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Herein, an approach for development of a novel FS-PCMCs by incorporation of FAs into the GCA, which was derived from one-step hydrothermal of C-MWCNTs and GO followed by annealing treatment, through a simple direct impregnation. The FS-PCMCs was developed for solar energy storage. [Display omitted] The exploitation of excellent performance form-stable phase change material composites (FS-PCMCs) with enhanced photothermal conversion efficiency and high phase change latent heat is of great significance for thermal energy storage. In this work, a new type of FS-PCMCs with superior light-to-thermal conversion performance were created by impregnation of organic phase change material (1-hexadecylamine (HDA) and 1-tetradecylamine (TDA)) into the graphene aerogel (GA) and all-carbon aerogel (GCA) through a simple direct infusion. The multiwalled carbon nanotubes (MWCNTs) are wound around the inner wall of the GA layer to form a three-dimensional (3D) porous network structure to support fatty amine (FAs), thus achieving shape stability before and after phase transition. Moreover, the FS-PCMCs has extremely high phase transition enthalpy (203.1–248 kJ·kg−1) and good recyclability. More importantly, due to the high absorbance of GCA, it can enhance its light absorption capacity and reduce thermal radiation. The light-to-thermal conversion efficiency of the FS-PCMCs is 72.36%-88.25%. Taking the improvement of the comprehensive properties of the FS-PCMCs, the results of this work may open up a way for rational design and preparation of high-performance FS-PCMCs with enhanced storage capacity and light-to-thermal conversion efficiency for the efficient utilization of solar energy. [ABSTRACT FROM AUTHOR]

The development of high-performance shape-stable phase change materials composites (ss-PCMCs) with enhanced thermal conductivity and high phase change enthalpy is of great importance for thermal energy storage. Herein, we report the creation of novel ss-PCMCs by incorporation of organic PCMs (1-hexadecanamine (HDA) and palmitic acid (PA)) into the biomass carbon aerogels (BCAs refer to sunflower receptacle spongy carbon aerogel (r-CA) and sunflower stem carbon aerogel (s-CA)) through a simple vacuum infusion. Due to their abundant porosity, light weight and high specific surface area, organic PCMs can be spontaneously loaded into BCAs with an ultrahigh loading rate of up to 1988 wt%. The obtained of PCM/BCAs composites show high phase change enthalpy of ranging from 207.9 kJ kg−1 to 271 kJ kg−1, in addition to their excellent thermal stability and recyclability, e.g., their phase change enthalpy nearly remains unchanged even after 50 times of melting/freezing cycles. The PCM/BCAs composites also show an enhanced thermal conductivity. Furthermore, the light-to-thermal conversion efficiency was found to be promising candidates for light-to-thermal energy storage applications on basis of their 75.6% for HDA/r-CA and 67.8% for HDA/s-CA, respectively, making them abundant resource, cost-efficiency, simple and scalable fabrication process. • HDA was first exploited as a new class of phase change material. • ss-PCMCs were fabricated by doping of PCM into biomass carbon aerogels of sunflower. • The HDA/BCAs shows high light-thermal conversion efficiency (67.8%–75.6%). • The loading rate of HDA in BCAs is up to 1988 wt % and 873%, respectively. [ABSTRACT FROM AUTHOR]

The development of high-performance shape-stable phase change materials composites (ss-PCMCs) with enhanced thermal conductivity and high phase change enthalpy is of great importance for thermal energy storage. Herein, we report the creation of novel ss-PCMCs by incorporation of organic PCMs (1-hexadecanamine (HDA) and palmitic acid (PA)) into the biomass carbon aerogels (BCAs refer to sunflower receptacle spongy carbon aerogel (r-CA) and sunflower stem carbon aerogel (s-CA)) through a simple vacuum infusion. Due to their abundant porosity, light weight and high specific surface area, organic PCMs can be spontaneously loaded into BCAs with an ultrahigh loading rate of up to 1988 wt%. The obtained of PCM/BCAs composites show high phase change enthalpy of ranging from 207.9 kJ kg−1 to 271 kJ kg−1, in addition to their excellent thermal stability and recyclability, e.g., their phase change enthalpy nearly remains unchanged even after 50 times of melting/freezing cycles. The PCM/BCAs composites also show an enhanced thermal conductivity. Furthermore, the light-to-thermal conversion efficiency was found to be promising candidates for light-to-thermal energy storage applications on basis of their 75.6% for HDA/r-CA and 67.8% for HDA/s-CA, respectively, making them abundant resource, cost-efficiency, simple and scalable fabrication process. • HDA was first exploited as a new class of phase change material. • ss-PCMCs were fabricated by doping of PCM into biomass carbon aerogels of sunflower. • The HDA/BCAs shows high light-thermal conversion efficiency (67.8%–75.6%). • The loading rate of HDA in BCAs is up to 1988 wt % and 873%, respectively. [ABSTRACT FROM AUTHOR]

Spongy carbon soot (s‐CS) was prepared and used as novel host material of the form‐stable composite phase change materials (PCMs). The s‐CS was constructed by the interconnected and compact large agglomerates of the soot particles with an average size of 25–60 nm. The average pore diameter of the s‐CS was measured to be 15.3 nm. Owing to capillary forces of s‐CS, n‐carboxylic acids can be easily absorbed into the pores and stay stable without leakage. The PCMs/s‐CS composite present a high heat storage capacity between 83.42 J g−1 and 99.63 J g−1, corresponding to the mass fraction of n‐carboxylic acids between 50.10% and 53.20%. The effects of the supporting material on thermal stability and thermal conductivity of composites were investigated by means of thermogravimetry and flash thermal conductivity testing. The PCM/spongy CS composites exhibit excellent thermal stability and durability, and may have great potential for renewable energy saving applications. [ABSTRACT FROM AUTHOR]

In order to improve the energy storage and conversion efficiency of phase change materials, a mixed clay sponge (MCS) containing palygorskite (Pal) and Halloysite Nanotubes (HNTs) was successfully constructed by solution polymerization. Expanded graphite (EG) was used to enhance the overall thermal conductivity and carbonized MCS with EG (mark as EG-MCS, C-EG-MCS). A series of form stable phase change materials (FSPCMs) were prepared by using them as scaffolds and encapsulated organic phase-change material 1-Hexadecylamine (HDA) by direct impregnation. By means of SEM, TEM, FTIR, XRD, XPS, DSC, TG, etc., their microstructure, chemical compatibility and thermophysical properties were systematically studied. The DSC results demonstrate that PCM composites exhibit relatively high thermal energy storage density of 214.2 kJ kg−1, 237.5 kJ kg−1 and 239.2 kJ kg−1 respectively. The reliability test shows that the PCM composites retain shape stability and almost no leakage of HDA even after 200 thermal cycles. Compared with the pure component HDA, the thermal conductivity of the as-prepared C-EG-MCS-HDA was improved from 0.147 W m−1 K−1 to 0.667 W m−1 K−1 and EG-MCS-HDA was improved from 0.147 W m−1 K−1 to 0.454 W m−1 K−1 owing to the high thermal conductivity of EG (only 6 wt%). Besides, the light-thermal conversion efficiency of EG-MCS-HDA and C-EG-MCS-HDA is 74.6%, 80.8% respectively. Therefore, the fabricated FSPCMs with high latent heat, good melting/freezing cycles reliability and high thermal conductivity, remarkable light-thermal energy conversion ability which have a broad application prospect in energy conversion and storage devices. Unlabelled Image • 1-Hexadecanamine (HDA) was first exploited as a new class of organic PCMs. • Form-stable PCMs composites were fabricated based mixed clay sponge. • The as-prepared PCM composites exhibit high light-thermal conversion efficiency. [ABSTRACT FROM AUTHOR]

Renewable pectin and cost-effective palygorskite (Pal) were used as raw materials to prepare hierarchically porous carbonized aerogels. The addition of cations (Ca2+) initiates supramolecular bonding of chains in the polymer and enhances the performance of the aerogel. Unlike the previous fragile biomass porous materials, the carbonized aerogels prepared this time showed excellent mechanical properties, with a compressive strength of up to 0.4 MPa at 80% strain. Dodecylamine (DDA) was loaded into the carbonized aerogel by the melt dipping method to obtain a stable phase change material (PCM) with positive performance. Furthermore, the chemical structure, microstructure, thermal stability, mechanical properties, heat storage performance, and thermal conductivity of carbonized clay/pectin aerogels and those of as-prepared composite PCMs were determined by various characterization techniques. The results demonstrate that inexpensive supporting materials can effectively improve the shape stability and thermal conductivity of composite PCMs. Meanwhile, the composite PCMs possess suitable phase transition temperature, reliable photothermal energy storage capacity, and excellent shape stability. The energy storage capacity and reliability of those cost-effective carbon-based form stable phase change materials (FSPCMs) reveal their tremendous application potential in solar energy utilization. • Resourceful raw materials were prepared as support with a simple method. • Palygorskite enhances the shape stability of composite phase change material (PCM). • Carbonized aerogel has an excellent mechanical property (0.4 MPa at 80% strain). • The composite PCM has a phase change enthalpy of 161.8 kJ kg−1 (after 300 cycles). • The photothermal conversion efficiency of composite PCM enables reach up to 77.5%. [ABSTRACT FROM AUTHOR]