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Monogenetic volcanoes are small-volume landforms (< 1 km3) which can develop complex eruption histories. Their genesis may include variations in their primary magma sources and petrogenetic evolution, eruption styles transitions, changes in their emplacement conditions. The Central Andes (Northern Chile) contains >900 small-volume volcanoes, most of which lack a detailed knowledge of their eruption histories due to the limited volcanological studies available. In this paper, we present a detailed volcanostratigraphic, morphometric and petrologic study are used to reconstruct the geology and eruptive history of Cerro Negro volcano. It is a Pleistocene pyroclastic cone which stands out from all monogenetic volcanoes of this region due to its larger size (~1 km3) and location along the axis of the orogen. The activity of Cerro Negro began with a phreatomagmatic phase that produced breccias and a lithic-rich tuff, followed by magmatic activity with lava fountaining and Strombolian styles. This latter magmatic phase produced short lava flows, but mostly spatter agglutination and tephra fallout layers. The composition of erupted materials spans from calk-alkaline basaltic andesite to dacite. The least evolved magmas of Cerro Negro are derived from mantle wedge's partial melts without significant crustal assimilation. However, changes in the composition through the eruption suggest crystal fractionation and shallow magma storage, followed by mixing and crustal contamination during the late stage of the eruption. The absence of significant repose period between the deposition of the distinct products and their total volume together with the observed compositional variations imply that Cerro Negro represents a large volume polycyclic monogenetic volcano. These results are important to understand the mafic magma evolution in thickened crusts and the eruptive styles of long-lasting monogenetic eruptions. • Cerro Negro (CNV) is a c. 1 km3 (bulk volume) Pleistocene pyroclastic cone; it classifies as a large monogenetic volcano • CNV erupted in successive phreatomagmatic, lava fountaining and Strombolian phases; the eruption may have lasted years • CNV magmas were calk-alkaline (55.1 to 66.5 wt% SiO 2) and became more silicic as the eruption progressed • Magmas sourced from metasomatized spinel peridotite; polymagmatism involving fractionation, crustal assimilation and mixing [ABSTRACT FROM AUTHOR]

Cerro Tujle is an isolated Quaternary maar located 21 km south-east of the Salar de Atacama basin. It is situated at 3,554 m a.s.l., on the top of the Cordón de Tujle ridge forming a north-south striking morphological element in the Central Volcanic Zone of the Andes, in northern Chile. The material erupted at Cerro Tujle lies over the Tucúcaro Ignimbrite (3.2 ± 0.3 Ma), covering the whole area. The origin of the magma source, as well as the evolution and control of the volcanic eruptive styles, were determined by fieldwork, stratigraphic, morphometric, textural (density and vesicularity), petrographic, and geochemical analyses. The Cerro Tujle maar features an elliptical crater (333 × 279 m wide in east-west and north-south directions, respectively) surrounded by lava flow and tephra deposits. The total Dense Rock Equivalent volume of the products was calculated in 1.53 × 105 m3, and mainly correspond to andesites (58.62–59.80 wt% of SiO 2). The lava flow can be categorized in at least two types: i) brown-red and green-to-gray andesites located on the north-northwestern flank of the crater, and ii) black andesites with felsic rock clasts distributed around the crater underlying the other lavas. In contrast, the pyroclastic deposit displays breccias of juvenile pyroclasts with xenoliths of rhyolitic composition. These felsic clasts suggest magma assimilation with a shallow magma reservoir during a relatively fast ascent of the magma. This is evidenced by disequilibrium textures in mineral levels, such as reaction rim, and skeletal and sieve textures of the phenocrysts. The field evidence and results of the different analyses suggest a change in the eruptive style from effusive to explosive. This transition is associated with a decrease of the magma flux and a withdrawal of magma below the groundwater table, which has produced a phreatomagmatic eruption by magma-water interaction. • The field relationships between lava flow emission and pyroclastic surge deposit. • Changing eruptive styles in intermediate volcanism. • The hydromagmatic explosive eruptions are not uncommon in the Altiplano-Puna region, northern Chile. [ABSTRACT FROM AUTHOR]