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Volcanic ash deposits (tephra) in western Canada are instrumental in providing independent chronologic control for many archaeological and paleoenvironmental sites. In Alberta, tephra are a key chronologic tool in a region where radiocarbon dates are often unreliable because of the prevalence of carbonate-rich bedrock and other "old carbon" sources, such as coal. However, many studies using tephra for age control, particularly archaeological projects, identify tephra simply through field characteristics or light microscopy. In both Alberta and British Columbia, many radiocarbon dates that were used to date key tephra deposits were bulk conventional ages on peat and lake sediments, which are not always reliable. These factors have led to uncertainty in the age and number of Bridge River and Mount St. Helens (MSH) set Y tephra present in the region and incomplete distribution maps. New major-element geochemical analyses from archaeological and sedimentary sites across south-central Alberta, complemented by new analyses of tephra from British Columbia and Saskatchewan, refine the distribution of the Bridge River, MSH Yn and Mazama tephra. New geochemical data, radiocarbon dates, and a detailed overview of proximal MSH set Y stratigraphy and geochemistry show that only one MSH layer, Yn, is present in this region, rather than two MSH set Y tephra as previously suggested. Additionally, re-assessment of age data combined with new geochemical analyses confirm that there is also only one Bridge River tephra. A Bayesian modelled age estimate is determined for MSH Yn based on new AMS dates on the tephra and vetted existing conventional ages, providing a revised age estimate for MSH Yn of 3805–3535 cal BP (mean of 3660 cal BP). [ABSTRACT FROM AUTHOR]

High-resolution studies of peat profiles are frequently undertaken to investigate natural and anthropogenic disturbances over time. However, overlapping profiles of the most commonly applied age-dating techniques, including 14 C and 210 Pb, often show significant offsets (>decadal) and biases that can be difficult to resolve. Here we investigate variations in the chronometers and individual site histories from six ombrotrophic peat bogs in central and northern Alberta. Dates produced using pre- and post-bomb 14 C, 210 Pb (corroborated with 137 Cs and 241 Am), and cryptotephra peaks, are compared and then integrated using OxCal's P_Sequence function to produce a single Bayesian age model. Environmental histories for each site obtained using physical and chemical characteristics of the peat cores, e.g. plant macrofossils, humification, ash content and dry density, provide important constraints for the models by highlighting periods with significant changes in accumulation rate, e.g. fire events, permafrost development, and prolonged surficial drying. Despite variable environmental histories, it is possible to produce high-resolution age-depth models for each core sequence. Consistent offsets between 14 C and 210 Pb dates pre-1960s are seen at five of the six sites, but tephra-corrected 210 Pb data can be used to produce more coherent models at three of these sites. Processes such as permafrost development and thaw, surficial drying and local fires can disrupt the normal processes by which chronological markers and environmental records are incorporated in the peat record. In consequence, applying standard dating methodologies to these records will result in even greater uncertainties and discrepancies between the different dating tools. These results show that using any single method to accurately date peat profiles where accumulation has not been uniform over time may be unreliable, but a comprehensive multi-method investigation paired with the application of Bayesian statistics can produce more robust chronologies. New cryptotephra data for the Alberta region are also reported here, including the historical Novarupta-Katmai 1912 eruption, White River Ash (East), and glass from Mt. St. Helens, Mt. Churchill, and probable Aleutian sources. [ABSTRACT FROM AUTHOR]

Tephrochronology is one of the most effective ways to correlate and date Quaternary deposits across large distances. However, it can be challenging to obtain direct ages on tephra beds when they are beyond the limit of radiocarbon dating, do not contain mineral phases suitable for 40K-40Ar (or 40Ar/39Ar) dating, or suitable glass shards for fission-track dating are not available. Zircon U-Pb dating by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is an emerging technique for dating young (<1 Ma) tephra. Here, we demonstrate that LA-ICP-MS zircon U-Pb dating can produce reliable ages for key tephra beds found in Yukon and Alaska. We assessed five different techniques for calculating tephra maximum depositional ages from zircon U-Pb ages for eight tephra beds. Our preferred zircon U-Pb ages (reported with 2σ uncertainties), based on a Bayesian model for calculating maximum depositional ages, are broadly consistent with previously established chronology constructed from stratigraphy, paleomagnetism, and/or glass fission track and 40Ar/39Ar ages: Biederman tephra (178 ± 17 ka), HP tephra (680 ± 47 ka), Gold Run tephra (688 ± 44 ka), Flat Creek tephra (708 ± 43 ka), PA tephra (1.92 ± 0.06 Ma), Quartz Creek tephra (2.62 ± 0.08 Ma), Lost Chicken tephra (3.14 ± 0.07 Ma), and GI tephra (542 ± 64 ka). We also present newly revised glass fission-track and 40Ar/39Ar ages recalculated from previous determinations using updated ages for the Moldavite tektite and Fish Canyon Tuff standards, and updated K decay constants. For Pleistocene age zircon crystals, corrections for 230Th disequilibrium and common-Pb are significant and must be treated with caution. Similarly, apparent tephra ages are sensitive to the choice of method used to calculate a maximum depositional age from the assemblage of individual crystallization ages. This study demonstrates that LA-ICP-MS zircon U-Pb dating can be successfully applied to numerous Pliocene-Pleistocene Alaskan-Yukon tephra, providing confidence in applying this method to other stratigraphically important tephra in the region. • LA-ICP-MS method is well suited for rapid dating of very young zircon crystals. • Eight key tephra beds from Eastern Beringia were dated by zircon U-Pb method. • Young U-Pb ages are particularly sensitive to common-Pb and 230Th corrections. • Bayesian modeling reduces subjectivity in calculating ages. [ABSTRACT FROM AUTHOR]

The Aleutian Arc-Alaska Peninsula and Wrangell volcanic field are the main source areas for tephra deposits found across Alaska and northern Canada, and increasingly, tephra from these eruptions have been found further afield in North America, Greenland, and Europe. However, there have been no broad scale reviews of the Late Pleistocene and Holocene tephrostratigraphy for this region since the 1980s, and this lack of data is hindering progress in identifying these tephra both locally and regionally. To address this gap and the variable quality of associated geochemical and chronological data, we undertake a detailed review of the latest Pleistocene to Holocene tephra found in interior Alaska and Yukon. This paper discusses nineteen tephra that have distributions beyond southwest Alaska and that have the potential to become, or already are, important regional markers. This includes three ‘modern’ events from the 20th century, ten with limited data availability but potentially broad distributions, and six that are widely reported in interior Alaska and Yukon. Each tephra is assessed in terms of chronology, geochemistry and distribution, with new Bayesian age estimates and geochemical data when possible. This includes new major-element geochemical data for Crater Peak 1992, Redoubt 1989–90, and two andesitic tephra from St Michael Island (Tephra D), as well as revised age estimates for Dawson tephra, Oshetna, Hayes set H, Aniakchak CFE II, and the White River Ashes, northern and eastern lobes. [ABSTRACT FROM AUTHOR]

Lakes and bogs in northeastern North America preserve tephra deposits sourced from multiple volcanic systems in the Northern Hemisphere. However, most studies of these deposits focus on specific Holocene intervals and the latest Pleistocene, providing snapshots rather than a full picture. We combine new data with previous work, supplemented by a broad review of the characteristics and ages of potential source regions and volcanoes, to develop the first composite tephrostratigraphic framework covering the last ∼14,000 years for this region. We report new cryptotephra records from three ombrotrophic peat bogs—Irwin Smith (Michigan), Bloomingdale (New York), and Sidney Bog (Maine)—as well as new analyses and age models from previously reported sites, Nordan's Pond Bog (Newfoundland) and Thin-Ice Pond (Nova Scotia). A new tephra (Iliinsky) from the NGRIP and GRIP ice cores is also presented as it can be correlated to new data from these terrestrial records and helps validate radiocarbon age models. We identify 21 new tephra in addition to the 15 already known, several of which cover the entire region – the White River Ash east, Newberry Pumice, Ruppert (NDN-230), and Mazama. For the first time we find Mount St. Helens Yn (ca. 3660 cal yr BP) and a set P tephra (∼3000–2550 cal yr BP), and confirm the presence of Jala Pumice from Volcan Ceboruco, Mexico, and KS 1 from Ksudach volcano, Kamchatka. We describe new "ultra-distal" tephra, including the early Holocene KS 2 eruption, and propose correlations to volcanoes Iliinsky and Shiveluch of Kamchatka, and Ushishir of the Kurile Islands. Not all of these tephra represent large eruptions, with several plausible correlations to sub-Plinian events. Using Bayesian age-modeling, we present new age estimates for the newly described tephra, for tephra with previously poor age control, and for several proximal correlatives. Overall, we demonstrate northeastern North America's importance for providing transcontinental linkages between paleoenvironmental records and providing insights into ash distribution from different styles and sizes of eruptions. • Tephra are abundant in NE North America, with 36 unique units deposited between ∼14,000 and the present day. • Source volcanoes are in the Cascades, Alaska, Kamchatka, Kuriles and potentially Japan. • Updated Bayesian modelled ages are presented for key proximal correlative eruptions and newly described tephra. • The tephra link paleoenvironmental records from this region to the Far East, Greenland and Europe. • Correlated source eruption volumes vary widely; this alone cannot explain recorded ash distribution trends. [ABSTRACT FROM AUTHOR]

Holocene cryptotephras of Alaskan and Pacific Northwestern origin have recently been detected ca. 7000 km away on the east coast of North America. This study extends the emerging North American tephrochronological framework by geochemically characterising seventeen cryptotephra layers from four newly explored peatlands. All detected tephras were deposited during the late Holocene, with no horizons present in the peat between ca. 3000–5000 years ago. The prevalence of the Alaskan White River Ash eastern lobe (AD 847 ± 1) is confirmed across the eastern seaboard from Newfoundland to Maine and a regional depositional pattern from Mount St Helens Set W (AD 1479–1482) is presented. The first occurrences of four additional cryptotephras in eastern North America are described, three of which may originate from source regions in Mexico, Kamchatka (Russia) and Hokkaido (Japan). The possibility of such tephras reaching eastern North America presents the opportunity to link palaeo-archives from the tropics and eastern Asia with those from the western Atlantic seaboard, aiding inter-regional comparisons of proxy-climatic records. [ABSTRACT FROM AUTHOR]

Abstract: Sedimentary deposits from two Middle to Late Pleistocene glaciations and intervening non-glacial intervals exposed along the White River in southwest Yukon, Canada, provide a record of environmental change for much of the past 200 000 years. The study sites are beyond the Marine Isotope stage (MIS) 2 glacial limit, near the maximum regional extent of Pleistocene glaciation. Non-glacial deposits include up to 25 m of loess, peat and gravel with paleosols, pollen, plant and insect macrofossils, large mammal fossils and tephra beds. Finite and non-finite radiocarbon dates, and twelve different tephra beds constrain the chronology of these deposits. Tills correlated to MIS 4 and 6 represent the penultimate and maximum Pleistocene glacial limits, respectively. The proximity of these glacial limits to each other, compared to limits in central Yukon, suggests precipitation conditions were more consistent in southwest Yukon than in central Yukon during the Pleistocene. Conditions in MIS 5e and 5a are recorded by two boreal forest beds, separated by a shrub birch tundra, that indicate environments as warm or warmer than present. A dry, treeless steppe-tundra, dominated by Artemisia frigida, upland grasses and forbs existed during the transition from late MIS 3 to early MIS 2. These glacial and non-glacial deposits constrain the glacial limits and paleoenvironments during the Middle to Late Pleistocene in southwest Yukon. [Copyright &y& Elsevier]

Abstract: Far-travelled volcanic ashes (tephras) from Holocene eruptions in Alaska and the Pacific northwest have been traced to the easternmost extent of North America, providing the basis for a new high-precision geochronological framework throughout the continent through tephrochronology (the dating and correlation of tephra isochrons in sedimentary records). The reported isochrons are geochemically distinct, with seven correlated to documented sources in Alaska and the Cascades, including the Mazama ash from Oregon (∼7600 years old) and the eastern lobe of the White River Ash from Alaska (∼1150 years old). These findings mark the beginning of a tephrochronological framework of enhanced precision across North America, with applications in palaeoclimate, surface process and archaeological studies. The particle travel distances involved (up to ∼7000 km) also demonstrate the potential for continent-wide or trans-Atlantic socio-economic disruption from similar future eruptions. [Copyright &y& Elsevier]