1. Experimental studies on the detachment of multi-walled carbon nanotubes by a mobile liquid interface
- Author
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Emmanuel Flahaut, Markus Ahlskog, Saara Lautala, Matti J. Hokkanen, Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), University of Jyväskylä (FINLAND), Centre Interuniversitaire de Recherche et d'Ingénierie des Matériaux - CIRIMAT (Toulouse, France), University of Jyväskylä (JYU), Centre interuniversitaire de recherche et d'ingenierie des matériaux (CIRIMAT), Centre National de la Recherche Scientifique (CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC), and Institut National Polytechnique de Toulouse - INPT (FRANCE)
- Subjects
GRAPHENE ,Materials science ,Capillary action ,SILICA SURFACES ,Matériaux ,Mécanique des fluides ,ta221 ,Nanotechnology ,Wetting ,02 engineering and technology ,Carbon nanotube ,010501 environmental sciences ,01 natural sciences ,law.invention ,[SPI.MAT]Engineering Sciences [physics]/Materials ,[SPI.MECA.MEFL]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Fluids mechanics [physics.class-ph] ,Surface tension ,Contact line ,symbols.namesake ,Colloid and Surface Chemistry ,REMOVAL ,law ,Composite material ,ta116 ,0105 earth and related environmental sciences ,Double layer (biology) ,RELEASE ,ta114 ,Adhesion ,Hydrophobic interaction ,021001 nanoscience & nanotechnology ,Surface chemistry ,pintakemia ,COLLOIDS ,[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry ,AIR-WATER INTERFACES ,Amorphous carbon ,symbols ,van der Waals force ,nanoputket ,0210 nano-technology ,pintajännitys - Abstract
International audience; Retention and detachment of colloidal particles from surfaces is often considered only in terms of spontaneous chemical dispersion when the surface is already fully submerged. Nevertheless, interfacial processes, where the particles are caught on a mobile liquid contact line by capillary effects are ubiquitous. Theoretical description of such interfacial processes exist for spherical microcolloids, while for anisotropic shapes the literature is limited. Arc-discharge synthesized multiwalled carbon nanotube (MWNT) material contains besides the very anisotropic tubes also irregular amorphous carbon particles (ACP) that both are strongly hydrophobic. As a water–air–solid contact line is swept over a deposition of MWNT material on a hydrophilic substrate, it causes selective detachment of the spherical ACPs over the one dimensional MWNTs. In this work we investigate the detachment process and the balance between the surface tension force and adhesive forces. Our results show that on hydrophilic substrates the surface tension force of the liquid interface dominates over adhesion, sweeping away most of the material. However, clean MWNTs oriented perpendicular to the contact line are able to resist detachment. On the other hand, on hydrophobic surfaces adhesive forces dominate, possibly via the hydrophobic interaction. We discuss these results with conventional models of capillarity and adhesion, including the van der Waals force and the electrostatic double layer interaction. However, a fully satisfactory analysis will require e.g. computational modelling of the problem.
- Published
- 2017
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