16 results on '"Thorogood, Gordon"'
Search Results
2. Cation disorder in NaW2O6+δ ·nH2−z O post-ion exchange with K, Rb, Sr, and Cs
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Thorogood, Gordon J., Kennedy, Brendan J., Avdeev, Maxim, Peterson, Vanessa K., Hanna, John V., and Luca, Vittorio
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CATIONS , *ION exchange (Chemistry) , *OXIDES , *POTASSIUM , *RUBIDIUM , *STRONTIUM , *CARBON , *THERMAL analysis , *NUCLEAR magnetic resonance , *X-ray diffraction , *NEUTRON scattering - Abstract
Abstract: The structure of the defect pyrochlore NaW2O6+δ ·nH2−z O after ion exchange with K, Rb, Sr or Cs for Na has been investigated using thermal analysis, solid-state nuclear magnetic resonance, laboratory X-ray and neutron diffraction methods. Neutron diffraction studies show that both the A-type cations (Na+, K+, Rb+, and/or Cs+) and the water molecules reside within the channels that form in the 111 direction of the W2O6 framework and that these strongly interact. The analytical results suggest that the water and A-type cations compete for space in the tunnels within the W2O6 pyrochlore framework, with the total number of water molecules and cations being approximately constant in the six samples investigated. The interplay between the cations and water explains the non-linear dependence of the a lattice parameter on the choice of cation. It appears that the ion-exchange capacity of the material will be controlled by the amount of water initially present in the sample. [Copyright &y& Elsevier]
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- 2011
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3. Structural studies of the aeschynite–euxenite transformation in the series Ln(TiTa)O6 Ln =Lanthanide
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Thorogood, Gordon J., Avdeev, Maxim, and Kennedy, Brendan J.
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MOLECULAR structure , *EUXENITE , *PHASE transitions , *TITANATES , *CERAMIC materials , *SOLID state chemistry , *MICROSTRUCTURE , *SCANNING electron microscopy - Abstract
Abstract: Ceramics based on LnTiTaO6 (Ln =La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) were prepared using a conventional solid-state ceramic route. The structure and microstructure of the samples were analyzed using scanning electron microscopy, synchrotron X-ray powder diffraction and neutron diffraction techniques. The unit cell volume of the ceramics decreased with a decrease in ionic radius of the rare-earth ions until a phase change was seen at Ho where the space group changed from Pnma to Pbcn. The results confirmed that the boundary of the aeschynite to euxenite phase change that lies between DyTiTaO6 and HoTiTaO6 and demonstrate that this is a result of distortion of the channels in the aeschynite structure. [Copyright &y& Elsevier]
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- 2010
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4. Anomalous lattice parameter increase in alkali earth aluminium substituted tungsten defect pyrochlores
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Thorogood, Gordon J., Kennedy, Brendan J., Peterson, Vanessa K., Elcombe, Margaret M., Kearley, Gordon J., Hanna, John V., and Luca, Vittorio
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ALKALI metals , *ALUMINUM compounds , *TUNGSTEN , *X-ray diffraction , *NEUTRON diffraction , *NUCLEAR magnetic resonance , *OXIDES , *MATHEMATICAL models - Abstract
Abstract: The structures of the defect pyrochlores AAl0.33W1.67O6 where A=K, Rb or Cs have been investigated using X-ray and neutron powder diffraction methods as well as the ab initio modelling program VASP. The three cubic pyrochlores exhibit a non-linear increase in lattice parameter with respect to ionic radius of the A cation as a consequence of displacive disorder of the A-type cations. Solid state 27Al MAS NMR studies of this pyrochlore system reveal shifts in the δ∼21–22ppm range that are indicative of pseudo-5 coordinate Al environments and emanate from distorted Al octahedral with one abnormally long Al–O bond. Solid state 39K, 85Rb, 87Rb and 133Cs MAS and static NMR studies reflect the local cation disorder demonstrated in the structural studies. [Copyright &y& Elsevier]
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- 2009
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5. Structure and dehydration of the pyrochlore system NaW2− y Mo y O6+ δ ·nH2− z O between 10 and 675K
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Thorogood, Gordon J., Kennedy, Brendan J., Luca, Vittorio, Blackford, Mark, van de Geest, Samantha K., Finnie, Kim S., Hanna, John V., and Pike, Kevin J.
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CRYSTAL lattices , *X-ray diffraction , *INFRARED spectroscopy , *NUCLEAR magnetic resonance - Abstract
Abstract: The temperature dependence of the structure of the pyrochlore NaW2− y Mo y O6+ δ ·nH2− z O has been investigated using a variety of diffraction and spectroscopic methods. The positions of OH−/H2O molecules in the structure have been determined. Increases in temperature induce small lattice parameter changes, which are thought to result from movement of the H2O molecules in the pyrochlore lattice. [Copyright &y& Elsevier]
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- 2008
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6. Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide.
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Thorogood, Gordon J., Zhang, Zhaoming, Hester, James R., Kennedy, Brendan J., Ting, Jimmy, Glover, Chris J., and Johannessen, Bernt
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TECHNETIUM compounds , *CHEMICAL structure , *OXIDES , *X-ray diffraction , *NEUTRON diffraction , *ABSORPTION spectra - Abstract
The structure of TcCo2O4has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc–O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent. [ABSTRACT FROM AUTHOR]
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- 2011
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7. The Effect of a Rapid Heating Rate, Mechanical Vibration and Surfactant Chemistry on the Structure-Property Relationships of Epoxy/Clay Nanocomposites.
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Nuhiji, Betime, Attard, Darren, Thorogood, Gordon, Hanley, Tracey, Magniez, Kevin, Bungur, Jenny, and Fox, Bronwyn
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X-ray diffraction , *DISPERSION (Chemistry) , *RAPID prototyping , *COLLOIDS , *TRANSMISSION electron microscopy - Abstract
The role of processing conditions and intercalant chemistry in montmorillonite clays on the dispersion, morphology and mechanical properties of two epoxy/clay nanocomposite systems was investigated in this paper. This work highlights the importance of employing complementary techniques (X-ray diffraction, small angle X-ray scattering, optical microscopy and transmission electron microscopy) to correlate nanomorphology to macroscale properties. Materials were prepared using an out of autoclave manufacturing process equipped to generate rapid heating rates and mechanical vibration. The results suggested that the quaternary ammonium surfactant on C30B clay reacted with the epoxy during cure, while the primary ammonium surfactant (I.30E) catalysed the polymerisation reaction. These effects led to important differences in nanocomposite clay morphologies. The use of mechanical vibration at 4 Hz prior to matrix gelation was found to facilitate clay dispersion and to reduce the area fraction of I.30E clay agglomerates in addition to increasing flexural strength by over 40%. [ABSTRACT FROM AUTHOR]
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- 2013
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8. Crystal structure and phase transitions in the uranium perovskite, Ba2SrUO6
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Reynolds, Emily, Kennedy, Brendan J., Thorogood, Gordon J., Gregg, Daniel J., and Kimpton, Justin A.
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CRYSTAL structure , *PHASE transitions , *URANIUM , *PEROVSKITE , *BARIUM compounds , *MIXED oxide fuels (Nuclear engineering) , *TEMPERATURE effect , *X-ray diffraction - Abstract
Abstract: The structure of one of the oxides proposed to be present in the grey phase of irradiated mixed oxide fuel, the double perovskite Ba2SrUO6 has been investigated from room temperature to 1300K using synchrotron X-ray powder diffraction methods. The divalent strontium and hexavalent uranium are found to be fully ordered in the double-perovskite arrangement of alternating octahedra sharing corner oxygen atoms. At room temperature Ba2SrUO6 adopts a monoclinic structure in space group P21/n. Heating to above 900K induces a first order transition to a rhombohedral structure, and further heating to above 1200K results in a continuous transition to a cubic structure. The sequence of structures is associated with the progressive loss of cooperative tilting of the corner sharing SrO6 and UO6 octahedra. [Copyright &y& Elsevier]
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- 2013
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9. The effect of alternate heating rates during cure on the structure–property relationships of epoxy/MMT clay nanocomposites
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Nuhiji, Betime, Attard, Darren, Thorogood, Gordon, Hanley, Tracey, Magniez, Kevin, and Fox, Bronwyn
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EPOXY resins , *NANOCOMPOSITE materials , *MOLECULAR structure , *RHEOLOGY , *HEATING , *TRANSMISSION electron microscopy , *MECHANICAL behavior of materials , *MONTMORILLONITE , *X-ray diffraction - Abstract
Abstract: This paper investigates the effect of both the mixing technique and heating rate during cure on the dispersion of montmorillonite (MMT) clay in an epoxy resin. The combination of sonication and using a 10°C/min heating rate during cure was found to facilitate the dispersion of nanoclay in epoxy resin. These processing conditions provided a synergistic effect, making it possible for polymer chains to penetrate in-between clay galleries and detach platelets from their agglomerates. As the degree of dispersion was enhanced, the flexural modulus and strength properties were found to decrease by 15% and 40%, respectively. This is thought to be due to individual platelets fracturing in the nanocomposite. Complementary techniques including X-ray diffraction (XRD), small angle X-ray scattering (SAXS), scanning electron microscopy–energy dispersive X-ray spectroscopy (SEM–EDX), transmission electron microscopy (TEM) and optical microscopy were essential to fully characterise localised and spatial regions of the clay morphologies. [Copyright &y& Elsevier]
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- 2011
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10. Comparing results of X-ray diffraction, µ-Raman spectroscopy and neutron diffraction when identifying chemical phases in seized nuclear material, during a comparative nuclear forensics exercise.
- Author
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Rondahl, Stina Holmgren, Pointurier, Fabien, Ahlinder, Linnea, Ramebäck, Henrik, Marie, Olivier, Ravat, Brice, Delaunay, François, Young, Emma, Blagojevic, Ned, Hester, James R., Thorogood, Gordon, Nelwamondo, Aubrey N., Ntsoane, Tshepo P., Roberts, Sarah K., and Holliday, Kiel S.
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X-ray diffraction , *RAMAN spectroscopy , *NEUTRON diffraction , *RADIOACTIVE substances , *DIFFRACTION patterns , *URANIUM oxides - Abstract
This work presents the results for identification of chemical phases obtained by several laboratories as a part of an international nuclear forensic round-robin exercise. In this work powder X-ray diffraction (p-XRD) is regarded as the reference technique. Neutron diffraction produced a superior high-angle diffraction pattern relative to p-XRD. Requiring only small amounts of sample, µ-Raman spectroscopy was used for the first time in this context as a potentially complementary technique to p-XRD. The chemical phases were identified as pure UO2 in two materials, and as a mixture of UO2, U3O8 and an intermediate species U3O7 in the third material. [ABSTRACT FROM AUTHOR]
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- 2018
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11. On the origin of strengthening mechanisms in Ni-Mo alloys prepared via powder metallurgy.
- Author
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Yang, Chao, Muránsky, Ondrej, Zhu, Hanliang, Thorogood, Gordon J., Huang, Hefei, and Zhou, Xingtai
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NUCLEAR reactors , *TRANSMISSION electron microscopy , *SINTERING , *ANNEALING of metals , *X-ray diffraction - Abstract
A new class of materials, which rely on the dispersion strengthening of SiC particles in addition to precipitation strengthening by nano-precipitates is being developed for the application in molten salt nuclear reactors. A battery of dispersion and precipitation strengthened (DPS) NiMo-based alloys containing varying amount of SiC (0.5–2.5 wt.%) was prepared via a mechanical alloying (MA) route followed by spark plasma sintering (SPS), rapid cooling, high-temperature annealing and water quenching. Lab X-ray Diffraction (XRD), Electron Back Scattering Diffraction (EBSD), and Transmission Electron Microscopy (TEM) were employed in the microstructural characterization of this new type of alloys. It is shown that the NiMo matrix of these alloys is effectively reinforced by dispersion of SiC from the initial powder mixture and nano-Ni 3 Si precipitates, which precipitated during the sintering/annealing process. Furthermore, the matrix is strengthened by solid-solution of Mo in Ni. As a result, these newly developed NiMo alloys take advantage of dispersion, precipitation and solid solution strengthening, which leads to their superior mechanical properties. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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12. Structural studies of the rhombohedral and orthorhombic monouranates: CaUO4, α-SrUO4, β-SrUO4 and BaUO4.
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Murphy, Gabriel, Kennedy, Brendan J., Johannessen, Bernt, Kimpton, Justin A., Avdeev, Maxim, Griffith, Christopher S., Thorogood, Gordon J., and Zhang, Zhaoming
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ORTHORHOMBIC crystal system , *CRYSTAL structure , *X-ray diffraction , *NEUTRONS , *MOIETIES (Chemistry) - Abstract
The structures of some A UO 4 ( A =Ca, Sr, or Ba) oxides have been determined using a combination of neutron and synchrotron X-ray diffraction, supported by X-ray absorption spectroscopic measurements at the U L 3 -edge. The smaller Ca cation favours a rhombohedral A UO 4 structure with 8-coordinate UO 8 moieties whilst an orthorhombic structure based on UO 6 groups is found for BaUO 4 . Both the rhombohedral and orthorhombic structures can be stabilised for SrUO 4 . The structural studies suggest that the bonding requirements of the A site cation play a significant role in determining which structure is favoured. In the rhombohedral structure, Bond Valence Sums demonstrate the A site is invariably overbonded, which, in the case of rhombohedral α-SrUO 4 , is compensated for by the formation of vacancies in the oxygen sub-lattice. The uranium cation, with its flexible oxidation state, is able to accommodate this by inducing vacancies along its equatorial coordination site as demonstrated by neutron powder diffraction. [ABSTRACT FROM AUTHOR]
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- 2016
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13. One-step approach for synthesis of nanosized Cu-doped zeolite A crystals using the Cu–EDTA-complex.
- Author
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Yordanov, Ivan, Karatchevtseva, Inna, Chevreau, Hubert, Avdeev, Maxim, Holmes, Rohan, Thorogood, Gordon, and Hanley, Tracey
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NANOPARTICLES , *COPPER compounds synthesis , *DOPING agents (Chemistry) , *ZEOLITES , *CRYSTAL structure , *X-ray diffraction - Abstract
Copper-doped nanosized zeolite A crystals were synthesized by an in situ templating approach using [Cu(EDTA)] 2− -complex. The structural properties of the copper containing zeolite crystals were characterized by a suite of different techniques including SEM–EDX, ESR, mid-IR and Far-IR, Raman, in situ XRD and non-ambient neutron powder diffraction. The SEM investigations on the morphology show spheroidal zeolite A crystals with average size ∼200 nm. The asymmetric ESR spectrum shows that the Cu 2+ ion is in a tetragonal-distorted octahedral crystal field. FT-IR and Raman spectroscopies provide information on coordination environment of the copper ion. The band due to stretching vibration of C–N bond, where N is coordinated to the copper ion (C–N–Cu), was observed at 1109 cm −1 in the mid-infrared region. The Raman band due to the Cu–O bond is present at 630 cm −1 indicating the coordination of the Cu 2+ -cation to COO − -group of the EDTA-ion. The XRD data shows an enlarged d -spacing between the adjacent zeolite lattice planes due to the presence of the [Cu(EDTA)] 2− -complex in comparison to template-free LTA zeolite structure. LeBail fitting approach on temperature-dependent in situ X-ray and neutron diffraction profiles have demonstrated the expansion of the zeolite cell during the thermal treatment followed by subsequent contraction with the decomposition of the organic template. [ABSTRACT FROM AUTHOR]
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- 2014
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14. Determination of martensite structures of the Au7Cu5Al4 and Au7Cu5.7Al3.3 shape-memory alloys.
- Author
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Elcombe, Margaret M., Kealley, Catherine S., Bhatia, Vijay K., Thorogood, Gordon J., Carter, Damien J., Avdeev, Maxim, and Cortie, Michael B.
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GOLD compounds , *MARTENSITIC structure , *SHAPE memory alloys , *TEMPERATURE effect , *SPACE groups , *PHASE transitions , *CRYOGENICS - Abstract
The β -phase of Au 7 Cu 5 Al 4 undergoes a reversible shape-memory phase transformation for which several conflicting martensite phases have been reported. Here we show the significance of the cooling temperature used to obtain the martensite. If Au 7 Cu 5 Al 4 is cooled from the parent phase condition to cryogenic temperatures, e.g. below 200 K, the martensitic phase is orthorhombic (space group Pcmn , a = 4.4841 Å, b = 5.8996 Å, c = 17.8130 Å); however, when this composition is cooled to only ∼260 K it will in general consist of a mixture of orthorhombic and monoclinic phase (the latter has space group P 2 1 / m , a = 4.4742 Å, b = 5.9265 Å, c = 13.3370 Å, β = 91.425°). In contrast, a sample with decreased Al content (Au 7 Cu 5.7 Al 3.3 ) transforms fully to monoclinic phase if cooled to ∼260 K. [ABSTRACT FROM AUTHOR]
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- 2014
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15. High temperature transformations of the Au7Cu5Al4 shape-memory alloy
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Cortie, Michael B., Kealley, Catherine S., Bhatia, Vijay, Thorogood, Gordon J., Elcombe, Margaret M., and Avdeev, Maxim
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SHAPE memory alloys , *MOLECULAR structure , *INTERMETALLIC compounds , *GOLD alloys , *ORDER-disorder in alloys , *HIGH temperatures , *X-ray diffraction , *PHASE equilibrium , *MELTING points - Abstract
Abstract: The β-phase of Au7Cu5Al4 undergoes a reversible shape-memory phase transformation, however there has been some uncertainty regarding the crystal structure or structures of the parent phase. Here we show that, under equilibrium conditions, the parent phase possesses the L21 structure between its A p (about 79°C) and ∼630°C, and the B2 primitive cubic structure between ∼630°C and its melting point. It melts directly from B2 into the liquid state and hence never achieves the random bcc A2 structure that has been previously mooted. Splat-cast samples of the alloy are martensitic, proving that development of equilibrium order and defect concentration are not pre-requisites for the A → M transformation to occur. [Copyright &y& Elsevier]
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- 2011
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16. Microcrystalline Hexagonal Tungsten Bronze. 1. Basis of Ion Exchange Selectivity for Cesium and Strontium.
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Griffith, Christopher S., Luca, Vittorio, Hanna, John V., Pike, Kevin J., Smith, Mark E., and Thorogood, Gordon S.
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TUNGSTEN bronze , *ION exchange (Chemistry) , *RADIOCHEMICAL analysis , *NUCLEAR magnetic resonance spectroscopy , *X-ray diffraction , *NEUTRON diffraction , *STRONTIUM , *CESIUM - Abstract
The structural basis of selectivity for cesium and strontium of microcrystalline hexagonal tungsten bronze (HTB) phase Na[subx]WO[sub3+x/2]∙zF[sub2]O has been studied using X-ray and neutron diffraction techniques, 1D and 2D [sup23]Na magic angle spinning (MAS) nuclear magnetic resonance (NMR) spetroscopy, and radiochemical ion exchange investigations. For the HTB system, this study has shown that scattering techniques alone provide an incomplete description of the disorder and rapid exchange of water (with tunnel cations) occuring in this system. However, 1D and 2D [sup23]Na MAS NMR has indentified three sodium species within the HTB tunnels—species A, which is located at the center of the hexagonal window and is devoid of coordinated water, and species B and C, which are the di and monohydrated variants, respectively, of species A. Although species B accords with the traditional crystallographic model of the HTB phase, this work is the first to propose and identify the anhydrous species A and monohydrate species .C. The population (total) of species B and C decreases in comparison to that of species A with increasing exchange of either cesium or strontium; that is, species B and C appear more exchangeable than species A. Moreover, a significant proportion of tunnel water is redistributed by these cations. Multiple ion exchange inversitgations with radiotracers [sup137]Cs and [sup85]Sr have shown that for strontium there is a definite advantage in ensuring that any easily exchanged sodium is removed from the HTB tunnels prior to exchange. The decrease in selectivity (wrt cesium) is most probably due to the slightly smaller effective size of Sr[sup2+]; namely, it is less of a good fit for the hexagonal window, ion exchange site. The selectivity of the HTB framework for cesium has been shown unequivovally to be defined by the structure of the hexagonal window, ion exchange site. Compromising the geometry of this window even in the slightest way by either (1) varying the cell volume through changes to hydration or sodium content or (2) introducing disorder in the a—b plane through isomorphous substitution of molybdenum is sufficient to reduce the selectivity. Indeed, it is our hypothesis that this applies for all cations which are strongly bound by the HTB framework. [ABSTRACT FROM AUTHOR]
- Published
- 2009
- Full Text
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