Search

In this study, carbon nanotube-based adsorbents, oxidized multi-walled carbon nanotube (OMWCNT) with non-magnetic property and OMWCNT-Fe 3 O 4 and OMWCNT-κ-carrageenan-Fe 3 O 4 nanocomposites with magnetic property, having different structural and surface properties were prepared and their adsorptive properties for the removal of toxic diquat dibromide (DQ) herbicide from water by adsorption were determined in detail. For each adsorption system, the effects of initial DQ concentration, contact time and temperature on the adsorption processes were determined. Equilibrium time was found to be 300 min for DQ solutions. OMWCNT showed faster adsorption and higher maximum adsorption capacity value than magnetic adsorbents. With increasing initial herbicide concentration from 5.43 mg.L -1 to 16.3 mg.L -1 , the values of initial sorption rate exhibited a decrease from 29.1 mg.g -1 .min -1 to 4.28 mg.g -1 .min -1 for OMWCNT-DQ system, from 1.21 mg.g -1 .min -1 to 0.823 mg.g -1 .min -1 for OMWCNT-Fe 3 O 4 -DQ system and from 0.674 mg.g -1 .min -1 to 0.612 mg.g -1 .min -1 OMWCNT-κ-carrageenan-Fe 3 O 4 system. Maximum adsorption capacity value of OMWCNT was approximately 2.8-fold higher than magnetic OMWCNT-Fe 3 O 4 and 5.4-fold higher than magnetic OMWCNT-κ-carrageenan-Fe 3 O 4 at 25 °C. Adsorption kinetic and isotherm data obtained for all adsorption systems were well-fitted by pseudo second-order and Langmuir models, respectively. Thermodynamic parameters indicated that the adsorption of DQ onto carbon nanotube-based adsorbents was spontaneous and endothermic process. Furthermore, OMWCNT having the highest herbicide adsorption capacity could be regenerated and reused at least five times. This study showed that carbon nanotube-based adsorbents with magnetic and non-magnetic property were of high adsorption performance for the removal of DQ from water and could be promising adsorbent materials for the efficient removal of herbicides from wastewaters., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

This work reports a study about the adsorption of the herbicides diquat and difenzoquat from aqueous medium employing polyurethane foam (PUF) as the adsorbent and sodium dodecylsulfate (SDS) as the counter ion. The adsorption efficiency was shown to be dependent on the concentration of SDS in solution, since the formation of an ion-associate between cationic herbicides (diquat and difenzoquat) and anionic dodecylsulfate is a fundamental step of the process. A computational study was carried out to identify the possible structure of the ion-associates that are formed in solution. They are probably formed by three units of dodecylsulfate bound to one unit of diquat, and two units of dodecylsulfate bound to one unit of difenzoquat. The results obtained also showed that 95% of both herbicides present in 45mL of a solution containing 5.5mgL -1 could be retained by 300mg of PUF. The experimental data were well adjusted to the Freundlich isotherm (r 2 ≥ 0.95) and to the pseudo-second-order kinetic equation. Also, the application of Morris-Weber and Reichenberg equations indicated that an intraparticle diffusion process is active in the control of adsorption kinetics., (Copyright © 2017 Elsevier Inc. All rights reserved.)

The goal of this work was to propose a novel method for the solid-phase extraction of the herbicides diquat (DQT(2+)) and difenzoquat (DFQT(+)) from aqueous medium using polymeric Amberlite XAD-2 and XAD-4 resins in the presence of sodium dodecylsulfate (SDS). The addition of SDS to the medium was of fundamental importance in order to allow the formation of a negatively charged surface able to sorb the cationic solutes. Several factors that could influence the sorption process, such as SDS concentration in the medium, sorbent mass, pH, ionic strength, and initial concentration of the solutes were investigated. Kinetic studies were also performed to model the system and to identify the mechanisms that operate the sorption process of the herbicides. SDS concentration in the medium presented remarkable influence on the extraction efficiency, achieving maximum values when the ratios [SDS]/[herbicide] were approximately 90, for XAD-2, and 22 and 11 for DQT(2+) and DFQT(+), respectively, for XAD-4. The sorption process followed a pseudo second-order kinetic in all cases studied. It was also found that an intraparticle diffusion process controlled exclusively the sorption of the herbicides by the Amberlite XAD-2 and XAD-4 resins in the first 15 min, becoming less active with time.

To test whether the dose-addition (DA) model can predict the combined toxicity of the mixtures of herbicides that coexisted with insecticide(s), we selected five herbicides (simetryn, prometon, bromacil, velpar, and diquat) and one organophosphorus insecticide (dichlorvos) as the test components. The inhibition toxicities of the six pesticides as well as those of their mixtures to Vibrio qinghaiensis sp.-Q67 were determined by using the microplate toxicity test procedure. The dose-response curves (DRCs) between the observed inhibition toxicities and the doses of the pesticides or the mixtures were modeled by using the nonlinear least square fitting. It was shown that all dose-response relationships were effectively described by the Weibull function. To fully explore the combined toxicities of mixtures including various concentration compositions, we designed three equivalent-effect concentration ratio (EECR) mixtures and six uniform design concentration ratio (UDCR) mixtures. The combined toxicity of a mixture is identified by inspecting whether the DRC predicted by the dose addition (DA) or independent action (IA) locates in the 95% confidence interval of the DRC of the mixture. Furthermore, the possible reason for the three mixtures to depart from the DA action was the very high concentration ratio of diquat in the mixtures.

Using the measures of initial reaction rate, a kinetic-photometric method is developed that uses the reaction of Diquat with H2O2 in basic medium. The reaction rate is very high and therefore the stopped-flow mixing technique is required in order to make kinetic measurements. The reaction rate is obtained in 20 s after the reactants are mixed and it allows the simple application of the method proposed to the routine analyses. The sensitivity of the method is very high being the detection limit 0.44 microgmL(-1) and the application range between 1 and 16 microgmL(-1). The time of measure per sample is 90s. The proposed kinetic-photometric method has been applied to the direct determination of this compound in river water, in the water of laundry of the olives, and in a commercial product. The results are very acceptable.