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Your search keyword '"Schleinitz, Jules"' showing total 2 results
Start Over Author "Schleinitz, Jules" Topic thulium
2 results on '"Schleinitz, Jules"'

1. Bis‐Cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single‐Molecule Magnets.

Author

Moutet, Jules, Schleinitz, Jules, La Droitte, Léo, Tricoire, Maxime, Pointillart, Fabrice, Gendron, Frédéric, Simler, Thomas, Clavaguéra, Carine, Le Guennic, Boris, Cador, Olivier, and Nocton, Grégory

Subjects
*SINGLE molecule magnets, *THULIUM, *CHARGE exchange, *RARE earth metals, *ORGANOMETALLIC compounds, *SMALL molecules
Abstract

Divalent lanthanide organometallics are well‐known highly reducing compounds usually used for single electron transfer reactivity and small molecule activation. Thus, their very reactive nature prevented for many years the study of their physical properties, such as magnetic studies on a reliable basis. Herein, the access to rare organometallic sandwich compounds of TmII with the cyclooctatetraenyl (Cot) ligand impacts on the use of divalent organolanthanide compounds as an additional strategy for the design of performing Single Molecule Magnets (SMM). The first divalent thulium sandwich complex with f13 configuration behaving as a single‐molecule magnet in absence of DC field is highlighted. [ABSTRACT FROM AUTHOR]

Published
2021
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2. Bis‐Cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single‐Molecule Magnets

Author

Moutet, Jules, Schleinitz, Jules, La Droitte, Leo, Tricoire, Maxime, Pointillart, Fabrice, Gendron, Frédéric, Simler, Thomas, Clavaguéra, Carine, Le Guennic, Boris, Cador, Olivier, Nocton, Grégory, Andersen, R. A., Laboratoire de chimie moléculaire (LCM), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-École polytechnique (X), Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Institut de Chimie Physique (ICP), Institut de Chimie du CNRS (INC)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), European Research Council (ERC) under the European Union European Research Council (ERC) [716314], ANR (French National Research Agency) French National Research Agency (ANR) [ANR-19-CE07-0019-1], CNRS Centre National de la Recherche Scientifique (CNRS)European Commission, Ecole polytechnique, Strategie d'Attractivite Durable [SAD18006-LnCPLSMM], European Research Council under the European Union European Research Council (ERC) [725184], ANR-19-CE07-0019,RelaxMax,Complexes organométalliques de lanthanides à relaxation magnétique lente(2019), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Lanthanide, Materials science, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, Article, Catalysis, Divalent, Electron transfer, Molecule, [CHIM]Chemical Sciences, Reactivity (chemistry), lanthanides, single-molecule magnets, chemistry.chemical_classification, 010405 organic chemistry, Ligand, General Medicine, General Chemistry, electron transfer, Small molecule, divalent thulium, 0104 chemical sciences, Crystallography, Thulium, chemistry, organometallics
Abstract

International audience; Divalent lanthanide organometallics are well-known highly reducing compounds usually used for single electron transfer reactivity and small molecule activation. Thus, their very reactive nature prevented for many years the study of their physical properties, such as magnetic studies on a reliable basis. Herein, the access to rare organometallic sandwich compounds of Tm-II with the cyclooctatetraenyl (Cot) ligand impacts on the use of divalent organolanthanide compounds as an additional strategy for the design of performing Single Molecule Magnets (SMM). The first divalent thulium sandwich complex with f(13) configuration behaving as a single-molecule magnet in absence of DC field is highlighted.

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