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The article assesses the atmospheric effects of the dust outbreaks in the Iberian Peninsula and Africa. The study was conducted on a weather situation unique to existing scenarios, where growth of an African dust outbreak in the southern Iberian Peninsula was caused by an unknown source from January 2004 to May 2008. Results showed that synoptic patterns of dust outbreaks without stable systems can elevate atmospheric pollution in various parts of Iberia.

Abstract: This study has investigated the influence of synoptic weather patterns and long-range transport episodes on the concentration levels of airborne particulate matter (TSP, PM10 and PM2.5) and some major ions (SO4 2−, NO3 − and NH4 +) at a background rural station in central Spain. Air mass back-trajectories arriving at the site in 1999–2005 have been analysed by statistical methods. First, cluster analysis was used to group trajectories into 8 clusters depending on their direction and speed. Meteorological scenarios associated to each cluster have been obtained and interpreted. Then, the incidence of different air mass transport patterns on particle concentrations and composition recorded at this station was evaluated. This evaluation included PM10 and PM2.5 concentrations and chemical composition data, obtained at three representative sites of the Madrid air basin during sampling campaigns carried out in the course of the 1999–2005 period. Finally, a residence time analysis of trajectories was also performed to detect remote sources and transport pathways. Significantly elevated concentrations of TSP and PM10 were observed for Northern African flows as a consequence of the transport of mineral dust. Significant inter-cluster differences were also observed for PM2.5 and secondary inorganic compounds, with the highest concentrations associated with low baric gradient situations and Southern European flows. The residence time analysis confirmed that current TSP and PM10 concentrations in central Spain are likely to be influenced significantly by long-range transport of desert dust from different desert regions in North Africa. Furthermore, emissions from continental Europe with a high time of residence in the western and central areas of the Mediterranean basin, seem to significantly influence PM2.5 and secondary inorganic aerosol concentrations in this region. [Copyright &y& Elsevier]

The occurrence of African dust outbreaks over specific areas of the Mediterranean basin has been associated with increases in the PM 10 concentration levels and also in the mortality rates. Different hypothesis have been proposed in the last years to explain the processes by which African dust storms generates negative health effect over urban areas in southern Europe but are still not clear. Some authors have suggested the existence of an interaction between air pollutants from local sources and the occurrence of African dust outbreaks, with a consequent increase in the risk of mortality due to exposure to these anthropogenic emissions. This study sought to identify such a synergistic effect in the Madrid metropolitan area. To this end, an assessment of the influence of African dust on air quality levels, the vertical structure of the atmosphere over Madrid and daily mortality was carried out. Our results indicated that African dust caused a reduction of the mixing layer height and the surface wind speed, by reducing the amount of solar radiation reaching the ground. These facts favored the accumulation of air pollutants emissions from local anthropogenic sources. Moreover, when the dust contribution to PM 10 levels exceeded a threshold value (8 μg/m3), particulate matter mass (PM 10 , PM 2.5) and number (ultra-fine particles) concentration as well as levels of gaseous air pollutants (CO, NO and NO 2) registered at urban-background and urban-traffic monitoring sites, increased with statistical significance. In these conditions, it was found a statistically significant increase in risk of daily mortality in the PM 10 exposure. Hence, ambient air in Madrid was more toxic during African dust events of increasing intensity due to this synergistic effect. Because it can be envisaged that the frequency, duration and intensity of dust storms will increase in the north of Africa due to climate change, it will be a priority to put forward and assess proposals to mitigate the adverse effects on health, focused on the reduction of air pollutant emissions from local sources, as well as proposals regarding the adaptation of the population in urban areas across the Mediterranean basin. • African dust produced a reduction of the mixing layer height over Madrid. • Air pollutants emissions from local sources accumulated in the reduced mixing layer. • This synergistic effect made more toxic the ambient air in Madrid. • Risk of daily mortality in the PM 10 exposure increased in intense African dust events. • Measures for reducing harmful effects should focus on local anthropogenic sources. [ABSTRACT FROM AUTHOR]

African dust (AD) contributions to particulate matter (PM) levels may be reported by Member States to the European Commission during justification of exceedances of the daily limit value (DLV). However, the detection and subsequent quantification of the AD contribution to PM levels is complex, and only two measurement-based methods are available in the literature: the Spanish-Portuguese reference method (SPR), and the Tel Aviv University method (TAU). In the present study, both methods were assessed. The SPR method was more conservative in the detection of episodes (71 days identified as AD by SPR, vs 81 by TAU), as it is less affected by interferences with local dust sources. The mean annual contribution of AD was lower with the TAU method than with SPR (2.7 vs 3.5 ± 1.5 μg/m³). The SPR and TAU AD time series were correlated with daily aluminum levels (a known tracer of AD), as well as with an AD source identified by the Positive Matrix Factorization (PMF) receptor model. Higher r² values were obtained with the SPR method than with TAU in both cases (r² = 0.72 vs 0.56, y = 0.05x vs y = 0.06x with aluminum levels; r² = 0.79 vs 0.43, y = 0.8x vs y - 0.4x with the PMF source). We conclude that the SPR method is more adequate from an EU policy perspective (justification of DLV exceedances) due to the fact that it is more conservative than the TAU method. Based on our results, the TAU method requires adaptation of the thresholds in the algorithm to refine detection of low-impact episodes and avoid misclassification of local events as AD. [ABSTRACT FROM AUTHOR]