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Volcano sector collapses are catastrophic events that can mobilize huge volumes of material and cause changes in the magmatic plumbing system, leading to variations in growth rate and/or composition. Dating pre-historic volcanic debris avalanche deposits is challenging. Geological materials directly recording avalanche formation and amenable to radiometric dating are rare, and, in the case of Holocene events, the applicable radiometric dating techniques are scarce. Socompa volcano suffered the largest collapse event in the Central Volcanic Zone of the Andes, producing one of Earth's most spectacular and best-preserved volcano avalanche deposits. We apply multiple dating techniques to unravel the timing of Socompa's collapse and gain insights into its pre- and post-collapse eruptive history. The age of the collapse event is constrained by a 14C age of 6,200–6,400 BP of a paleosol buried by the avalanche, and by a post-collapse lava flow dated at 5.91 ± 0.43 ka by zircon double-dating. Bayesian age sequence modeling integrating these ages determines that the collapse occurred at 6.18 - 0.64 + 0.28 ka. Four zircon eruption dates and one unspiked K–Ar age between 69.2 ± 6.0 and 22.1 ± 1.9 ka constrain the age of the youngest stage of activity before the collapse. The ages, together with paleosurface modeling and volume calculations, allow estimating growth rates for the young pre-collapse and post-collapse stages of ~ 0.2–0.3 km3/kyr and ~ 0.5–2 km3/kyr, respectively, indicating a significant increase in activity after the collapse event. The collapse may have triggered a new growth phase or accelerated an ongoing one and was likely associated with a Plinian eruption that produced widespread pumice fallout. The pre- and post-collapse lavas have similar compositions and zircon crystallization age distributions, suggesting that the same or a similar magma reservoir was tapped before and after the collapse. Thus, huge collapses such as Socompa's event can promote increased volcanic activity as a consequence of the unloading effect, but the overall plumbing system may not be affected enough to show significant variations in erupted compositions, at least transiently. Our results highlight the efficacy of the zircon double-dating method for dating very young felsic lavas and for constraining the age of debris avalanche deposits. This is particularly relevant in the Andean Central Volcanic Zone and other regions with arid climates, where organic material is rare and hence 14C dating is often unfeasible. Furthermore, the post-collapse zircon eruption age of 5.91 ± 0.43 ka is the youngest radiometric age yet obtained for a lava flow in the southern Central Volcanic Zone, highlighting the youth of volcanic activity at Socompa, and confirming its status as a Holocene active volcano. [ABSTRACT FROM AUTHOR]

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Cerro Overo maar and La Albóndiga lava dome are two independent monogenetic volcanoes located in the Central Volcanic Zone of the Andes in northern Chile, close to the active Lascar and Chiliques volcanoes. Cerro Overo maar was formed <77 ka ago by explosive-effusive eruptions, including phreatomagmatic activity, while La Albóndiga lava dome (Pleistocene) is the result of magmatic explosive-effusive activity alone. Cerro Overo and La Albóndiga are characterized by deposits composed of pyroclastic rocks and dense coherent lava blocks. At Cerro Overo, these deposits are located around the crater rim, while at La Albóndiga, they form coherent in situ lava dome features. Cerro Overo also displays thin ash- and lapilli-dominated deposit layers presumed to be pyroclastic surge deposits, which include juvenile pyroclasts exhibiting cauliflower textures, numerous exotic accidental lithics, and ballistically transported lapilli, bombs, blocks, and bomb sags. These fragments include recycled, juvenile pyroclasts, as well as material from older volcanic and intrusive rocks from the stratigraphic units immediately below. These small-volume volcanoes represent two of the less silicic volcanoes (~54 wt.% SiO2) in the northern Chilean Pleistocene to Holocene volcanic provinces. They are characterized by a fine grain size (mainly fine lapilli), olivine phenocrysts with skeletal textures, ignimbritic, dioritic, and granitic xenoliths, and quartz xenocrysts, with high concentrations of incompatible trace elements and light rare earth elements. The general magmatic evolution of the Cerro Overo and La Albóndiga systems has been controlled by fast ascent (e.g., skeletal olivine phenocrysts) of mantle-derived magma associated with mixing, fractional crystallization, and a low degree of crustal assimilation during turbulent ascent processes. Such eruptions provide evidence that various factors play an essential role in the transition from explosive-effusive magmatic (Cerro Overo and La Albóndiga) to phreatomagmatic (Cerro Overo) volcanic eruption styles. [ABSTRACT FROM AUTHOR]

Monogenetic volcanoes are small-volume landforms (< 1 km3) which can develop complex eruption histories. Their genesis may include variations in their primary magma sources and petrogenetic evolution, eruption styles transitions, changes in their emplacement conditions. The Central Andes (Northern Chile) contains >900 small-volume volcanoes, most of which lack a detailed knowledge of their eruption histories due to the limited volcanological studies available. In this paper, we present a detailed volcanostratigraphic, morphometric and petrologic study are used to reconstruct the geology and eruptive history of Cerro Negro volcano. It is a Pleistocene pyroclastic cone which stands out from all monogenetic volcanoes of this region due to its larger size (~1 km3) and location along the axis of the orogen. The activity of Cerro Negro began with a phreatomagmatic phase that produced breccias and a lithic-rich tuff, followed by magmatic activity with lava fountaining and Strombolian styles. This latter magmatic phase produced short lava flows, but mostly spatter agglutination and tephra fallout layers. The composition of erupted materials spans from calk-alkaline basaltic andesite to dacite. The least evolved magmas of Cerro Negro are derived from mantle wedge's partial melts without significant crustal assimilation. However, changes in the composition through the eruption suggest crystal fractionation and shallow magma storage, followed by mixing and crustal contamination during the late stage of the eruption. The absence of significant repose period between the deposition of the distinct products and their total volume together with the observed compositional variations imply that Cerro Negro represents a large volume polycyclic monogenetic volcano. These results are important to understand the mafic magma evolution in thickened crusts and the eruptive styles of long-lasting monogenetic eruptions. • Cerro Negro (CNV) is a c. 1 km3 (bulk volume) Pleistocene pyroclastic cone; it classifies as a large monogenetic volcano • CNV erupted in successive phreatomagmatic, lava fountaining and Strombolian phases; the eruption may have lasted years • CNV magmas were calk-alkaline (55.1 to 66.5 wt% SiO 2) and became more silicic as the eruption progressed • Magmas sourced from metasomatized spinel peridotite; polymagmatism involving fractionation, crustal assimilation and mixing [ABSTRACT FROM AUTHOR]

Maar volcanoes are monogenetic landforms whose craters cut below the pre-eruptive surface and are surrounded by a tephra ring. Both the maar crater and the surrounding tephra rim deposits are typically formed due to magma–water explosive interactions. Northern Chile is located in the Central Volcanic Zone of the Andes where, in literature, 14 maars have been recognized as parasite (6) and individual (8) volcanoes. Amongst these individual maars, 3 of them, namely the Tilocálar Sur, Cerro Tujle, and Cerro Overo volcanoes, are not related to calderas and were emplaced <1 Ma ago by magmatic explosive-effusive and phreatomagmatic eruptions. Based on the evolution and control of the volcanic eruptive styles of these three maars, which have been determined in previous research through fieldwork, stratigraphic, morphometric, textural (density and vesicularity), petrographic, and geochemical analyses, a set of key features that favor a prediction of the emplacement location of maar volcanoes in Central Andes, northern Chile are proposed. The set of features that permit and favor the growth mechanisms for maar formations corresponds to (i) a compressive tectonic setting (e.g., ridge structures), (ii) groundwater recharge (e.g., snowmelt and seasonal rainfall), (iii) the lithological setting (e.g., layers of low permeability), (iv) the presence of aquifer and/or endorheic basins (e.g., lakes or salars), and (v) a period of stress relaxation that permits magma ascent to the surface in volcanically active areas. Considering these characteristics, it is possible to identify places where phreatomagmatic eruption can occur. If the magma ascent flux is lower than the groundwater flux, this can lead to a phreatomagmatic eruption because of groundwater coming into contact with the magma. These eruptive features evidence internal—and external—factors that play an essential role in the transition from explosive-effusive magmatic to phreatomagmatic volcanic eruption styles during the same eruptive period that is one of the biggest challenges in volcanic hazard evaluations. Although, in this contribution, a set of features that permit and favor the growth mechanisms for a prediction of the emplacement location of maars in northern Chile is proposed, these considerations could also be applied to identify potential locations in other parts of the world where magma–water interaction eruption could occur. Therefore, this approach could be useful in the prediction of hydromagmatic volcanic eruptions and, thus, in mitigating the impact of volcanic hazard for the inhabitants of the surrounding areas. [ABSTRACT FROM AUTHOR]

UV cameras have been used for over a decade in order to remotely sense SO2 emission rates from active volcanoes, and to thereby enhance our understanding of processes related to active and passive degassing. Whilst SO2 column density retrievals can be more accurate/sophisticated using alternative techniques (e.g., Differential Optical Absorption Spectrometer (DOAS), Correlation Spectrometer (COSPEC)), due to their higher spectral resolutions, UV cameras provide the advantage of high time-resolution emission rates, a much greater spatial resolution, and the ability to simultaneously retrieve plume speeds. Nevertheless, the relatively high costs have limited their uptake to a limited number of research groups and volcanic observatories across the planet. One recent intervention in this regard has been the introduction of the PiCam UV camera, which has considerably lowered instrumental cost. Here we present the first data obtained with the PiCam system from seven persistently degassing volcanoes in northern Chile, demonstrating robust field operation in challenging conditions and over an extended period of time, hence adding credence to the potential of these units for more widespread dissemination to the international volcanic gas measurement community. Small and weak plumes, as well as strongly degassing plumes were measured at distances ranging 0.6–10.8 km from the sources, resulting in a wide range of SO2 emission rates, varying from 3.8 ± 1.8 to 361 ± 31.6 td−1. Our acquired data are discussed with reference to previously reported emission rates from other ground-based remotely sensed techniques at the same volcanoes, in particular considering: resolution of single plume emissions in multi-plume volcanoes, light dilution, plume geometry, seasonal effects, and the applied plume speed measurement methodology. The main internal/external factors that influence positive/negative PiCam measurements include camera shake, light dilution, and the performance of the OpenCV and control points post processing methods. A simple reprocessing method is presented in order to correct the camera shake. Finally, volcanoes were separated into two distinct groups: low and moderate SO2 emission rates systems. These groups correlate positively with their volcanological characteristics, especially with the fluid compositions from fumaroles. [ABSTRACT FROM AUTHOR]

El País is a monogenetic lava flow field located 16 km southeast of Peine town in the Altiplano-Puna area, Antofagasta region, Chile. El País is a monogenetic lava flow field located 16 km southeast of Peine town in the Altiplano-Puna area, Antofagasta region, Chile. El País is composed by lava flows of small-to-moderate volumes, which are fed from individual point sources unassociated with a central volcano of large-volume (stratovolcano) typical of the Andean arc. This lava flow field was emplaced in an area dominated by thin-skinned deformation under a compressive tectonic regime, where multiple volcanic centers (monogenetic and polygenetic volcanoes) have been developed. The volumetric and chemical evolutions were determined by fieldwork, stratigraphic, morphometric, textural (density and vesicularity), petrographic, and geochemical analyses. El País can be divided into three principal mafic lava flows such as Northern-, Main-, and Western-lava flows, which display an E-W orientation. Besides, at least eight ephemeral vents were identified as small erosion remnants of lava emitting point-sources. The identified vents are principally aligned in an ENE-WSW direction, east of the Main lava flow. It is inferred that El País was emplaced near-simultaneously above two ignimbrite sheets: Tucúcaro Ignimbrite (3.2 Ma) and Patao Ignimbrite (3.1 Ma). Stratigraphically, the Main lava flow has a surface texture with strong similarities to an ʻaʻā lava flow, composed of three unique layers well distinguishable in the field such as i) Basal, ii) Top auto-breccia, composed of sub-angular scoriaceous and dense clasts in an oxidized matrix, and iii) A single core between both auto-breccias, composed of dense lavas, exhibiting multiple cooling jointing, such as vertical to platy jointing. The advanced stage of erosion since the formation of El País is evidenced by the poorly preserved lava flows (flat morphology), upper auto-breccia layer, and the presence of large sub-angular blocks of lava (vesicular and dense) along the axis of the lava flows. The eruptive products are geochemically basaltic andesite (Main lava flow and ephemeral vents) and andesite (specifically in the Northern lava flow), making the lava flow field one of the most mafic in the broader region. The lava presents a glomeroporphyric texture, showing at least three different glomerocrysts: i) Plagioclase + clinopyroxene having reabsorption boundaries, ii) Clinopyroxene with reabsorption boundaries, and iii) Plagioclase with sieve-texture. The groundmass is principally composed of glass, plagioclase microlites with a low orientation preference, and opaque minerals (magnetite). This study helps understand the development of dispersed-monogenetic-volcanism (e.g., Tilocálar complex and Cerro Tujle maar), and its relationship with neighboring polygenetic volcanism (e.g., Toloncha stratovolcano) in the Central Volcanic Zone of the Andes, northern Chile. • Different vent location during effusive eruption in lava flow field context. • Ascent rate of basic and intermediate volcanism related with deep source and low magma supply. • Erosion process in dessert climate. [ABSTRACT FROM AUTHOR]

A detailed study on the mineralogy and chemistry of fumarolic deposits with a focus on metals and metalloids is presented. Two active volcanoes in northern Chile, Guallatiri and Lastarria, are characterised by vigorous and persistent fumarolic activity and the formation of zoned fumarolic deposits. Twelve minerals were identified in the studied deposits by X-ray diffraction: anhydrite, barite, gypsum, rhomboclase, orpiment, pyrite, galena, cristobalite, quartz, magnetite, sassolite, and native sulphur. Chemical analyses revealed the presence of 30 chemical elements, including metals and metalloids such as As, Hg, Pb, Sb, Te, and Tl. Backscattered-electron imaging revealed four types of rock textures in the fumarolic deposits: i) massive and poorly vesiculated, ii) highly vesiculated, iii) clastic-like, and iv) flow-like. Micro-chemical analyses showed the presence of cinnabar nataliyamalikite and unidentified mineral assemblages of As S, Te S, Pb S, Hg S, Tl I, and Tl-I-Pb compositions. Based on colour, outlet gas temperature, mineralogy, and chemistry, four distinct zones of fumarolic deposits are identified. (1) Grey zone: sulphide and silicate dominant with minor native elements, high concentrations of Pb and As, and a clastic-like texture (gas outlet temperature > 265 °C). (2) Red zone: sulphide and silicate dominant with minor oxides and native elements, small As, Pb, Tl, I, and Te minerals, and predominance of a flow-like texture (200–280 °C). (3) Yellow-orange zone: dominated by native sulphur and minor borates and sulphur with small As-, Sb-, Hg-, and I-containing minerals, massive and vesiculated texture (80–200 °C). (4) Yellow-white zone: formed by native sulphur, minor borates and As-rich zones, usually displaying a vesiculated texture (<100 °C). • Mineralogy and chemistry of fumarolic deposits of Guallatiri and Lastarria volcanoes are investigated. • Native sulphur is the most common mineral in fumarolic deposits. • Rare As S, Te S, Pb S, Hg S, Tl I, and Tl-I-Pb mineral assemblages were found. • A detailed description of northern Chilean fumarolic deposits is provided. [ABSTRACT FROM AUTHOR]