1. Free-standing honeycomb-like N doped carbon foam derived from coal tar pitch for high-performance supercapacitor.
- Author
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Wang, Yanzhong, Liu, Yuexin, Wang, Donghua, Wang, Chao, Guo, Li, and Yi, Tingfeng
- Subjects
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COAL tar , *CARBON foams , *ENERGY density , *POWER density , *SURFACE area , *ELECTRIC capacity - Abstract
A free-standing honerycomb-like N doped carbon (FHNC) was fabricated by one-step carbonization and activation of the commercial melamine foam loading coal tar pitch and KOH. The as-prepared FHNC exhibits three-dimensional interconnected architecture with hierarchical honeycomb-like structure, which has a large specific surface area of 3105 m2 g−1. The specific capacitance of FHNC is 280.3 F g−1 at 1 A g−1, and still maintains 185.4 F g-1 at 40 A g−1, indicating the good rate capability. • A free-standing honeycomb-like N doped carbon (FHNC) was fabricated by the commercial melamine foam and coal tar pitch. • FHNC electrodes have a large specific surface area of 3105 m2 g−1. • The specific capacitance of FHNC is 280.3 F g−1 at 1 A g−1. • The supercapacitors show 10.1 Wh kg−1 at a power density of 250 W kg−1. • The capacity retention of supercapacitor device is 96.3% after 10,000 cycles. A free-standing honeycomb-like N doped carbon foam (FHNC) is fabricated by one-step carbonization and activation of the commercial melamine foam loading coal tar pitch and KOH. The as-prepared FHNC exhibits the three-dimensional (3D) interconnected architecture with hierarchical honeycomb-like structure, which has a large specific surface area of 3105 m2 g−1. The specific capacitance of FHNC reaches up to 280.3 F g−1 at 1 A g−1, and still maintains 185.4 F g−1 at 40 A g−1, indicating the excellent rate capability. Additionally, the assembled symmetrical supercapacitor demonstrates the maximum energy density of 10.1 Wh kg−1 at a power density of 250 W kg−1, and excellent cycling stability (96.3% capacitance retention after 10,000 charge-discharge cycles at 5 A g−1). The outstanding electrochemical performance is assigned to the unique 3D interconnected architecture that endow the large accessible surface area, and rapid transfer pathway for ion and electron. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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