling site show little difference. The isotopes in tap water collected from one single sampling site can be considered as a representative for isotopes in tap water in the area with a single tap water source. (3) Isotopes in tap water show weak connection with precipitation isotopes, but exhibit good connection (consistent seasonal variation, similar numerical range, small numerical difference and high correlation) with isotopes in surface water, which is the direct water source. Isotopes in water change little from raw water to tap water. Isotopic composition of tap water in Lanzhou can be used as a representative of isotopes in surface water. [ABSTRACT FROM AUTHOR]

Although stable isotopes of hydrogen and oxygen in surface waters (especially in river waters) are useful tools to understand regional hydrological processes, relevant information at some upper reaches of large rivers in western China is still limited. During 2016–2017, we focused on the Liujiaxia Reservoir along the upper Yellow River, where we collected surface water samples at two locations, above and below the dam (identified as "lake water" and "river water"). The results show that the heavy isotopes in lake and river waters are enriched during the warm months, when the river discharge is large, and depleted during the cold months. The slopes of the water line (δ2H versus δ18O) for both the lake and river waters were lower than that of the global mean, due to evaporation. The different d values of the lake and river water reflect the regional evaporation and water sources. [ABSTRACT FROM AUTHOR]

• Clarifying the response relationship between mountain precipitation and irrigation in oasis with multisource data. • The climate background information and evidence of precipitation recycling contained in stable isotopes. • Impacts of irrigation and local hydrological cycle driven by mountain-valley winds on precipitation. • The oasis and irrigation influence the local precipitation through offset, remote, combination, and delayed effects. Water is one of the scarcest resources in arid regions, and irrigation is an important means to improve crop yield and ensure food security. The Xinjiang features an integrated irrigation agriculture and oasis economy paradigm. However, the understanding of the impact mechanism and quantitative analysis of irrigation on precipitation is inadequate now. With the aim of clarifying the response relationship between mountain precipitation and irrigation in oasis, we clarify and quantify the moisture sources of precipitation using the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model and multisource data (including field-collected isotopes data, C-Isoscape, ERA5, and GDAS). The results obtained show: (1) Isotope analysis provides valuable insights into the climate background and precipitation recycling. The Local Meteoric Water Line's lower slope and intercept than Global Meteoric Water Line suggest a severe arid climate and strong sub-cloud evaporation. The intercept (13.44) of Local Meteoric Water Line in Mountain Areas exceeds the global average, indicating significant moisture recycling in mountain areas (MA). The d-excess in MA is prominent year-round, highlighting the influence of recycled moisture. (2) The oasis and irrigation influence the local precipitation through offset, remote, combination, and delayed effects. The offset effect hinders precipitation formation in irrigation areas (IA) due to the counteracting irrigation-induced humidification and cooling effect. Through the interaction of westerly circulation and local mountain-oasis hydrological cycle, irrigation-induced moisture is transported to MA and uplifted, which is remote effect. The combination effect synergistically enhances precipitation intensity, especially in intricate MA, through the combined influence of terrain's forced uplift and convective cells. Furthermore, the mountainous precipitation influenced by the mountain-oasis hydrological cycle often exhibits a delayed effect. (3) Based on HYSPLIT model tracking results, the contribution ratio of oasis and irrigation induced evapotranspiration to summer precipitation in MA is approximately 19.60%, ranging from 13.68% to 28.49%. The findings provide insights into the mechanisms of irrigation and water resource management in the northern slope of Tianshan Mountains. [ABSTRACT FROM AUTHOR]

The ecohydrological separation (ES) phenomenon which states that there are two incompletely mixing subsurface water pools, one of which is supplied to plants for transpiration while the other flows to groundwater and river water, has far-reaching implications for hydrological model simulation and water resources management. Specifically, it is unclear whether it occurs under different geomorphological units (hillside, foothill, and floodplain) within the same climate zone, as well as the reasons for such variations. We collected samples of precipitation, groundwater, river water, soil water, and plant stem water from April to October 2019 and analyzed their stable isotopic composition. Moreover, in order to further confirm whether the ES phenomenon exists in both hillside, foothill, and floodplain, we also calculated the line-conditioned excess and the isotope values of source water. The isotope values of plant stem water were similar to that of soil water rather than groundwater on the hillside. Groundwater on the foothill in April, June, July, and August had considerably different isotope values from plant stem water. The isotopic composition of plant stem water was comparable to that of groundwater in the floodplain, but there were differences in the isotope values of source water and line-conditioned excess. On the hillside, foothill, and floodplain, this study found evidence of the ES phenomenon. As a result of preferential flows through soils that cause soil-water heterogeneity, the ES phenomenon under various geomorphic units differs from one another. This research disproved theories about translational flow across the rooting zone and offered a new perspective on the ES phenomenon. • The phenomenon of ecohydrological separation (ES) was shown in different geomorphic. • The proportion of preferential flow reflects the degree of the ES phenomenon. • Evaluation of soil water infiltration patterns is conducive to explaining the ES. [ABSTRACT FROM AUTHOR]

• The marine sources largely contribute to precipitation amount and the lower isotopic values in the MLYRB. • The regional effect of precipitation amount and cloud cover on precipitation isotopes is more remarkable than local effect. • The mean subcloud evaporation fraction is greater during the rainy season compared with that during the dry season. • Strong convection in the upstream moisture transport region is the key control on precipitation isotopes in the MLYRB. Paleoclimatic records in the East Asian monsoon region (EAM) depend on precipitation isotopes as proxies for past hydroclimatic variability. However, the potential mechanisms controlling precipitation isotopic variability in this region remain poorly understood. This study collected daily precipitation isotopes in the middle-lower reaches of the Yangtze River Basin from 2017 to 2020 to explore how convective behaviors and moisture sources determining the variability of precipitation stable isotopes. Daily precipitation δ18O presented a weak inverse relationship with local precipitation amount and air temperature. Results of correlation analysis showed that the maximum correlation zones of precipitation δ18O between different cloud levels and outgoing long wave radiation were identified in the upstream regions such as the Indian Peninsula, BoB, and Indo-China Peninsula during the rainy season. Back-trajectory analysis showed that substantial water vapor from maritine sources in the Indian Ocean and the Bay of Bengal (BoB) largely contributed to the lower δ18O values during the rainy season (−7.5 ‰) because of intense rainout processes in the upstream sourced regions, demonstrated by significant regional correlation between precipitation δ18O and regional precipitation amount. The regional correlations were stronger in the upstream regions than the local influences, indicating that precipitation isotopes in this region are more influenced by regional convective processes in the upstream region during the rainy season. Using the modified Stewart model, the mean subcloud evaporation fraction estimated was greater in rainy season (24.1 % vs 36.1 % for HK and HZ, respectively) than that in dry season (15.1 % vs 19.9 % for HK and HZ, respectively). These findings highlight the importance of upstream processes in controlling precipitation isotopes in the EAM region and provide reliable evidence on the interpretation of monsoonal climate variability. [ABSTRACT FROM AUTHOR]

Based on the variations in stable hydrogen and oxygen isotope ratios (δD and δ 18 O) of precipitation and NCEP/NCAR (National Centers of Environmental Prediction/National Center for Atmospheric Research) re-analysis data, we investigated the characteristics of the precipitation isotopes and the moisture origin during spring and summer seasons (from May to August) in the Yushugou River basin, East Tianshan Mountains. The more negative δ 18 O and higher d-excess values in spring and more positive δ 18 O and lower d-excess values in summer indicated the different moisture sources and temperature effects on isotope variations. By studying the meteoric water line, we found that the slope and intercept of local meteoric water line (LMWL) were lower than the global meteoric water line (GMWL) and China LMWL, which indicated arid climate. The temperature effect of δD and δ 18 O in precipitation was obvious with correlation coefficients of 0.41 and 0.48, respectively, and there was no rainfall effect. The research of water vapor transfer showed that the moisture origin was predominantly from westerly air masses during the observation period. δ 18 O and d-excess values variations in precipitation and the HYSPLIT4.0 air mass trajectory model suggested that there were accidental events, and sometimes the moisture was from drier polar air masses during the spring. [ABSTRACT FROM AUTHOR]