1. Quinone-Bodipy H-bonding interaction over π-stacking in toluene.
- Author
-
Karmakar A, Mula S, Ghosh K, Chaudhuri T, Shivran N, Banerjee M, and Chattopadhyay S
- Subjects
- Hydrogen Bonding, Magnetic Resonance Spectroscopy, Molecular Structure, Monte Carlo Method, Boron Compounds chemistry, Photochemical Processes, Quinones chemistry, Toluene chemistry
- Abstract
Quinone type compounds (o-chloranil, p-chloranil and DDQ) demonstrate excellent H-bonding interactions with a meso-phenol Bodipy dye (1) in both ground and excited state in a non-polar toluene medium. The spectroscopic detection of isosbestic absorption occurs with both quinones and fullerenes, but only quinones form isoemissive complexes with dye 1. (1)H NMR study and Monte Carlo global minima searching justified the above mentioned results with efficiency.
- Published
- 2015
- Full Text
- View/download PDF