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Emissions of nitrous oxide (N2O) over croplands are a major source of greenhouse gases to the atmosphere. The precise accounting of sources of N2O is essential to national and global budgets, as well as the understanding of the spatial and temporal relationships with environmental variables such as rainfall, air and soil temperature, and soil moisture. The objective of this work was to investigate the temporal correlations of N2O fluxes with soil and air temperatures, as well as soil moisture. N2O fluxes were measured over four biofuel crops in Central Illinois during their establishment phase. Measurements were carried out from 2009 to 2011 using a trace gas analyzer (TGA) with tunable laser technology. Measurements of concentrations of N2O and CO2 were taken at the center of four plots of maize/soybean rotation, miscanthus (Miscanthus × giganteus), switchgrass (Panicum virgatum) and a mixture of native prairie plants. Cumulative fluxes indicate an average emission of nitrogen via N2O fluxes on the order of 1.5 kg N ha−1 year−1, in agreement with chamber measurements previously reported for the site. N2O fluxes were associated with peaks in soil and air temperature, and soil moisture, particularly during spring and winter thaws. Cross‐wavelet analysis was used to investigate the correlation between N2O fluxes and those variables. Results indicate that N2O fluxes and meteorological variables have significant covariance in time scales ranging from 4 to 32 days. In addition, temporal delays of 1–8 days were found in those relationships. Cross‐wavelet patterns were similar when relating N2O fluxes with soil temperature, air temperature and soil moisture. The temporal patterns of fluxes and environmental variables reported here support the modeling of emissions and highlight the importance of considering the timing of fluxes in relation to trends in meteorological variables. [ABSTRACT FROM AUTHOR]

It is generally accepted that El Niño–Southern Oscillation (ENSO) is the main modulator of rainfall variability over Northern South America in the interannual scale. Assuming that, an index is proposed to quantify this expected interannual variability in time series of rainfall. The result is the exposure assessment to the effects of droughts, measured with the Standardized Precipitation Index (SPI) for the monthly scale. The SPI is calculated from rainfall series, and wavelet analysis is used to estimate the variance for different frequencies present in the signal. The Wavelet Interannual Variability Index (WIVI) is calculated as the sum of the wavelet coefficients over a predetermined range of modes of variability (with periods longer than 2 year and shorter than 8 years). The index was tested using a dataset of rainfall records from Tocantins state, Central Brazil. Most of the series ranged from 1974 to 2012. On average, the series had 3.2% of gaps which were not filled to avoid the effect of artificial trends on the data. The state lies mostly over the Cerrado biome and is a new frontier of agricultural development in Brazil. According to the results, the Northern region is under higher exposure of interannual variability, with higher values of WIVI. The assessment is in agreement with large‐scale features of South American climate, specifically considering the influences of the Pacific and Atlantic Oceans and their patterns of sea surface temperature (SST). Interannual variability of rainfall was quantified by applying wavelet decomposition to time series of Standardized Precipitation Index (SPI). The wavelet variance for time scales of 2–8 years was quantified for 36 stations over Tocantins, Central Brazil. The variability within those scales was normalized as the Wavelet Index of Interannual Variability (WIVI). According to results, the Northern region is under higher exposure of interannual variability, with higher values of WIVI. The assessment is in agreement with large‐scale features of South American climate, specifically considering the influences of the Pacific and Atlantic Oceans and their patterns of sea surface temperature (SST). [ABSTRACT FROM AUTHOR]

The contribution of coherent structures ( CSs) to daytime buoyancy heat flux was calculated for three forest sites in the Amazon region and a wetland site. Ejections and sweeps had similar contributions to fluxes at all sites, and when decomposing this contribution in scales, the resulting spectra were narrower for the forests. When accounting for times scales from 10 to 200s, CSs contributed to approximately 80% of fluxes for Caxiuanã forest site, with lower values for other locations. Among the forest, the contribution for the Jaru site was the lowest (≈66%) due to peak of contribution being close to 200s. [ABSTRACT FROM AUTHOR]