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This study explored enhancing WC-12Co coatings' performance and preventing decarburization by adding Cr, Cr 3 C 2 , and VC. Coatings were prepared using HVOF technology, and their microstructure, mechanical properties, wear behavior, and corrosion resistance were analyzed. Results indicated that VC and Cr 3 C 2 add-ins effectively prevented decarburization, with T2 coatings (WC-12Co-2VC-2Cr 3 C 2) showing lower porosity, higher hardness, and improved wear resistance. However, T1 coatings (WC-12Co-2VC-2Cr) demonstrated superior corrosion resistance due to Cr addition. The findings provide insights into the additives' effects on WC-12Co coatings and underscore the potential of VC and Cr 3 C 2 as decarburization inhibitors. • VC and Cr 3 C 2 suppressed the decarburization of WC particles in the HVOF process. • The addition of Cr resulted in the formation of oxide film in high temperature sliding wear. • T2 coating with Cr 3 C 2 added showed better wear resistance due to higher hardness and low porosity [ABSTRACT FROM AUTHOR]

The industry widely uses WC coatings to protect vital machine parts, including industrial gas turbines, ball valves, and aircraft landing gear shafts. To enhance the comprehensive performance of WC-10Co cemented carbide coatings, this study added VC and Cr 3 C 2 grain inhibitors to refine the WC particles. Two novel powder compositions, S1 (WC-10Co-2Cr 3 C 2 -2VC) and S2 (WC-10Co-2VC-2Cr) were developed using the spray granulation method, alongside a commercial WC-10Co-4Cr powder as a control. These coatings were applied to 316 stainless steel substrates using the HVOF technique and subjected to XRD, SEM, hardness, friction, and electrochemical analysis. The microstructures, phase compositions, and various properties of WC-10Co-2Cr 3 C 2 -2VC and WC-10Co-2VC-2Cr coatings were systematically investigated. The results indicate a significant reduction in decarburization and porosity in S1 and S2 coatings compared to the commercial WC-10Co-4Cr coatings. VC and Cr 3 C 2 suppressed the Ostwald ripening phenomenon, leading to smaller WC particle sizes in S1 and S2 coatings. In terms of performance, WC-10Co-2Cr 3 C 2 -2VC exhibited the highest hardness and superior wear resistance, while the WC-10Co-2VC-2Cr coating displayed the lowest corrosion rate in a 5 wt% H 2 SO 4 solution at 25 °C, all while maintaining excellent mechanical properties. This study opens potential directions for the creation of high-performance WC-based coatings. • VC and Cr 3 C 2 suppressed the Ostwald ripening phenomenon, leading to smaller WC particle sizes. • WC-10Co-2Cr 3 C 2 -2VC exhibited the highest hardness and superior wear resistance. • WC-10Co-2VC-2Cr coating displayed the lowest corrosion rate in a 5 wt% H 2 SO 4 solution at 25 °C. [ABSTRACT FROM AUTHOR]

The 1.0C-1.5Cr steel was subjected to conventional quenching and laser surface quenching treatment. A process combing double quenching and laser surface quenching was proposed for enhancing surface hardness and obtaining finer microstructure. The cementite dissolution and grain growth behavior in the austenitizing process of single quenching, double quenching, and laser surface quenching were studied. The results indicated that compared with single quenching, mean diameter of undissolved cementite particles (UCP) was much finer in double quenching, and the final prior austenite grain size (PAGS) could be decreased by nearly 40% to about 4.5 μm. Both grain and cementite particles near the surface will coarsen after laser surface treatment. Compared with single quenching, the PAGS within hardened layer can be decreased by at least 11% through double quenching, and the mean diameter of UCP at the bottom of hardened layer can be decreased by about 20%. Compared with conventional quenching, surface hardness was enhanced by about 20% through laser surface quenching, contributing to the wear resistance. However, the hard and brittle surface layer tends to be crack source during the impact process, leading to the deterioration of final impact toughness. Under the identical laser parameters, the impact absorbed energy is similar in both single and double quenching, which is about 25% of that before laser surface quenching. The impact absorbed energy can be increased from 22J to 28J by preheating at 160 °C during the laser surface quenching. [ABSTRACT FROM AUTHOR]