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Start Over Author "Mangalaraj Selvaraj" Topic x-ray diffraction
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1. Syntheses of fused tetrahydro-β-carboline analogues through imide carbonyl activation using BBr: Evidence for the involvement of fused cyclic N-acyliminium ion intermediate.

Author

MANGALARAJ, SELVARAJ, SELVAKUMAR, JAYARAMAN, and RAMANATHAN, CHINNASAMY

Subjects
*CARBOLINES, *HETEROCYCLIC compounds, *SINGLE crystals, *X-ray diffraction, *INTRAMOLECULAR catalysis
Abstract

The fused cyclic N-acyliminium ion generated during the imide carbonyl activation reaction of phenethylphthalimide was confirmed by single crystal X-ray diffraction. The Lewis acid assisted imide carbonyl activation methodology was successfully extended to synthesize fused tetrahydro-β-carboline units from the corresponding N-indolylethylimides. [Figure not available: see fulltext.] [ABSTRACT FROM AUTHOR]

Published
2015
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