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The importance of considering groundwater (GW) and surface water (SW) as a single resource of two interconnected components has rapidly increased during the last decades. To investigate GW-SW interaction in an aquifer system exploited by several pumping wells, an integrated continuous monitoring of the hydrological conditions was carried out. The sub-catchment (14 km2), located in the Aspio basin near Ancona (Central Italy), is drained by a small stream named Betelico, and it is characterised by the presence of an unconfined alluvial aquifer and a semi-confined limestone aquifer. The aim of this study is to evaluate the drivers of stream drying up occurred during the last couple of years. This has been achieved by applying a trend analysis on rainfall, air temperatures, piezometric and stream level, and well pumping rates. Precipitation trends were analysed over a 30-years period through the calculation of the Standard Precipitation Index (SPI) and through heavy rainfall events frequency plots, while the correlation between piezometric stream levels and pumping rate was analysed during the last six years. The groundwater level was compared with the stream baseflow level, highlighting the interconnection between GW-SW over the years. The analysis on the water surplus (WS) trend, together with the rainfall events characterisation, supports the hypothesis of the decrease in recharge rate as the main driver of the stream drying up. This case study stresses the importance of studying GW-SW interactions in a continuously changing climatic context characterised by a decreasing precipitation trend, coupling both the advantages of a robust method like trend analysis on time series and the field continuous monitoring.

In the framework of landslides, the hydrogeological features play an essential role in slope stability, governing water movement and thus resulting in modification of the effective stress in the soil. In this framework, the hydrogeological conceptualization of landslide areas and the identification of groundwater origin are key points to developing risk mitigation measures. In fact, groundwater recharge cannot always be attributed to local precipitation alone. Mixing processes between water derived from local infiltration and deep water upflow along tectonic lineaments or anthropogenic water can affect the groundwater balance on a local scale. This study aims to define the potential groundwater origin of one of the highest risk urban landslides in central Italy and to define a hydrogeological conceptual model by exploiting its existing drainage system network. This research is based on a multiple-techniques approach based on hydrological water balance, artificial tracer tests during recharge period, seasonal monitoring of the water stable-isotope content, hydro-chemical survey during low-flow periods, and analysis of the piezometric level fluctuation. All these analyses are coupled with a detailed reconstruction of the geology of the area depicted from boreholes and drill holes. Two groundwater bodies have been evidenced from the study. The shallower one is located in the landslide unstable zone and is hydraulically connected to a deeper groundwater body hosted in the underlying bedrock. Results highlighted that the local rainfall regime could not fully explain the hydro-chemical facies. Local water contributions to the landslide area coming from leakage of the urban sewerage system have been evidenced, excluding deep groundwater upflow from the fault system.

Nowadays, the balance between incoming precipitation and stream or spring discharge is a challenging aspect in many scientific disciplines related to water management. In this regard, although advances in the methodologies for water balance calculation concerning each component of the water cycle have been achieved, the Thornthwaite–Mather method remains one of the most used, especially for hydrogeological purposes. In fact, in contrast to physical-based models, which require many input parameters, the Thornthwaite–Mather method is a simple, empirical, data-driven procedure in which the error associated with its use is smaller than that associated with the measurement of input data. The disadvantage of this method is that elaboration times can be excessively long if a classical MS Excel file is used for a large amount of data. Although many authors have attempted to automatize the procedure using simple algorithms or graphical user interfaces, some bugs have been detected. For these reasons, we propose a WebApp for monthly water balance calculation, called WaterbalANce. WaterbalANce was written in Python and is driven by a serverless computing approach. Two respective European watersheds are selected and presented to demonstrate the application of this method.

Carbonate aquifers are characterised by strong heterogeneities and their modelling is often a challenging aspect in hydrological studies. Understanding carbonate aquifers can be more complicated in the case of strong seismic events which have been widely demonstrated to influence groundwater flow over wide areas or on a local scale. The 2016–2017 seismic sequence of Central Italy is a paradigmatic example of how earthquakes play an important role in groundwater and surface water modifications. The Campiano catchment, which experienced significant discharge modifications immediately after the mainshocks of the 2016–2017 seismic sequence (Mmax = 6.5) has been analysed in this study. The study area is within an Italian national park (Sibillini Mts.) and thus has importance from a naturalistic and socio-economic standpoint. The research strategy coupled long-period artificial tracer tests (conducted both before and after the main earthquakes), geochemical and discharge analyses and isotope hydrology with hydrogeological cross-sections. This study highlights how the seismic sequence temporarily changed the behaviour of the normal faults which act predominantly as barriers to flow in the inter-seismic period, with water flow being normally favoured along the fault strikes. On the contrary, during earthquakes, groundwater flow can be significantly diverted perpendicularly to fault-strikes due to co-seismic fracturing and a consequent permeability increase. The interaction between groundwater and surface water is not only important from the point of view of scientific research but also has significant implications at an economic and social level.

Environmental isotopes are essential in hydrogeological studies, thanks to their contribution to the understanding of aquifers dynamics, vulnerability, water resources assessment, and management issues. The environmental isotopic approach plays a vital role in tracing the hydrological cycle and identifying various sources of contamination in the environment and gives independent information concerning what can be determined by a traditional hydrogeological study. Even in the framework of COP-26, isotopes have been indicated as fingerprints of climate change and therefore suitable for the evaluation of water balance and assessment of processes involved therein; in pollution studies they are used as fundamental support of traditional geochemical measures. Tritium, in particular, has been used since the 1960s to identify potential leaks in the containment walls of waste disposal sites, since its presence in the leachate (at very high levels in some cases) depends on the incorrect waste disposal of some peculiar items. Its use as a tracer of pollution by landfills is highlighted and emphasized by the very low concentrations of tritium in the natural environment. By comparing tritium content of leachate to that of water downflow from the waste disposal site, it is therefore possible to establish with a good success rate whether leachate have migrated or not out of the landfill, in the surrounding environment. An additional potential of tritium is to give a prompt indication of pollution risk in the environment indicating leaching even before the chemical indicator of pollution can be detected. This article wants to provide a contribution to the scientific community, collecting all the existing research in this field and providing data and benchmarks about this method, in particular stressing the role of tritium as an indicator of leachate transfer out of waste disposal sites.