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The Kanggur ductile shear zone (KDSZ), located in the south margin of the Central Asia Orogenic Belt (CAOB), plays a critical role in the tectonic evolution and mineralization in eastern Tianshan. Although different isotopic chronologies have been reported, the termination of the KDSZ deformation remains controversial. Here, we provide new data obtained by U-Pb dating of zircon and apatite from Huangshandong synkinematic granite (HSG) and Huludong deformed granite (HDG) to constrain the termination of the KDSZ deformation. The U-Pb age of apatite from HSG (249.1 ± 1.8 Ma) is identical to that of zircon (256.5 ± 2.1 Ma) within the error range. In contrast, the U-Pb age of apatite from HDG (248.1 ± 4.0 Ma) is significantly younger than that of zircon (347.3 ± 2.5 Ma). The HDG and HDG have the geochemical characteristics of I-type granites petrogenesis, including high SiO2 (up to 75.47%), high alkaline (K2O + Na2O = 6.39%–8.05%), low FeOT/MgO (2.4–3.4), and peraluminous (A/CNK = 1.01–1.08). Combined with previous Sr-Nd isotope compositions, the positive zircon εHf(t) values and TDM2 ages indicate that the ca. 347 Ma HDG originated from the re-melting of juvenile crust crustal-derived magma in a volcanic arc environment during the northward subduction of the Kanggur oceanic basin, and the ca. 257 Ma HSG originated from the partial melting of thickened juvenile crust in a post-collisional environment. Although trace elements of zircon show typical magmatic characteristics, apatite does not. With the presence of distinct major and trace elements in apatite, the apatite from HSG is characterized by high Mn (>2500 ppm), slight enrichment in the middle rare earth elements (MREEs), and obvious negative Eu anomalies (δEu = 0.09–0.21), indicating that it is related to magmatic apatite. In contrast, the apatite from HDG, with low Mn (<860 ppm), depleted light rare earth elements (LREEs), and variable Eu anomalies (δEu = 0.30–1.34), demonstrated fluid metasomatism with metamorphic overprinting. Combined with the regional geology and published geochronology data, the HSG is interpreted to be derived from the magma experiencing cooling crystallization in the plastic state from 256.5 to 249.1 Ma, while the HDG is considered to have experienced metamorphism and deformation between 347.3 and 248.1 Ma. Owing to the relatively low closure temperature of the U-Pb isotopic system, the apatite U-Pb ages are interpreted as Early Triassic tectono-magmatism events, corresponding to the end of deformation of the KDSZ. This is inferred to be related to the continuous evolution of the Paleo-Asian Ocean in the Late Permian to Early Triassic. [ABSTRACT FROM AUTHOR]

[Display omitted] • Mo hosted biotite moyite of the Tieling deposit formed at ca. 304.5 Ma. • Biotite moyite-related Mo mineralization age was limited to ca. 300.6 ∼ 298.7 Ma. • The biotite moyite mainly derived from the partial melting of juvenile lower crust. • Mo mineralization formed in an extensional setting after Kanggur Ocean subduction. The Aqishan-Yamansu belt in the Eastern Tianshan (NW China) contains many Carboniferous granitic intrusive rocks and volcanic rocks and hosts numerous large to medium sized Fe (-Cu) deposits. The Tieling deposit consisting of 89 iron ore bodies in the Aqishan-Yamansu belt has been mined since discovered in 1970 s. Mo mineralization was newly identified in concealed rocks of the Tieling deposit, and molybdenite is extensively distributed as a disseminated phase in the biotite moyite and occurs as aggregates in quartz veins. The molybdenite Re-Os model ages (300.6 ∼ 298.7 Ma) are consistent with the zircon U-Pb age (304.5 ± 2.4 Ma) of the ore-causative biotite moyite within error, which indicating that the Tieling Mo mineralization occurred during the Late Carboniferous. The Late Carboniferous biotite moyite exhibits calc-alkaline and peraluminous characteristics, with negligible Eu anomalies, akin to I-type granites. Dominantly positive εHf(t) values (+13.6 to + 15.2), variable Mg# values (31 to 49), and limited variation in (87Sr/86Sr) i ratios (I Sr = 0.70358–0.70390), and positive εNd(t) values (+4.55 to 6.39), along with the juvenile T DM2 age (548 to 697 Ma), suggest that the biotite moyite was probably originated from partial melting of the juvenile lower crust with involvement of mantle-derived magmas. Integrating published data and our work, we conclude that the Aqishan-Yamansu belt evolved from the pre- Early Carboniferous forearc basin (ca. 450–350 Ma) to the Carboniferous island arc environment (ca. 350–310 Ma) triggered by the bidirectional subduction of the Kanggur Ocean, then the extensional geodynamic setting (ca. 310–270 Ma) is conducive to the porphyry Mo mineralization of the Tieling deposit and Ni-Cu-Au deposits in the Eastern Tianshan. [ABSTRACT FROM AUTHOR]