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Abstract: Recent seafloor mapping around volcanic islands shows that submarine landslide deposits are common and widespread. Such landslides may cause devastating tsunamis, but accurate assessment of tsunami hazard relies on understanding failure processes and sources. Here we use high-resolution geophysical data offshore from Montserrat, in the Lesser Antilles, to show that landslides around volcanic islands may involve two fundamentally different sources of sediment (island-flank and larger seafloor-sediment failures), and can occur in multiple stages. A combination of these processes produces elongate deposits, with a blocky centre (associated with island-flank collapse), surrounded by a smoother-surfaced deposit that is dominated by failed seafloor sediment. The failure of seafloor sediment is associated with little marginal accumulation, and involves only limited downslope motion. Submarine landslide deposits with similar blocky and smooth-surfaced associations are observed in several locations worldwide, but the complex emplacement processes implied by this morphological relationship can only be revealed by high-resolution geophysical data. Such complexity shows that the volume of landslide deposits offshore of volcanic islands cannot simply be used in tsunami models to reflect a single-stage collapse of primary volcanic material. By applying predictive equations for tsunami amplitude to investigate general scenarios of volcanic island landslide generation, we show that the tsunami hazard associated with volcanic island collapse remains highly significant. Volcanic flank failures, even if relatively small, may generate large local tsunamis, but associated seafloor sediment failures, even if they have a much greater volume, have a substantially lower potential for tsunami generation. [Copyright &y& Elsevier]

Abstract: Mt. Etna is a major natural source of Hg to the Mediterranean region. Total mercury concentrations, [Hg]tot, in Castanea sativa (sweet chestnut) leaves sampled 7–13km from Etna''s vents (during six campaigns in 2005–2011) were determined using atomic absorption spectroscopy. [Hg]tot in C. sativa was greatest on Etna''s SE flank reflecting Hg deposition from the typically overhead volcanic plume. [Hg]tot also showed Hg accumulation over the growing season, increasing with leaf age and recent eruptive activity. [Hg]tot in C. sativa was not controlled by [Hg]tot in soils, which instead was greatest on Etna''s NW flank, and was correlated with the proportion of organic matter in the soil (% Org). An elevated [Hg]tot/% Org ratio in soils on Etna''s SE flank is indicative of increased Hg deposition. This ratio was also found to decrease with local soil pH, suggesting that Hg deposited to the low pH and organic-poor soils on Etna''s SE flank may not be retained but will instead be released to groundwater or re-emitted to the atmosphere. These results show that the deposition of volcanic Hg has clear impacts and confirm that Etna is an important source of Hg to the local environment. [Copyright &y& Elsevier]

Abstract: A major uncertainty regarding the environmental impacts of volcanic Hg is the extent to which Hg is deposited locally or transported globally. An important control on dispersion and deposition is the oxidation state of Hg compounds: Hg(0) is an inert, insoluble gas, while Hg(II) occurs as reactive gases or in particles, which deposit rapidly and proximally, near the volcanic vent. Using a new high temperature thermodynamic model, we show that although Hg in Etna''s magmatic gases is almost entirely Hg(0) (i.e., gaseous elemental mercury), significant quantities of Hg(II) are likely formed at Etna''s vents as gaseous HgCl2, when magmatic gases are cooled and oxidised by atmospheric gases. These results contrast with an earlier model study and allow us to explain recent measurements of Hg speciation at the crater rim of Etna without invoking rapid (<1min) low temperature oxidation processes. We further model Hg speciation for a series of additional magmatic gas compositions. Compared to Etna, Hg(II) production (i.e., Hg(II)/Hgtot) is enhanced in more HCl-rich magmatic gases, but is independent of the Hg, HBr and HI content of the magmatic gases. Hg(II) production is not strongly influenced by the initial oxidation state of magmatic gases above NNO, although production is hindered in more reduced magmatic gases. The model and results are widely applicable to other open-vent volcanoes and may be used to improve the accuracy of chemical kinetic models for low temperature Hg speciation in volcanic plumes. [Copyright &y& Elsevier]