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We consider here the validity, accuracy, and precision of rhyolite-MELTS modelling in inferring the pre-eruptive magma storage conditions for the caldera-forming 25.5 ka Oruanui and 232 CE (1.72 ka) TaupÅ eruptions at TaupÅ volcano, New Zealand as proposed by Pamukçu et al. (2020: Contrib Mineral Petrol 175: 48). There are four major issues with the modelling as used. First, the model is inappropriately applied for the TaupÅ event as this magma does not contain phenocrystic quartz. Second, the products of both eruptions, as is typical for virtually all TaupÅ Volcanic Zone rhyolites, contain plagioclase but lack sanidine, leading to increased model errors beyond those stated. Third, temperatures utilised for modelling crystallisation histories for both magmas are in conflict with independent measures of magmatic temperatures for these rocks. Fourth, glass compositions for each of these eruptions individually fall within analytical uncertainty yet yield model pressures that vary over hundreds of MPa, in part due to contrasting analytical protocols. We conclude that rhyolite-MELTS is too imprecise (errors of ± ~ 100 MPa or more for the methods applied) for quartz + 1 feldspar systems like at TaupÅ volcano specifically and the TaupÅ Volcanic Zone in general to be applied with confidence to deriving relative or absolute depths of magma storage., Author(s): Colin J. N. Wilson [sup.1], Simon J. Barker [sup.1], Bruce L. A. Charlier [sup.1], Madison L. Myers [sup.2], Kristian F. Hansen [sup.1] Author Affiliations: (1) grid.267827.e, 0000 0001 2292 [...]

New geochemical data, including Sr–Nd–Pb isotopes for whole-rock and groundmass samples, are reported for edifice-forming eruptives at Tongariro volcano, New Zealand, which span its ~ 350 ka to late Holocene history. Tongariro eruptives are medium-K basaltic-andesites to dacites (53.0–66.2 wt% SiO2) that evolved via assimilation-fractional crystallisation (AFC) processes partly or mostly in the uppermost 15 km of the crust. When ordered chronologically using a high-resolution 40Ar/39Ar-dated eruptive stratigraphy, the compositional data show systematic 10–130 kyr cycles. Mafic replenishment events inferred from MgO values occurred at ~ 230, ~ 151, ~ 88 and ~ 56 ka and in the late Holocene, with high-MgO flank vents erupting at ~ 160, ~ 117, ~ 35 and ~ 17.5 ka. Cycles in Sm/Nd, 87Sr/86Sr, 143Nd/144Nd and Pb isotopic ratios, which are decoupled from MgO, K2O and Rb/Sr cycles, indicate periods of prolonged crustal residence of magmas from ~ 230 to ~ 100 ka and ~ 95 to ~ 30 ka. AFC modelling shows that intermediate and silicic melt compositions, with r-values between 0.1 and 1, are needed to reproduce Tongariro compositional arrays. AFC models also indicate that ~ 20% of the average Tongariro magma comprises assimilated (meta)sedimentary basement material. Locally, Tongariro and adjacent Ruapehu volcanoes attain their most crust-like 87Sr/86Sr and 143Nd/144Nd compositions at ~ 100 and ~ 30 ka, paralleling with zircon model-age crystallisation modes at the rhyolitic Taupō volcano ~ 50 km to the NNE. These coincidences suggest that the timing and tempo of magma assembly processes at all three volcanoes were contemporaneous and may have been tectonically influenced since at least 200 ka. [ABSTRACT FROM AUTHOR]

The transport and degassing pathways of volatiles through large silicic magmatic systems are central to understanding geothermal fluid compositions, ore deposit genesis, and volcanic eruption dynamics and impacts. Here, we document sulfur (S), chlorine (Cl), and fluorine (F) concentrations in a range of host materials in eruptive deposits from Taupō volcano (New Zealand). Materials analysed are groundmass glass, silicic melt inclusions, and microphenocrystic apatite that equilibrated in shallow melt-dominant magma bodies; silicic melt and apatite inclusions within crystal cores inferred to be sourced from deeper crystal mush; and olivine-hosted basaltic melt inclusions from mafic enclaves that represent the most primitive feedstock magmas. Sulfur and halogen concentrations each follow distinct concentration pathways during magma differentiation in response to changing pressures, temperatures, oxygen fugacities, crystallising mineral phases, the effects of volatile saturation, and the presence of an aqueous fluid phase. Sulfur contents in the basaltic melt inclusions (~ 2000 ppm) are typical for arc-type magmas, but drop to near detection limits by dacitic compositions, reflecting pyrrhotite crystallisation at ~ 60 wt. % SiO2 during the onset of magnetite crystallisation. In contrast, Cl increases from ~ 500 ppm in basalts to ~ 2500 ppm in dacitic compositions, due to incompatibility in the crystallising phases. Fluorine contents are similar between mafic and silicic compositions (< 1200 ppm) and are primarily controlled by the onset of apatite and/or amphibole crystallisation and then destabilisation. Sulfur and Cl partition strongly into an aqueous fluid and/or vapour phase in the shallow silicic system. Sulfur contents in the rhyolite melts are low, yet the Oruanui supereruption is associated with a major sulfate peak in ice core records in Antarctica and Greenland, implying that excess S was derived from a pre-eruptive gas phase, mafic magma recharge, and/or disintegration of a hydrothermal system. We estimate that the 25.5 ka Oruanui eruption ejected > 130 Tg of S (390 Tg sulfate) and up to ~ 1800 Tg of Cl, with potentially global impacts on climate and stratospheric ozone. [ABSTRACT FROM AUTHOR]

Taupō volcano (New Zealand) is distinguished as the source of Earth's youngest supereruption (∼25.5 ka), with Lake Taupō occupying the resulting caldera. Taupō has also produced eruptions of a wide variety of sizes, styles and associated landscape responses over a ∼350 kyr period. Early Taupō (>54 ka) is poorly demarcated, merging with Maroa to the north, and is represented by widely scattered, geochemically distinct, effusive domes and explosive eruption products from vents all around the modern lake. Taupō had two independent magmatic systems from 54–25.5 ka, one that led to the Oruanui event focussed beneath the area of the modern lake and a second, northeast of the lake that has remained active to the present. Following the Oruanui supereruption, the rebuilt modern hyperactive Taupō magmatic system is primarily focussed beneath the lake and has generated 25 rhyolitic eruptions since ∼12 ka. The young rhyolite magmas come from an evolving silicic magma reservoir, but vary widely in their eruptive sizes and destructive potential. In the modern era Taupō experiences unrest every decade or so, but uncertainties remain over the nature of the magma reservoir and the processes that drive unrest or eruptive activity that require new geophysical data and interpretations. [ABSTRACT FROM AUTHOR]

The timescales over which moderate to large bodies of silicic magma are generated and stored are addressed here by studies of two geographically adjacent, successive eruption deposits in the Taupo Volcanic Zone, New Zealand. The earlier, caldera-forming Rotoiti eruption (>100 km3 magma) at Okataina volcano was followed, within months at most, by the Earthquake Flat eruption (∼10 km3 magma) from nearby Kapenga volcano; both generated non-welded ignimbrite and coeval widespread fall deposits. The Rotoiti and Earthquake Flat deposits are both crystal-rich high-silica rhyolites, with sparse glass-bearing granitoid fragments also occurring in Rotoiti lag breccias generated during caldera collapse. Here we report 238U–230Th disequilibrium data on whole rocks and mineral separates from representative Rotoiti and Earthquake Flat pumices and the co-eruptive Rotoiti granitoid fragments using TIMS and in situ zircon analyses by SIMS. Multiple-grain zircon-controlled crystallisation ages measured by TIMS from the Rotoiti pumice range from 69±3 ka (<63 μm size fraction) to 76±6 (125–250 μm fraction), with a weighted mean of all size fractions of 71±2 ka. SIMS model ages from single zircons in pumice range from 50±24 ka to >350 ka, with a pronounced peak at 70–90 ka. The weighted mean of isochrons is 83±14 ka, in accord with the TIMS data. One glass-bearing Rotoiti granitoid clast yielded an age of 57±8 ka by TIMS (controlled by Th-rich phases that, however, are not apparently present in the juvenile pumices). Another glass-bearing Rotoiti granitoid yielded SIMS zircon model ages peaking at 60–90 ka, having a similar age distribution to the pumice. Age data from pumices are consistent with a published 64±4 ka eruptive age (now modified to 62±2 ka), but chemical and/or mineralogical data imply that the granitoid lithics are not largely crystalline Rotoiti rhyolite, but instead represent contemporaneous partly molten intrusions reflecting different sources in their chemistries and mineralogies. Similarly, although the Earthquake Flat eruption immediately followed (and probably was triggered by) the Rotoiti event, age data from juvenile material are significantly different. A multiple-grain zircon-controlled crystallisation age measured by TIMS from a representative pumice is 173±5 ka, while SIMS model ages range from 70−26+34 ka to >350 ka, with a peak at 105 ka. These age data coupled with previously published geochemical and isotopic data show that the Rotoiti and Earthquake Flat deposits were erupted from independent, unconnected magma bodies. [Copyright &y& Elsevier]

Understanding the timescales and processes through which magma bodies form and develop in the crust prior to eruption is vital for volcanic monitoring and interpreting future unrest signals, particularly at caldera volcanoes. Here we present the results of a case study on Ōkataina Volcanic Centre, New Zealand, into the timescales of pre-eruptive processes operating during young intra-caldera eruptions, using Fe-Mg interdiffusion profiles in orthopyroxene. Three eruptions covering the three different vent regions, the 15.6 ka Rotorua episode from the Ōkareka Embayment, the 14.0 ka Waiohau episode from Tarawera, and the 5.5 ka Whakatāne episode from Haroharo have broadly similar rhyolitic compositions but show distinctions in their mineralogy and crystal zoning profiles. Back-scattered electron imaging coupled with major-element analyses of orthopyroxene cores and rims imply that open-system mixing and disequilibrium is a common process in the early stages of magma assembly at Ōkataina. Through interpreting mineral chemistry and zoning patterns, we infer that melt segregation, magma body assembly from the source mush and residence in the upper crust takes place on the order of decades up to several centuries, or (if prematurely triggered) as short as months. Priming events such as heating by basaltic injection (common in the Ōkataina rhyolite eruptions) occur over decades prior to eruption. Our findings highlight that multiple processes can dictate the assembly, residence and eruption of melt bodies from the crust and that most magmatic processes occur over timescales that are short enough to be directly relevant to geophysical imaging of magma reservoirs and monitoring initiatives. • Fe-Mg diffusion modelling in orthopyroxenes can indicate the timescales of the pre-eruptive processes driving rhyolitic eruptions. • At Ōkataina, these processes occur on decadal to centennial timescales. • No systematic relationship exists between pre-eruptive timescales and eruption size. [ABSTRACT FROM AUTHOR]