Search

Abstract: Highly efficient light‐harvesting systems were successfully fabricated in aqueous solution based on the supramolecular self‐assembly of a water‐soluble pillar[6]arene (WP6), a salicylaldehyde azine derivative (G), and two different fluorescence dyes, Nile Red (NiR) or Eosin Y (ESY). The WP6‐G supramolecular assembly exhibits remarkably improved aggregation‐induced emission enhancement and acts as a donor for the artificial light‐harvesting system, and NiR or ESY, which are loaded within the WP6‐G assembly, act as acceptors. An efficient energy‐transfer process takes place from the WP6‐G assembly not only to NiR but also to ESY for these two different systems. Furthermore, both of the WP6‐G‐NiR and WP6‐G‐ESY systems show an ultrahigh antenna effect at a high donor/acceptor ratio. [ABSTRACT FROM AUTHOR]

A bola-type supra-amphiphile assembled from a water-soluble pillar[5]arene host (WP5) and a rod-coil guest molecule (G) containing a photoactive 9,10-dialkoxyanthracene group was successfully constructed, which could further assemble into a monolayer supramolecular vesicle. Interestingly, the photodecomposition rate of G was remarkably promoted after its aggregation with WP5, accompanied by the disassembly of the formed supramolecular vesicle, especially with the coassembly of a photosensitizer eosin Y, which has potential applications in phototherapy. [ABSTRACT FROM AUTHOR]

A π-conjugated AB2 monomer 1 with a dibenzo[24]crown-8 (DB24C8) ring and two secondary amine centres has been synthesised. Treatment of a solution of 1 in dichloromethane with trifluoroacetic acid (TFA) leads to protonation of the amine groups, and then the DB24C8 rings are threaded by the dialkylammonium ion centres of other monomer molecules, leading to the formation of a supramolecular hyperbranched polymer, TFA- 1. Rather strong π-π stacking interactions between the conjugated cores are evident in this polymer. The supramolecular hyperbranched polymer (SHP) can be completely depolymerised by adding a slight excess of N- tert-butyl- N′, N′, N′′, N′′, N′′′, N′′′-hexamethylphosphorimidic triamide, tetrabutylammonium fluoride, or tetrabutylammonium acetate. The acid-base-controlled process induces a reversible change in the fluorescence intensities of the solutions due to the controllable presence of the π-π stacking interactions between the conjugated cores. This dynamic behaviour is significant with respect to 'smart' supramolecular polymer materials. [ABSTRACT FROM AUTHOR]

A luminescence supramolecular hyperbranched polymer is reversibly fabricated by successively adding acid and base to a solution of an AB2 platinum(ii) monomer in dichloromethane on the basis of acid–base controllable host–guest recognition of dibenzo[24]crown-8 moieties with dialkylammonium ion centers. [ABSTRACT FROM AUTHOR]