Search

Barium titanate (BaTiO3 or BTO) is a perovskite structure material with interesting intrinsic properties, such as spontaneous ferroelectricity or electro-optical behavior, which strongly depend on thin film crystallinity. For such functional oxide systems, the pulsed-laser deposition (PLD) approach is one promising growth technique due to its precise stoichiometry control of the metals composing the perovskite crystal and higher oxygen environment compared to the classically used molecular beam epitaxy (MBE) approach. In this article, we demonstrate a BTO epitaxial layer by PLD onto an Si(001) substrate thanks to a thin pseudomorphic SrTiO3 buffer layer grown by MBE. In our study, the various investigated PLD parameters show strong impacts on the BTO polarization orientation. Hence, adjusting the growth conditions allows control of the polarization orientation, which is crucial for both electronic and optical applications. In addition, lattice parameter changes of BTO layers are investigated using x-ray diffraction and cross-sectional transmission electron microscopy, which evidenced a correlation between mismatch relaxation and oxygen growth pressure. Finally, with the analysis of BTO C–V curves, the polarization direction transition is demonstrated electrically. [ABSTRACT FROM AUTHOR]

In this work, we present a systematic study of the effect of the stoichiometry of BaTiO3 (BTO) films grown on the Ge(001) substrate by molecular-beam-epitaxy using different characterization methods relying on beam diffraction, including reflection high-energy electron diffraction (RHEED), X-ray diffraction (XRD), and selected-area electron diffraction in transmission electron microscopy. Surprisingly, over a wide range of [Ba]/[Ti] ratios, as measured by the Rutherford backscattering spectrometry, all the BTO layers exhibit the same epitaxial relationship h100iBTO(001)// 〈110〉Ge(001) with the substrate, describing a 45° lattice rotation of the BTO lattice with respect to the Ge lattice. However, varying the [Ba]/[Ti] ratio does change the diffraction behavior. From RHEED patterns, we can derive that excessive [Ba] and [Ti] generate twinning planes and a rougher surface in the non-stoichiometric BTO layers. XRD allows us to follow the evolution of the lattice constants as a function of the [Ba]/[Ti] ratio, providing an option for tuning the tetragonality of the BTO layer. In addition, we found that the intensity ratio of the 3 lowest-order Bragg peaks I(001)/ I(002), I(101)/I(002), and I(111)/I(002) derived from ω-2θ scans characteristically depend on the BTO stoichiometry. To explain the relation between observed diffraction patterns and the stoichiometry of the BTO films, we propose a model based on diffraction theory explaining how excess [Ba] or [Ti] in the layer influences the diffraction response. [ABSTRACT FROM AUTHOR]

The observation and interpretation of Frank stacking faults, Shockley stacking faults, Lomer dislocations, and 60° misfit dislocations, which have similar line shapes in the (001) In0.53Ga0.47As crystalline surface, are performed with the electron channeling contrast imaging (ECCI) technique. To minimize the backscattered electron (BSE) contrast that resulted from the surface morphology, a relatively flat region is first selected and compared with an atomic force microscopy (AFM) image and then, subsequently, examining ECCI with transmission electron microscopy (TEM)‐like invisibility criteria. By orthogonally choosing the diffraction vector g between (220) and (2‐20), misfit dislocations seem to be always visible but partially faint in the g parallel to the line direction on the surface. With respect to the image contrast, Frank stacking faults and Lomer dislocations are likely to be completely invisible for parallel g. The criteria are further confirmed by cross‐sectional TEM analysis, which shows a preferred homogeneous surface nucleation. [ABSTRACT FROM AUTHOR]

Several approaches for growing III-V lasers on silicon were recently demonstrated. Most are not compatible with further integration, however, and rely on thick buffer layers and require special substrates. Recently, we demonstrated a novel approach for growing high quality InP without buffer on standard 001-silicon substrates using a selective growth process compatible with integration. Here we show high quality InGaAs layers can be grown on these InP-templates. High-resolution TEM analysis shows these layers are free of optically active defects. Contrary to InP, the InGaAs material exhibits strong photoluminescence for wavelengths relevant for integration with silicon photonics integrated circuits. Distributed feedback lasers were defined by etching a first order grating in the top surface of the device. Clear laser operation at a single wavelength with strong suppression of side modes was demonstrated. Compared to the previously demonstrated InP lasers 65% threshold reduction is observed. Demonstration of laser arrays with linearly increasing wavelength prove the control of the process and the high quality of the material. This is an important result toward realizing fully integrated photonic ICs on silicon substrates. [ABSTRACT FROM AUTHOR]

• Encapsulation of S-K grown InAs QDs on InP(0 0 1) substrate by InAlGaAs material. • No defect observed inside InAs QDs, at the interfaces, and in the capping layer. • A change in strain distribution observed in InAs QDs after InAlGaAs capping. • InAs QDs' photoluminescence intensity varies in function of capping layer thickness. • A two-step Non-uniform model explains the InAlGaAs capping process of InAs QDs. Stranski-Krastanow (S-K) grown self-assembled quantum dots (QDs) are considered as an efficient active layer for many optoelectronic applications, such as semiconductor laser, photodetector, due to the possibility to confine carriers in three dimensions. Towards the device application, the subsequent growth of an encapsulation layer is a key step to obtain the desired QDs-based heterostructures. In this work, we have studied step-by-step the encapsulation process of S-K grown InAs QDs/InP(0 0 1) by InAlGaAs (lattice matched to InP) in MOVPE. A detailed investigation with Electron Channeling Contrast Imaging (ECCI) and cross-sectional Transmission Electron Microscopy (TEM), indicated that after the InAlGaAs capping the partially relaxed, dome shaped InAs QDs are transformed into fully biaxially strained, truncated pyramids however without introducing any defects in the heterostructure. The study also presents the important role of the capping layer thickness on the QDs photoluminescence efficiency. The gradual change of the surface morphology during the encapsulation process, has been investigated step-by-step in-depth by atomic force microscopy. The morphological changes can be explained by a capping model based on the localized growth rates. We show that two growth steps of Non-uniform capping, where growth rates are different from each other, result in the successful planarization of the InAlGaAs capping without forming any defect. [ABSTRACT FROM AUTHOR]