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Abstract In areas with extensive soil erosion, there is a need to identify the sources supplying sediment to rivers in order to improve our understanding of erosion processes and to guide the implementation of effective soil management measures. Geochemical elements are often used as tracers in sediment fingerprinting studies. Among them, P has often been used as it may specifically trace sediment originating from cropland. Although P-fractions can provide more detailed information than the total P content, their potential to distinguish between different potential sources of sediments has rarely been tested. The objective of the current research was to evaluate the contribution of sediment sources in a rural catchment (Arvorezinha, 1.23 km2) of Southern Brazil, using different sets of tracers (i.e. P-fractions only, geochemical tracers only, and a combination of both tracers). Three potential sediment source types were identified in the catchment: (i) cropland, (ii) unpaved roads and (iii) stream channel banks. Thirty-one suspended sediment samples were collected in the river draining this catchment during 9 significant floods between 2009 and 2011. Estimates of P-fractions were obtained by Hedley fractionation using anion exchange resin membrane (P resin); 0.5 mol L−1 NaHCO 3 (pH 8.5) (P bic); 0.1 mol L−1 NaOH (P NaOH0.1); 1.0 mol L−1 HCl (P HCl); 0.5 mol L−1 NaOH (P NaOH0.5); and residual P (P residual). Total organic (P org) and inorganic P (P inorg) were obtained by the ignition method. The concentrations of P HCl , P NaOH0.5 and P inorg in suspended sediments were higher than those found in the sources. Accordingly, these fractions were considered not to be conservative and were excluded from further analysis. With the exception of P residual , all P-fractions passed the Kruskal-Wallis H -test and were considered as potential tracers of sediment sources. When the P-fractions were combined with geochemical tracers, the discrimination power was much higher than when using geochemical tracers only. The Mahalanobis distance was 9% higher than that observed in the geochemical approach. The calculated contribution of sediment sources using the three approaches was very similar, and cropland was the dominant source of sediment, with calculated contributions of 56 ± 19, 46 ± 16 and 48 ± 16% for those approaches based on geochemical elements, P-fractions, and geochemical + P-fractions, respectively. These results demonstrate the effectiveness of some P-fractions to trace potential sediment sources in rural catchments, as they have a high discriminant power while remaining conservative during sediment transport in the catchment. Graphical abstract Unlabelled Image Highlights • Combining P-fractions with geochemical tracers increased the discrimination power. • P-fractions alone provided results similar to those obtained with geochemical tracers. • Three P-fractions in suspended sediments were considered non-conservative. • All P-fractions were considered as potential tracers of sediment, except residual P. [ABSTRACT FROM AUTHOR]

Abstract: Sediments produced from eroding cultivated land can cause on‐site and off‐site effects that cause considerable economic and social impacts. Despite the importance of soil conservation practices (SCP) for the control of soil erosion and improvements in soil hydrological functions, limited information is available regarding the effects of SCP on sediment yield (SY) at the catchment scale. This study aimed to investigate the long‐term relationships between SY and land use, soil management, and rainfall in a small catchment. To determine the effects of anthropogenic and climatic factors on SY, rainfall, streamflow, and suspended sediment concentration were monitored at 10‐min intervals for 14 years (2002–2016), and the land use and soil management changes were surveyed annually. Using a statistical procedure to separate the SY effects of climate, land use, and soil management, we observed pronounced temporal effects of land use and soil management changes on SY. During the first 2 years (2002–2004), the land was predominantly cultivated with tobacco under a traditional tillage system (no cover crops and ploughed soil) using animal traction. In that period, the SY reached approximately 400 t·km−2·year−1. From 2005 to 2009, a soil conservation programme introduced conservation tillage and winter cover crops in the catchment area, which lowered the SY to 50 t·km−2·year−1. In the final period (2010–2016), the SCP were partially abandoned by farmers, and reforested areas increased, resulting in an SY of 150 t·km−2·year−1. This study also discusses the factors associated with the failure to continue using SCP, including structural support and farmer attitudes. [ABSTRACT FROM AUTHOR]

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Purpose: The impact of agriculture on water resources has long been a problem associated with the formation of runoff, the siltation of lakes and reservoirs, and overall depletion of water quality. In Brazil, these problems are mainly related to soil degradation by water erosion. However, studies of catchment-scale erosion are still rare particularly in grain-producing regions which have adopted conservative tillage systems for soil protection. In order to contribute to a better understanding of the impact of conservation agriculture on water resources, this study determined the runoff coefficient and sediment yield for two agricultural catchments. Materials and methods: Hydrological and sedimentological monitoring was conducted in two catchments: the Conceicao catchment is characterized by grain production in weathered soils and a gently sloping landscape, while the Guapore catchment is characterized by heterogeneous soils and topography. Both catchments have problems associated with water erosion. Results and discussion: The magnitudes of annual runoff coefficients and sediment yield were high, even if compared to similar agricultural regions, including a catchment with widespread adoption of no-tillage. The sediment yield was 140 t km year, and the runoff coefficient was 14 % for the Conceicao catchment, while the sediment yield was 270 t km year, and the runoff coefficient was 31 % for the Guapore catchment. The results indicate that problems such as gullies, soil compaction, runoff, floods, siltation, and water quality depletion associated with the misuse of agricultural areas in terms of soil conservation and water use are still evident and important even in regions with widespread adoption of no-tillage systems. Conclusions: The magnitudes of both runoff and sediment yield clearly indicate the need to adopt complementary practices of soil conservation measures, such as mechanical runoff control. [ABSTRACT FROM AUTHOR]

Purpose: Hydrosedimentological modeling is a tool that can be used to understand better important processes occurring at the catchment scale, such as runoff and sediment yield. The aim of this study was to use the Limburg Soil Erosion Model (LISEM) to describe the runoff and sediment yield during rainfall-runoff events in a small rural catchment in southern Brazil. Materials and methods: The study was conducted in the Lajeado Ferreira Creek catchment (drainage area of 1.19 km) where intense land use has caused a negative impact on water resources. Thirteen rainfall-runoff events that occurred in 2010 and 2011, including high-magnitude events, were used to model hydrosedimentological processes. Results and discussion: Results: from the calibration and validation stages indicate that the model had a good performance when representing the hydrograph, including events with greater complexity. The use of a second soil layer in the model increased its efficiency, which is in accordance with the importance of subsurface flow in this catchment and its sensitivity to the physical properties of the soil, which are essential for controlling hydrosedimentological processes at the catchment scale. The simulation of sediment yield was overestimated by the model, constrained by the lack of sensitivity of the model to soil cohesion and the stability of soil aggregates. During the model calibration stage, these parameters had values different from those measured in the field. Conclusions: The LISEM model performed well in representing runoff for events of different magnitudes. The discretization of the physical-hydrologic properties in the soil profile enabled the evaluation of the effect of subsurface impediment layers on water infiltration and runoff. The simulation was less accurate for suspended sediment concentration than for runoff. This indicates the need for further studies to either identify other factors controlling erosion and sediment yield that have not been identified by the model, or identify if the representation of the physical parameters is inadequate, especially the values of soil cohesion and aggregate stability. [ABSTRACT FROM AUTHOR]

Purpose: Information on the effects of eucalyptus forests on hydrosedimentological processes is scarce, particularly at the catchment scale. Monitoring and mathematical modeling are efficient scientific tools used to address the lack of information for natural resource management and the representation and prediction of those processes. This study evaluates the effects of eucalyptus cultivation on hydrosedimentological processes in watersheds and to use the Limburg soil erosion model (LISEM) to represent and predict hydrological processes. Material and methods: The study was conducted in two forested watersheds: the main watershed (94.46 ha) and a nested sub-watershed (38.86 ha), both cultivated with eucalyptus and residual riparian native forest, located in southern Brazil. Hydrosedimentalogical monitoring was conducted from 16th February 2011 to 31st December 2012, and LISEM model calibrations were performed on the bases of six storms events. Results and discussion: The sediment yield for 2011 was 41.6 Mg km and 38.5 Mg km for the watershed and sub-watershed, respectively. An extreme event in 2012 provided greater sediment yield for the sub-watershed (99.8 Mg km) than that for the watershed (51.7 Mg km). Rainfall events with a greater maximum intensity generated rapid discharge and suspended sediment concentration responses in the sub-watershed due to the smaller drainage area and steeper landscape. In the main watershed, the accumulation of flood waves occurred for most events, with less steep hydrographs, and a later occurrence of the discharge peak after that of the sub-watershed. The LISEM adequately reproduced the peak discharge and runoff for the calibrated events; however, the peak time and the shape of the hydrograph were not adequately represented. Conclusions: The hydrosedimentological patterns of the watershed and sub-watershed, both cultivated with eucalyptus, was characterized by sedimentographs preceding hydrographs during rainfall-runoff events where scale effects occur, with maximum discharge and specific sediment yield greater in the watershed than that in the sub-watershed. Empirical models based on hydrologic variables may be used for estimating the suspended sediment concentration and sediment yield. Therefore, LISEM may be used for the prediction of hydrological variables in these forested watersheds. [ABSTRACT FROM AUTHOR]

An important step in the sediment source fingerprinting approach is the selection of the appropriate tracing parameters to maximise source discrimination. In order to reduce uncertainties and increase discrimination between sources it may be necessary to use multiple tracing parameters. Accordingly, this study investigates the discrimination and apportionment of sediment sources in a rural agricultural catchment obtained by combining colour, magnetic, and geochemical fingerprinting approaches. The Conceição River catchment (804 km²) has predominantly deep and highly weathered Ferralsols with land-use consisting of croplands (73%), pastures (18%), forests (8%) and other uses (1%). A total of 189 samples were taken from the main sediment sources, including: Croplands (CR, n=78), pastures (P, n=24), unpaved roads (UR, n=38), gullies (G, n=15) and stream bank (SB, n=34). Sediment samples were taken from the surface bed (n=10) of the river and with time integrated samplers (n=4). Twenty-two geochemical tracers, 6 magnetic properties and 24 colour parameters were analyzed. Tracers were selected following a three step procedure, including: (i) a conservative range test (95% confident interval), (ii) a Kruskal–Wallis H test, and (iii) discriminant function analysis (DFA). The DFA was performed using four different sets of variables: (i) geochemical variables only (G); (ii) geochemical+magnetic+colour (GMC); (iii) geochemical+colour (GC); (iv) geochemical+magnetic (GM). The selected tracers were introduced into a modified version of the classical Solver-based mixing model that in order to determine the relative contribution of different sources to in-stream sediment through simultaneously minimizing mixing model difference. The G and GC DFAs both resulted 69% of samples correct classified (SCC) as no colour parameters were selected by the DFA. The GMC and GM approaches improved the discrimination, both resulting in 76% of SCC. For the G and GC approaches, the average source contribution for the 12 sediment samples were P 47%, SB 29%, CR 19%, UR 5% and G 0%. For the GMC and GM approaches, the contribution of each source was P 41%, SB 37%, CR 14%, UR 8% and G 0%. These results are counterintuitive to field observations where cropland is anticipated to contribute more sediment than pastures. Future research should use artificial mixtures to validate these results. Both magnetic and colour parameters hold potential to improve discrimination between sources, particularly magnetic parameters in catchments with high weathered soils. [ABSTRACT FROM AUTHOR]

Information on the main sources supplying deleterious sediment loads to river systems is needed to improve our understanding of soil erosion processes to better target erosion control measures. In particular, it is important to quantify the respective contributions of surface and subsurface sources to material degrading waterbodies. Radiocesium (137Cs), emitted during thermonuclear bomb testing (~1950–1980) and nuclear accidents provides significant discrimination between surface material exposed to atmospheric fallout and subsurface material sheltered from it. A systematic worldwide review of research articles (n = 123) that used 137Cs to trace sediment sources showed that the United Kingdom (n = 24), Australia (n = 23) and the United States (n = 20) had the highest number of publications utilizing 137Cs in a sediment tracing framework. In contrast, few studies were published for catchments in Africa (n = 9) or South America (n = 2). In the northern hemisphere, positive relationships were evident between 137Cs activities in surface and subsurface sources and the proportion of thermonuclear bomb fallout. However, given the low proportions of fallout received in regions between 0 and 20°N and 0–20°S, the potential application of 137Cs tracing techniques may be limited in this area of the world as well as in agricultural regions with severe soil erosion (i.e. Chinese Loess Plateau and South Africa). In total, 94% of the studies researching surface and subsurface sources that analysed 137Cs as a potential tracing property included this parameter in end-member mixing models. The main challenges for the future of this technique are related to the access to ultra-low background gamma spectrometry facilities and the development of surrogate tracers. Future research should ensure that basic catchment information and details on the sampling design are properly documented to ensure studies are reproducible. Moreover, researchers should provide raw measurement data to help improve our global understanding of 137Cs dynamics in soil erosion research. • The meta-analysis compiled 123 articles considering 137Cs for sediment tracing. • 70% of these studies were conducted in Europe, North America and Australia. • Fallout levels are too low in regions near the Equator and with extensive erosion. • 137Cs was included in 71 to 94% of studies modelling source contributions. • Future research should systematically include details on sampling design. [ABSTRACT FROM AUTHOR]

Most existing erosion models implicitly assume that runoff is generated due to infiltration excess, i.e. Hortonian overland flow. However, at catchment scale the dynamics is more complex because there exist others water sources and process involved, for example, translatory, return, and macropore flow, which can move slowly from soil towards to catchment outlet. Therefore, those must be included in studies of flow dynamics and description of erosion process. Because an error at representation of water sources can lead to errors on erosion process modelling, when slowly movements, are the main contributor at catchment outlet. Thus, we aim to investigate the role played by water sources in the catchment and how it may affect the process-based erosion models performance. The study was conducted in Arvorezinha catchment, Brazil, and has a drainage area of ca. 1.23 km². Currently, the catchment is characterized by the cultivation of tobacco, especially through the minimum cultivation system. Accumulated rainfall is measured in a rain gauge and used as a reference to adjust the measurements of two pluviograph. Monitoring of water discharge (Q) and suspended sediments concentration (SSC) is performed in the outlet of the catchment through a Parshall flume with a limnigraph and turbidimeter, respectively. Using dissolved silicon concentration (DSi) the hydrograph can be separated into two components: i) surface runoff, i.e., fast movement water (new water) and ii) groundwater+soil water, i.e., slow movement water (old water). Twenty-six samples were collected during subsurface+base flow conditions to characterize DSi in groundwater+soil water from 9/7/2011 to 9/7/2012. Sampling during events started on 10/01/2011 and lasted until to 10/26/2013, in total six rainfall events to characterize surface runoff. An aliquot of each sample (sediment + water) was collected and filtered through a 0.22 µm porosity. The determination of DSi content was through an ICP-OES. Modeling of the erosion process (sediment yield-SY) was performed using the Limburg Soil Erosion Model (2.01 version). A manual calibration procedure was used, and its procedure was repeated for both approaches: with and without runoff separation. For the six rainfall events evaluated, 62% of the hydrograph is formed by groundwater+soil water, especially in autumn-winter and with low-medium magnitude (up to Q = 800 L.s-1). Runoff separation by DSi was essential for obtaining the correct estimation of surface runoff volumes. Furthermore, the effect of dilution during the events was observed, i.e. as Q increases, DSi concentration decreases. Hydrossedimentological monitoring quantifies the sediment at the catchment outlet, which is the result of sediment from soil detachment in the catchment, carried by surface runoff and diluted in the flows that move slowly in outlet (subsurface and base flow). On the other hand, erosion process modeling done by the LISEM model is based only on sediment transported by surface runoff. Since the model simulates only surface flow, the dilution effect does not occur and thus SSC and SY are simulated incorrectly. Therefore, it is essential to consider different sources of water on the occurrence of runoff events, because the dynamics of the sediment is directly influenced by those. [ABSTRACT FROM AUTHOR]

The intensification of agricultural activities increases the transfer of phosphorus (P) to surface water bodies causing a wide range of environmental, social and economic problems, such as eutrophication. This paper describes the dynamics of P loss during rainfall events (intra-event) and between events (inter-event) in a rural catchment with intensive soil use in southern Brazil, emphasizing the relationships of the solutes with the hydrosedimentological variables. The information on the magnitude and the pattern of P transport was obtained during eighth significant rainfall events, in addition to the sampling performed during the baseflow period (between events). During the events, we evaluated the transfer dynamics of the total P (TP), dissolved P (DP), particulate P (PP) and suspended sediment concentration (SSC). Phosphorus (dissolved and particulate) is predominantly lost during events. The concentrations of DP and PP were low in samples collected in the period between events, when groundwater flow predominates. There is predominance of subsurface flow for the total volume of DP drained into the catchment. The hysteresis of TP forms a loop in the counterclockwise direction at the moment the soil is exposed by plowing, due to P transfer from the cropland to the water course. The transfer of P occurred predominantly in the particulate form (88%) due to the high affinity of P with mineral colloids. There was predominance of clockwise hysteresis for TP and SSC during the fallow period and at the beginning of soil mobilization, indicating the presence of P and sediment sources closer to the catchment outlet. However, during the development period of the crop, when the soil was more exposed due to plowing, counterclockwise hysteresis was observed for TP, which indicates a predominance of sources farther from the outlet, such as the cropland. Thus, we believe that efforts towards adopting practices that reduce erosion can contribute to a reduction of P transfer to water sources. Consequently controlling the process of eutrophication. [ABSTRACT FROM AUTHOR]

[Display omitted] • On average 62% of the streamflow is composed of subsurface + base flow. • Subsurface + base flows are responsible for increased streamflow, especially in autumn–winter. • The sediment dynamic is affected by the dilution process that occurs in the outlet. • The knowledge of flow sources allowed to improve calibration of erosion parameters. • Hydrographs and sedimentographs are not adequately represented by LISEM model. Water flows that move slowly in the landscape are not simulated by spatially and physical distributed erosion models and can contribute significantly during rainfall events in the streamflow, making model calibration complex. The goals of this study were: (i) to assess the relative contribution of subsurface and surface runoff to the streamflow at the outlet and (ii) to investigate to what extent the presence of runoff, other than Hortonian overland flow, affects erosion model performance. The Arvorezinha catchment (1.23 km2 – Southern Brazil) is characterized by the cultivation of tobacco under minimum cultivation system on shallow soils. From October 2011 until October 2013, we set up a complementary monitoring program of water chemistry and samples were collected during rainfall-runoff events to analyze dissolved silicon (DSi). The observed hydrograph was separated into two components using DSi: i) surface flow and ii) groundwater + soil water flow. The OpenLISEM model was used to assess the impact of different runoff sources and understand the hydrological and erosive process dynamics in the catchment. For this, a manual calibration procedure was used and repeated for two approaches: with and without runoff separation. For the six rainfall events evaluated, 62% of the hydrograph is formed by groundwater + soil water, especially in autumn–winter and for low-medium magnitude events (up to Q peak = 800 L s−1). The dilution effect was observed during rainfall events, when liquid discharge increases, DSi concentration and suspended sediment concentration decreases. The performance of physics-based models in a catchment with very fragile soils and with frequent changes in land use, is impacted by runoff separation. [ABSTRACT FROM AUTHOR]

The hydrological dynamics of a small rural river catchment in southern Brazil have been used to understand the impact of agricultural activity on soil and water resource degradation. The monitoring and modeling strategies employed to better understand the integrated phenomena focus on surface flow dynamics and the associated processes, such as erosion, sediment yield (SY), and chemical element transfer. In this context, monitoring and modeling techniques are combined in order to include the main hydrological processes involved in soil and water resource degradation. The project began in 2002 and over 500 rainfall-runoff-sediment events and suspended sediment concentration make up the hydrological database under different land use and soil management conditions. The 1.2 km2 catchment of the study is characterized by the presence of shallow soils, high slope, intense agricultural activity, and high SY (~150 t.km-2.y-1). Techniques that enable the identification of the origin and redistribution of sediments (e.g fingerprinting approach and Cs137) and hydrograph analysis are being used to further understand the dynamics of SY in the catchment. The comprehension of the factors involved in the SY dynamics has allowed the improvement and application of different mathematical models (e.g., LISEM and WATERSHED) to simulate surface flow and SY. These models are used to represent the influence of soil and water conservation practices while considering the interaction between the different landscape components (crops, roads, drainage network, etc.). From this set of data and tools, the capacity of the agricultural production system, drainage network, wetlands and riparian forests in accelerating or retarding water flow, sediment, and chemical elements in the landscape are evaluated. All of these studies have been used to improve soil and water conservation practices at catchment scale, meeting the expectations of farmers in erosion control and water storage as well as of the society interested in maintaining the hydrological functions of soils in catchment scale. [ABSTRACT FROM AUTHOR]