1. Growth mechanisms for Si epitaxy on O atomic layers: Impact of O-content and surface structure.
- Author
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Jayachandran, Suseendran, Billen, Arne, Douhard, Bastien, Conard, Thierry, Meersschaut, Johan, Moussa, Alain, Caymax, Matty, Bender, Hugo, Vandervorst, Wilfried, Heyns, Marc, and Delabie, Annelies
- Subjects
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SURFACE structure , *EPITAXY , *SILICON , *SUBSTRATES (Materials science) , *CRYSTAL defects , *OXYGEN , *CHEMICAL vapor deposition - Abstract
The epitaxial growth of Si layers on Si substrates in the presence of O atoms is generally considered a challenge, as O atoms degrade the epitaxial quality by generating defects. Here, we investigate the growth mechanisms for Si epitaxy on O atomic layers (ALs) with different O-contents and structures. O ALs are deposited by ozone (O 3 ) or oxygen (O 2 ) exposure on H-terminated Si at 50 °C and 300 °C respectively. Epitaxial Si is deposited by chemical vapor deposition using silane (SiH 4 ) at 500 °C. After O 3 exposure, the O atoms are uniformly distributed in Si-Si dimer/back bonds. This O layer still allows epitaxial seeding of Si. The epitaxial quality is enhanced by lowering the surface distortions due to O atoms and by decreasing the arrival rate of SiH 4 reactants, allowing more time for surface diffusion. After O 2 exposure, the O atoms are present in the form of SiO x clusters. Regions of hydrogen-terminated Si remain present between the SiO x clusters. The epitaxial seeding of Si in these structures is realized on H-Si regions, and an epitaxial layer grows by a lateral overgrowth mechanism. A breakdown in the epitaxial ordering occurs at a critical Si thickness, presumably by accumulation of surface roughness. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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