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Abstract: We present the results of six soundings of the atmosphere of Titan by the radio occultation technique using the Cassini spacecraft currently in orbit around Saturn. These occultations occurred during four separate targeted Titan encounters in both the Prime and Equinox missions of Cassini over 3years. They cover a wide range of latitude from 75°S to 79°N, split so that three soundings are in the northern hemisphere and three are in the southern hemisphere. Techniques and error analysis are similar to Schinder et al. (2011). The six temperature-altitude profiles presented here are compared to those earlier results. Of special interest is the sudden cooling observed at altitudes of ∼80–100km in the two high northern (winter) soundings at 74°N and 80°N, where the temperature drops by about 10K over the course of 20km. The northern profiles also exhibit a transition between the troposphere and stratosphere that is much more abrupt than in the south, and the northern tropopause temperatures are much cooler. [Copyright &y& Elsevier]

Abstract: We present results from the two radio occultations of the Cassini spacecraft by Titan in 2006, which probed mid-southern latitudes. Three of the ingress and egress soundings occurred within a narrow latitude range, 31–34°S near the surface, and the fourth at 52.8°S. Temperature–altitude profiles for all four occultation soundings are presented, and compared with the results of the Voyager 1 radio occultation (Lindal, G.F., Wood, G.E., Hotz, H.B., Sweetnam, D.N., Eshleman, V.R., Tyler, G.L. [1983]. Icarus 53, 348–363), the HASI instrument on the Huygens descent probe (Fulchignoni, M. et al. [2005]. Nature 438, 785–791), and Cassini CIRS results (Flasar, F.M. et al. [2005]. Science 308, 975–978; Achterberg, R.K., Conrath, B.J., Gierasch, P.J., Flasar, F.M., Nixon, C.A. [2008b]. Icarus 194, 263–277). Sources of error in the retrieved temperature–altitude profiles are also discussed, and a major contribution is from spacecraft velocity errors in the reconstructed ephemeris. These can be reduced by using CIRS data at 300km to make along-track adjustments of the spacecraft timing. The occultation soundings indicate that the temperatures just above the surface at 31–34°S are about 93K, while that at 53°S is about 1K colder. At the tropopause, the temperatures at the lower latitudes are all about 70K, while the 53°S profile is again 1K colder. The temperature lapse rate in the lowest 2km for the two ingress (dawn) profiles at 31 and 33°S lie along a dry adiabat except within ∼200m of the surface, where a small stable inversion occurs. This could be explained by turbulent mixing with low viscosity near the surface. The egress profile near 34°S shows a more complex structure in the lowest 2km, while the egress profile at 53°S is more stable. [Copyright &y& Elsevier]

In response to ESA's "Voyage 2050" announcement of opportunity, we propose an ambitious L-class mission to explore one of the most exciting bodies in the Solar System, Saturn's largest moon Titan. Titan, a "world with two oceans", is an organic-rich body with interior-surface-atmosphere interactions that are comparable in complexity to the Earth. Titan is also one of the few places in the Solar System with habitability potential. Titan's remarkable nature was only partly revealed by the Cassini-Huygens mission and still holds mysteries requiring a complete exploration using a variety of vehicles and instruments. The proposed mission concept POSEIDON (Titan POlar Scout/orbitEr and In situ lake lander DrONe explorer) would perform joint orbital and in situ investigations of Titan. It is designed to build on and exceed the scope and scientific/technological accomplishments of Cassini-Huygens, exploring Titan in ways that were not previously possible, in particular through full close-up and in situ coverage over long periods of time. In the proposed mission architecture, POSEIDON consists of two major elements: a spacecraft with a large set of instruments that would orbit Titan, preferably in a low-eccentricity polar orbit, and a suite of in situ investigation components, i.e. a lake lander, a "heavy" drone (possibly amphibious) and/or a fleet of mini-drones, dedicated to the exploration of the polar regions. The ideal arrival time at Titan would be slightly before the next northern Spring equinox (2039), as equinoxes are the most active periods to monitor still largely unknown atmospheric and surface seasonal changes. The exploration of Titan's northern latitudes with an orbiter and in situ element(s) would be highly complementary in terms of timing (with possible mission timing overlap), locations, and science goals with the upcoming NASA New Frontiers Dragonfly mission that will provide in situ exploration of Titan's equatorial regions, in the mid-2030s. [ABSTRACT FROM AUTHOR]

Highlights • We fit the spectrum propene in Titan's stratosphere for the first time. • Propene is present in Titan's stratosphere at 3–11 ppbv within 60° of the equator. • Equatorward of 60°, propene is most abundant within 20° of the equator. • Using new line data we propose a 3- σ upper-limit of for allene of 2.5 ppbv. Abstract Of the C 3 H x hydrocarbons, propane (C 3 H 8) and propyne (methylacetylene, CH 3 C 2 H) were first detected in Titan's atmosphere during the Voyager 1 flyby in 1980. Propene (propylene, C 3 H 6) was first detected in 2013 with data from the Composite InfraRed Spectrometer (CIRS) instrument on Cassini. We present the first measured abundance profiles of propene on Titan from radiative transfer modeling, and compare our measurements to predictions derived from several photochemical models. Near the equator, propene is observed to have a peak abundance of 10 ppbv at a pressure of 0.2 mbar. Several photochemical models predict the amount at this pressure to be in the range 0.3–1 ppbv and also show a local minimum near 0.2 mbar which we do not see in our measurements. We also see that propene follows a different latitudinal trend than the other C 3 molecules. While propane and propyne concentrate near the winter pole, transported via a global convective cell, propene is most abundant above the equator. We retrieve vertical abundances profiles between 125 km and 375 km for these gases for latitude averages between 60°S–20°S, 20°S–20°N, and 20°N–60°N over two time periods, 2004 through 2009 representing Titan's atmosphere before the 2009 equinox, and 2012 through 2015 representing time after the equinox. Additionally, using newly corrected line data, we determined an updated upper limit for allene (propadiene, CH 2 CCH 2 , the isomer of propyne). We claim a 3- σ upper limit mixing ratio of 2.5 × 10 − 9 within 30° of the equator. The measurements we present will further constrain photochemical models by refining reaction rates and the transport of these gases throughout Titan's atmosphere. [ABSTRACT FROM AUTHOR]

Abstract: Maps of isotherms on surfaces of constant pressure in Titan''s middle atmosphere encircle the poles but show an offset, implying that the mean zonal flow has an axis of symmetry that is tilted relative to the spin axis of the solid body. The effect is seen in both hemispheres around a consistent axis. Periodogram analysis of the temperature field shows that wavenumber one, the signal corresponding to the spin tilt, is the strongest wave component. We conjecture that the tilt of the atmospheric spin is due to a feedback between the flow and the solar heating. The spin adjusts itself to align the spin equator with the direction toward the Sun, and thereby maximizes the efficiency with which the meridional circulation pumps angular momentum upward to generate superrotation. [Copyright &y& Elsevier]

Abstract: We report here the first detection of mono-deuterated acetylene (acetylene-d1, C2HD) in Titan''s atmosphere from the presence of two of its emission bands at 678 and 519 cm−1 as observed in CIRS spectral averages of nadir and limb observations taken between July 2004 and mid-2007. By using new laboratory spectra for this molecule, we were able to derive its abundance at different locations over Titan''s disk. We find the C2HD value () to be roughly constant with latitude from the South to about 45° N and then to increase slightly in the North, as is the case for C2H2. Fitting the 678 cm−1 band simultaneously with the nearby C2H2 729 cm−1 band, allows us to infer a D/H ratio in acetylene on Titan with an average of the modal values of from the nadir observations, the uncertainties being mainly due to the vertical profile used for the fit of the acetylene band. Although still subject to significant uncertainty, this D/H ratio appears to be significantly larger than the one derived in methane from the CH3D band (upper limit of ; Bézard, B., Nixon, C.A., Kleiner, I., Jennings, D.E., 2007. Icarus, 191, 397–400; Coustenis, A., Achterberg, R., Conrath, B., Jennings, D., Marten, A., Gautier, D., Bjoraker, G., Nixon, C., Romani, P., Carlson, R., Flasar, M., Samuelson, R.E., Teanby, N., Irwin, P., Bézard, B., Orton, G., Kunde, V., Abbas, M., Courtin, R., Fouchet, Th., Hubert, A., Lellouch, E., Mondellini, J., Taylor, F.W., Vinatier, S., 2007. Icarus 189, 35–62). From the analysis of limb data we infer D/H values of (at 54° S), (at 15° S), (at 54° N) and (at 80° N), which average to a mean value of . [Copyright &y& Elsevier]

Abstract: The Composite Infrared Radiometer–Spectrometer (CIRS) instrument, on the NASA Cassini Saturn orbiter, has been acquiring thermal emission spectra from the atmosphere of Titan since orbit insertion in 2004. Observation sequences for measuring stratospheric temperatures have been obtained using both a nadir mapping mode and a limb viewing mode. The limb observations give better vertical resolution, and give information from higher altitudes, while the nadir observations provide more complete longitude coverage. Because the scale height of Titan''s atmosphere is large enough so that emission from a grazing ray is influenced by horizontal temperature variations in the atmosphere, we have developed a two-dimensional temperature retrieval algorithm for reducing the limb spectra, which solves simultaneously for meridional and vertical temperature variations. The analyzed nadir mapping data have sampled nearly all longitudes at latitudes from about 90° S to 60° N, providing temperatures between pressure levels of about 5 to 0.2 mbar. The limb data covers latitudes between about 75° S and 85° N, and yields temperatures between about 1 and 0.005 mbar, at a small number of longitudes. The retrieved temperatures are consistent with early results from nadir observations [Flasar, F.M., and 44 colleagues, 2005. Science 308, 975–978] between 0.5 and 5 mbar where both results are valid, with the warmest temperatures at the equator, and much stronger meridional temperature gradients in the northern (winter) hemisphere than in the southern. At higher altitudes not probed by nadir viewing, the limb data reveal that the stratopause is nearly 20 K warmer in the northern polar regions than at the equator and southern hemisphere, and that the altitude of the stratopause shifts from ≈0.1 mbar (300 km) near the equator to 0.01 mbar (400 km) poleward of about 40° N. When the gradient wind equation is used to construct a zonal mean wind, the reversal in sign of the temperature leads to capping of the winter westerly flow. The core of the resulting jet is about 190 m s−1 in magnitude, spans between 30° N and 60° N, and peaks near 0.1 mbar. Estimates of the radiative heating associated with the radiative disequilibrium lead to a meridional overturning timescale of about three Earth years. [Copyright &y& Elsevier]

Abstract: We have analyzed data recorded by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft during the Titan flybys T0–T10 (July 2004–January 2006). The spectra characterize various regions on Titan from 70° S to 70° N with a variety of emission angles. We study the molecular signatures observed in the mid-infrared CIRS detector arrays (FP3 and FP4, covering roughly the 600–1500 cm−1 spectral range with apodized resolutions of 2.54 or 0.53 cm−1). The composite spectrum shows several molecular signatures: hydrocarbons, nitriles and CO2. A firm detection of benzene (C6H6) is provided by CIRS at levels of about around 70° N. We have used temperature profiles retrieved from the inversion of the emission observed in the methane band at 1304 cm−1 and a line-by-line radiative transfer code to infer the abundances of the trace constituents and some of their isotopes in Titan''s stratosphere. No longitudinal variations were found for these gases. Little or no change is observed generally in their abundances from the south to the equator. On the other hand, meridional variations retrieved for these trace constituents from the equator to the North ranged from almost zero (no or very little meridional variations) for C2H2, C2H6, C3H8, C2H4 and CO2 to a significant enhancement at high northern (early winter) latitudes for HCN, HC3N, C4H2, C3H4 and C6H6. For the more important increases in the northern latitudes, the transition occurs roughly between 30 and 50 degrees north latitude, depending on the molecule. Note however that the very high-northern latitude results from tours TB–T10 bear large uncertainties due to few available data and problems with latitude smearing effects. The observed variations are consistent with some, but not all, of the predictions from dynamical-photochemical models. Constraints are set on the vertical distribution of C2H2, found to be compatible with 2-D equatorial predictions by global circulation models. The D/H ratio in the methane on Titan has been determined from the CH3D band at 1156 cm−1 and found to be . Implications of this deuterium enrichment, with respect to the protosolar abundance on the origin of Titan, are discussed. We compare our results with values retrieved by Voyager IRIS observations taken in 1980, as well as with more recent (1997) disk-averaged Infrared Space Observatory (ISO) results and with the latest Cassini–Huygens inferences from other instruments in an attempt to better comprehend the physical phenomena on Titan. [Copyright &y& Elsevier]

Abstract: Limb spectra recorded by the Composite InfraRed Spectrometer (CIRS) on Cassini provide information on abundance vertical profiles of C2H2, C2H4, C2H6, CH3C2H, C3H8, C4H2, C6H6 and HCN, along with the temperature profiles in Titan''s atmosphere. We analyzed two sets of spectra, one at 15° S (Tb flyby) and the other one at 80° N (T3 flyby). The spectral range 600–1400 cm−1, recorded at a resolution of 0.5 cm−1, was used to determine molecular abundances and temperatures in the stratosphere in the altitude range 100–460 km for Tb and 170–495 km for T3. Both temperature profiles show a well defined stratopause, at around 310 km (0.07 mbar) and 183 K at 13° S, and 380 km (0.01 mbar) with 207 K at 80° N. Near the north pole, stratospheric temperatures are colder and mesospheric temperatures are warmer than near the equator. C2H2, C2H6, C3H8 and HCN display vertical mixing ratio profiles that increase with height at 15° S and 80° N, consistent with their formation in the upper atmosphere, diffusion downwards and condensation in the lower stratosphere, as expected from photochemical models. The CH3C2H and C4H2 mixing ratios also increase with height at 15° S. But near the north pole, their profiles present an unexpected minimum around 300 km, observed for the first time thanks to the high vertical resolution of the CIRS limb data. C2H4 is the only molecule having a vertical abundance profile that decreases with height at 15° S. At 80° N, it also displays a minimum of its mixing ratio around the 0.1-mbar level. For C6H6, an upper limit of 1.1 ppb (in the 0.3–10 mbar range) is derived at 15° S, whereas a constant mixing ratio profile of is inferred near the north pole. At 15° S, the vertical profile of HCN exhibits a steeper gradient than other molecules, which suggests that a sink for this molecule exists in the stratosphere, possibly due to haze formation. All molecules display a more or less pronounced enrichment towards the north pole, probably due, in part, to subsidence of air at the north (winter) pole that brings air enriched in photochemical compounds from the upper atmosphere to lower levels. [Copyright &y& Elsevier]