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Deep geological repositories are the sole option for safeguarding the atmosphere from hazardous radiation from high-level radioactive waste. Hyperalkaline pore fluids are produced when fluids from host rocks penetrate through the concrete/cement layers of such repositories, the layers created as bulkheads in vaults or to facilitate gallery access between buffers and the host rock. Such fluids also disperse through the compacted bentonite layers placed around the steel canisters that contain the waste in the repositories. The corrosion of steel canisters inside such repositories can be observed over a certain time. Chemical corrosion can lead to harmful leachates that can seep through the compacted bentonite layers that surround the steel canisters, altering the bentonite properties. In addition, these compacted bentonite layers are subjected to thermal histories due to the canisters emitting continuous heat (150°C to 200°C). These compacted bentonite layers have to hold up under these three conditions in repositories, all of which can affect the swelling properties of the bentonite. Two bentonite samples (B1 and B2) from Rajasthan's Barmer area were mixed with corrosion products and compacted to dry densities of 1.5, 1.75, and 2.0 Mg/m3 for this investigation. Thermal histories were induced at 110°C and 200°C for 3 h to prepare samples that were then saturated with hyperalkaline cement water. The presence of corrosion products resulted in a decrease in swelling pressure values when compared with samples without adding corrosion products. This decrease was more significant with an increase in the temperature of the induced thermal history. [ABSTRACT FROM AUTHOR]

• Thermo-mechanical characteristics of two bentonites from India are presented. • Variation of swell pressures of bentonite with variation in thermal loading and densities is presented. • The development of time swelling curves for various thermal histories is presented. • The swell pressures of both the bentonite decreased with an increase in the thermal loading. The deep geological disposal system is an internationally adopted option for the disposal of high-level nuclear waste (HLW). It consists of a highly expansive bentonite, which is used as a buffer material and as a part of an engineered barrier system. Bentonite provides sufficient swelling pressure and low hydraulic conductivity to the barrier system giving long-term stability. The high-temperature waste canister in DGR and the variation in temperature due to thermal gradient impose a thermal loading on the compacted bentonite buffer and may alter the swelling pressures of the compacted bentonite. Hence it is necessary to investigate the influence of thermal loading on the swelling pressure of compacted bentonite. The paper discusses an assessments of swell pressures of two compacted bentonites (Barmer 1 (B 1) and Barmer 2 (B 2)) from Barmer district of Rajasthan, India with initial dry densities of 1.5 Mg/m3, 1.75 Mg/m3, and 2 Mg/m3 and subjected to 110 °C and 200 °C, hydrated with distilled water. The swelling load is recorded and compared with non-heated samples of same densities. Experimental and theoretical evidences indicated that the swelling pressure of heated compacted bentonite decreased with an increase in the temperature. Statistical analysis is also presented with the help of analysis of variance (ANOVA). [ABSTRACT FROM AUTHOR]