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Ultra high pressure (UHP) metamorphism observed in continental terranes implies that continental crust can subduct to ~40 kbar before exhuming to the surface. This process is one of the least understood and widely debated parts of the orogenic cycle. The dominantly felsic composition of UHP continental terranes means that many petrology‐based techniques for determining peak pressures and temperatures are often not possible. In such cases, the detection of UHP conditions depends on the preservation of coesite, a rarely preserved mineral in exhumed UHP terranes as it rapidly transforms to quartz on decompression. Consequently, the qualitative identification of palisade quartz microstructures that form during the retrograde transformation of coesite to quartz is often used to identify UHP terranes. In this study, we conduct electron backscatter diffraction and misorientation analysis of palisade quartz inclusions in the coesite‐bearing pyrope quartzite from the Dora Maira massif in the Alps, and matrix‐scale palisade quartz in the Polokongka La granite from Tso Morari in the Ladakh Himalaya, in order to quantitatively define crystallographic characteristics of quartz after coesite. The repeatability of our observations in two unrelated occurrences of UHP rocks supports our interpretation that the following features provide a systematic and predictable set of criteria to identify the coesite to quartz transition: (1) Quartz crystallographic orientations define spatially and texturally distinct subdomains of palisade quartz grains with 'single crystal' orientations defined by distinct c‐axis point maxima. (2) Adjacent subdomains are misorientated with respect to each other by a misorientation angle/axis of 90°/. (3) Within each subdomain, palisade quartz grain boundaries commonly have intra‐ and inter‐granular misorientations of 60°/[0001], consistent with the dauphiné twin law. Our observations imply that the coesite‐quartz transformation is crystallographically controlled by the epitaxial nucleation of palisade quartz on the former coesite grain, specifically on potential coesite twin planes such as (1‐01) and (021). [ABSTRACT FROM AUTHOR]