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The analyses to determine the state of preservation of waterlogged archaeological wood follow three different directions: anatomical analyses, physical evaluation and chemical characterisation. Physical parameters (densities and moisture content) are the ones most frequently found in the specialised literature. The measurement of moisture content is normally referred as maximum water content (MWC) in the case of archaeological wood in waterlogged conditions, because wood has been long-time preserved by the lack of oxygen in waterlogged conditions. Aim of the paper is the comparison of three pre-measurement treatments in the calculations of MWC: without any vacuum-pressure treatment, after 300 mbar vacuum pressure and after 50 mbar impregnation in water. The evaluations were performed on 240 samples of waterlogged archaeological wood coming from different excavation sites and including different wood species (both hardwoods and softwoods) in different state of preservation, from low to very high decay. The three tested methodologies to measure the maximum water content on waterlogged archaeological wood provided substantially equivalent results. Nevertheless, a deeper analysis of the results showed that the MWC values of 300 mbar impregnations were rather low compared to MWC standard measurements. Thus, this impregnation was a little bit harsher, causing most probably an anatomical damage on a portion of most degraded samples. The opposite result was obtained after the 50 mbar impregnation procedure. In this case, the MWC values were slightly higher. This means that this treatment seemed to be more effective in subtracting even the smallest air bubbles trapped inside waterlogged archaeological wood samples. Some suggestions on how to measure MWC on waterlogged archaeological wood are detailed at the end of conclusions. [ABSTRACT FROM AUTHOR]

The present paper deals with wood from Venice historic centre foundation elements. Samples were taken from both piles and planking (horizontal elements positioned above the pile heads), in 5 out of 6 districts of Venice. Considering the watery milieu, the diagnostic methodology for waterlogged archaeological wood was adopted, performing anatomical, chemical and physical characterisations. Our results show that the wood used for Venetian foundation elements belong to a small group of 5–6 species (alder, larch, oak, pine, elm and spruce, although the latter was probably of more recent introduction). Most of the analysed samples evidenced decay, which in some cases was high (residual basic densities of only 32%, and values of the ratio holocellulose to lignin as low as 0.3). It was evidenced how the state of preservation of wood was related to several factors, including: thickness of the element, depth of burial, horizontal/vertical position, and wood species. It was also shown how ash content does not reflect the state of preservation of waterlogged material, as it is sometimes reported in the literature. The diffuse decay was apparently not related to the general stability of the buildings under study. [ABSTRACT FROM AUTHOR]

Abstract: Artefacts made of wood coming from archaeological excavations provide insights into human cultural behaviour of the past. They show how man utilised natural resources and how the development of woodworking techniques and artistic endeavour were developed. Within archaeological contexts, waterlogged anaerobic conditions generally preserve the appearance of artefacts, although wood is subject to severe decay processes. The said conditions can transform the original material into a new one, thus demonstrating specific differences from those of the “fresh” wood of the same species. In order to assess these new properties correctly, an integrated diagnostic approach is needed, one which includes a multidisciplinary (micromorphological, physical and chemical) evaluation of the state of preservation. This paper reports several diagnostic results regarding wood artefacts coming from a series of archaeological excavations carried out in Italy. Different types of artefacts – ships, furniture, foundation piles, etc. – that date to different eras (Roman times, the Middle Ages, the Renaissance) have been included in this study. In addition, several species of wood at different levels of decay were analysed. Our study provides evidence of how a multidisciplinary approach, based on anatomical (micromorphological), physical and chemical analyses, avoids goes beyond the limits of each single type of analysis, thus contributing to a complete and reliable evaluation of the state of preservation of these archaeological artefacts. [Copyright &y& Elsevier]

This paper outlines the physical characterisation of findings of woods from the excavation of the Etruscan–Roman ancient harbour of Pisa. The physical characterisation deals with measurements of wood density, shrinkages and maximum water content. The measurements are performed with a methodology specifically set up for the archaeological wet material, not applicable as standardised international methodologies. Physical characterisation is necessary to measure the wood decay, through a useful decay index, and to define the consolidation strategies for the recovery of the wooden findings, for their conservation and enjoyment. Results confirm the high decay of wood samples, probably due to the almost complete loss of the cellulose fraction of the cell walls, shown by the very low basic density (average value less than 0.2 g/cm3) and the high water content (more than 500%). The parameter of the residual basic density seems less useful for the identification of the consolidation strategy. [Copyright &y& Elsevier]

Abstract: The aim of the work is to set up a methodological approach to verify the effectiveness of the treatments of decayed waterlogged archaeological wood and to point out the proper thermo-hygrometric conditions for its preservation after treatment. The treatments were performed on wood samples of maritime pine (Pinus pinaster Aiton), oak (Quercus sp. caducifolia), elm (Ulmus cf. minor) and strawberry tree (Arbutus unedo L.), obtained from stems pertaining to the original vegetation found in the excavation site of the Ancient Ships in Pisa (Italy), and dated from seventh century BC to second century AD The utilised products were: Polyethylene Glycols (PEG) of various molecular weights, a Polypropylene Glycol (PPG 425), Trehalose (α-D-glucopyranosyl-α-D-glucopyranoside), and their mixtures, and also a Hydroxypropylcellulose (Klucel). The main objective to be pursued by the treatments was considered the stabilisation of the original size and shape of samples. The various steps of this approach were: the execution of a preliminary diagnostic survey on untreated samples; the characterisation of treatment solutions ‘as such’ to establish the property to be monitored during the treatment; the evaluation of the main physical characteristics of wood after the treatment were determined. Among the latter, the coefficient of dimensional stability during the exposure to a series of selected thermo-hygrometric conditions and the retention of consolidants after the treatment. These two measurements allowed the definition of the ‘efficacy of a treatment’, φ T , a new parameter firstly utilised in this work. It measures the stabilisation capability of the percent unit of retained product, and its value permits to put in evidence the consolidants that stabilise wood with the lowest amount of product. Conversely, it was not possible to measure the Anti-Shrink Efficiency (ASE), one of the most utilised parameters for the evaluation of treatments, because of the serious distortions and fractures observed in all the heavily degraded untreated samples. [Copyright &y& Elsevier]

Huaguangjiao І is a Chinese ancient wooden shipwreck of South Song Dyansty (1127–1279 AD). Wood samples from Huaguangjiao І were analyzed in order to evaluate the preservation state of the waterlogged wood. Samples were studied from the anatomical, physical and chemical point of view. Thin slides of cross and longitudinal sections from samples were observed by optical microscope, micromorphological decay was classified into class 3 or class 4 according to the anatomical characters. Water content and basic density were measured. Maximum water content (MWC) of the wood samples is between 300% and 600%, residual basic density is about 50%. The proportion of the α-cellulose decreased to 25% of the normal value, and the content of the ash increased greatly. These results indicate the degradation of the wood is very high. In addition, there is a plenty of inorganic deposit in the wood structure. The inorganic compounds deposited in wood samples were analyzed by XRD and ICP qualitatively and quantitatively. The morphology and composition of the inorganic deposit was characterized through SEM-EDS, the majority were iron sulfide, including pyrite and marcasite (FeS 2 ), and fluorite (CaF 2 ). [ABSTRACT FROM AUTHOR]

Abstract: Some acetone-carried consolidants for waterlogged archaeological wood were tested in order to evaluate treatments able to save time and energy. In details, colophony (rosin), two esterified colophonies (Rosin 100® and Rosin 459®), a mixture of colophony with PEG 3400 and a vinyl acetate - vinyl versate copolymer (Vinavil 8020S®) were tested. The treatments were carried out at temperatures of 20 and 35 °C on waterlogged maritime pine, elm, oak and beech. The materials came from the archaeological site of the ancient ships of Pisa (Tuscany, Italy) and were dated back to VII cent. BC – II cent. AD. To evaluate the processes, equilibrium moisture content and dimensional stability of treated wood samples at different relative humidity, and retention of impregnating products were measured; moreover macroscopic and microscopic examination were also run to respectively assess the shape and appearance of treated wood and the way of deposition of consolidants. The results highlighted that natural and modified colophony treatments gave the most satisfactory results both in the maintenance of shape and dimensions of samples and in the stabilization with respect to RH variations. Moreover, the equilibrium moisture contents of samples treated with R100 and R459 were much reduced in comparison to the other consolidants and to untreated archaeological wood. This fact was related to the high retention values of those products that occluded most of the porosity including the microporosity of cell walls. Therefore, in terms of higroscopicity treated wood was more similar to impregnating substances rather than to decayed wood. This fact was considered helpful in contrasting the moisture-related negative effects in cases of eventual faults in the climate control during e.g. exhibition and in protecting treated wood from the risks of new fungal attacks. [Copyright &y& Elsevier]