1. Optimization of Coating Temperature of TiO2 Nanoparticles on the Polypropylene Copolymer Surface for Photodegradation of Methylene Blue.
- Author
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Aliah, Hasniah, Arutanti, Osi, Masturi, Setiawan, Andhy, Sustini, Euis, Budiman, Maman, and Abdullah, Mikrajuddin
- Subjects
SURFACE coatings ,TEMPERATURE effect ,TITANIUM dioxide ,NANOPARTICLES ,POLYPROPYLENE ,SURFACES (Technology) ,PHOTODEGRADATION ,METHYLENE blue ,MECHANICAL alloying - Abstract
TiO
2 nanoparticles have been coated on the polypropylene (PP) copolymers using a milling method with temperature controller modification. These experiments were carried out at different milling temperature: 100 °C, 110 °C, 120 °C and 130 °C for 90 minute milling time for each experiment. Photocatalytic degradation of methylene blue (MB) was investigated using TiO2 coated PP copolymer which floats on the MB solution and illuminated under sunlight for 36 hours. It was found that TiO2 coated PP polymer at temperature of 100 °C resulted in optimum decomposition of MB solution. The concentration of MB in a test solution after 18 hours of exposure to the sun was 15.42%. The reaction rate constants (k) and the half-reaction (t1/2 ) in the MB photodegradation using the catalysts with a coating temperature of 100 °C, are 0.106 hours-1 and 6.53 hours, respectively. This coated material is very potential for repeated use to purify bulk water in high sunlight intensity region. [ABSTRACT FROM AUTHOR]- Published
- 2011
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