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High frequency monitoring of water quality and stable isotopes quantify large hydrological and geochemical differences across a rural to urban land use gradient that includes three watersheds and two of their subbasins. Following precipitation events, floods on a rural stream feature hydrographs with low peak discharges and long lag times, high baseflow contributions, and small geochemical variations. In contrast, the flows of an urban stream and its tributary respond in a flashy manner, with average lag times decreasing by at least 55% compared to the rural stream. We also observed that baseflow contributions during floods decreased by an average of 40% in the urban streams. Importantly, we find that reduced baseflow as a function of increasing impervious surface area is not a linear trend among the streams, and suburban streams are less impacted than would be predicted by impervious surface area alone. The urban streams also exhibit large variations in water quality parameters during flooding events, often with five times the variability of the rural end-member. These differences are observed among all physical and geochemical characteristics that were monitored, including flow magnitude, stable isotope ratios, temperature, dissolved oxygen (DO), pH, turbidity, specific conductivity, concentrations of Cl − and nutrients, and bacterial loads. The great variability of urban streams following storms is paralleled by their larger diurnal and seasonal oscillations. Collectively, the extreme variations in the physical and geochemical character of urban streams have negative consequences to environmental quality and aquatic life. [ABSTRACT FROM AUTHOR]

Data from the 1803–1806 Lewis and Clark expedition and nineteenth century stage records are used to quantitatively benchmark natural, premanagement hydrology of the lower Missouri River and assess the magnitude and timing of hydrologic change over nearly two centuries. Data show doubling in daily stage variability from the nineteenth century to 2005. Annual maximum stages have, at some sites, become more extreme, and their seasonality is less regular. Observed changes adversely affect riverine habitat and flood levels; their timing, beginning as early as 1900, suggests that channelization is the major driver. [ABSTRACT FROM AUTHOR]

An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (Al), and sulfate (SO4) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO3), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent. [ABSTRACT FROM AUTHOR]

Editorial. Comments on the nitrate contamination of surface water and groundwater in the U.S. Excess nitrates produced by fertilizer use; Effect of nitrates on water quality; Evidence of excess nitrates becoming nonpoint source pollution.